Surface of room temperature ionic liquid [bmim][PF6] studied by polarization- and experimental configuration-dependent sum frequency generation vibrational spectroscopy

Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface.     

一种新颖的光纤应力传感器

基于模体积失配效应与微弯原理，提出了一种新颖的强度型光纤应力传感器，其传输光功率变化与应力之间近似为线性关系，重复性好，无迟滞现象     

中心裂纹圆盘应力强度因子的测试误差分析

本文在中心裂纹圆盘应力强度因子解析解的基础上,利用一阶微分法则,给出了与裂纹相对长度和加载角相关的应力强度因子(K 和K )的4个误差传递函数。这4个误差传递函数关于裂纹相对长度和加载角均是非线性的,它们既是误差分析的基础,又是合理确定裂纹相对长度和加载角的基础。分析结果表明,加载角的误差Δθ除了对纯 型K 的误差几乎没有影响,对纯 型K 影响较小外,对复合型K 、K 的误差均有较大影响。最后,本文建议裂纹相对长度的取值范围为0.4～0.6;还建议在复合型断裂试验时,必须依据对K 、K 的总体精度要求来严格控制加载角的精度。     

EFFECTS OF FINELY DISPERSED METALLIC PALLADIUM ON MICROSTRUCTURE AND PROPERTIES OF NANOCOMPOSITES PRODUCED BY SOL-GEL TECHNIQUE

Nanosized palladium particles were incorporated into mesoporous silica matrix to obtain nanocomposites using the sol-gel technique. Effects of the finely dispersed metallic palladium on the microstructure and properties of the nanocomposites were investigated. By means of X-ray diffraction and optical absorption, it was found that palladium particles were 5-9 nm in diameter and their uniform dispersion in the mesoporous silica depended on both the content of the palladium and the structural features of the silica matrix. The results showed that the mixing method of preparation led to wider size distribution of the nanosized particles as compared to the immersion method, but dispersed degree was reduced. Although the incorporation of nanosized palladium particles could not substantially induce significant structural changes of the matrix, the apparent red-shifted optical absorptions for the nanocomposites were observed as compared to the parent monolithic silica, particularly with increase in palladium loading and calcination temperature.     

非保守圆薄板的轴对称振动和稳定性

建立了受切向均布随从力作用的圆薄板在面内周边可移、不可移两种情况下的轴对称控制方程，用打靶法直接导出求解变系数常微分方程特征值问题数值解的计算式．通过数值计算，给出了周边可移、不可移的简支、固支圆板自振频率和临界载荷的特征曲线以及相应的临界发散载荷，并分析了泊松比对圆板自振频率和临界载荷的影响．     

SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION

A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane.     

结构模态参数的时序分析(ARMAV模型)识别法

本文简述了用时间序列分析(ARMAV 模型)识别结构模态参数的原理,对建模方法进行了分析,并对建模分析中至关重要的初值选择问题进行了讨论,提出了一种有效的初值的选取方法;在模拟计算部分中,用 Wilson-θ积分法模拟了一个三个自由度的振动和低信噪比、大阻尼振动和密集模态等复杂情形,对用时序方法(ARMAV 模型)识别模态参数的能力进行了检验;最后通过对实验数据进行有效的预处理后,用时序方法(ARMAV 模型)识别出一个真实结构(圆盘)的第一、二阶模态参数,并得到结构的完整振型.     

粘弹性基支粘弹板轴对称问题的动力响应

本文讨论粘弹性半空间地基上粘弹性圆板受轴对称载荷时的动力响应,将问题化为在Laplace变换空间中的第一类Fr积分方程,通过数值解和进行数值逆变换求得问题的解答。     

论庞加莱-契达耶夫方程

研究表明：庞加莱－契达耶夫正则方程是非正则变量下相当普遍的哈密顿方程．这表明，多余坐标下的广义拉格朗日方程和广义哈密顿方程（其阶数低于带有不定乘子的方程），以及准坐标下的欧拉－拉格朗日方程，都是庞加莱－契达耶夫方程的特殊情况；从而，可将其理论推广到上述系统．而且还研讨了庞加莱－契达耶夫方程在非完整系动力学中的应用问题．     

白洋淀内水体的流动特征研究

研究了风对白洋淀内水体循环流动的影响，研究指出：(1)风应力可看作是水体循环 的主要驱动力. (2)在风应力的作用下，水体表层的流动主方向与风的方向一致，下层水体 的流动方向与表层方向相逆或近似相逆. (3)表层以下水体流动复杂，次表层水平流动有明 显的双涡结构. (4)淀底地形对水体垂向流动影响很大，垂向速度变化复杂，垂向上有双涡 流动现象. 从动力学角度研究了淀内水体流动的情况.