Solid-state NMR spectra of paramagnetic silica-based materials: observation of 29Si and 27Al nuclei in the first coordination spheres of manganese ions

Some silica-based solids, prepared by the sol/gel method in the presence of high Mn2+ concentrations, have been characterized by the 29Si, 27Al MAS NMR spectra and 29Si T1 measurements. The single-pulse 29Si and 27Al MAS NMR spectra have shown broad spinning sideband patterns that are interpreted in terms of anisotropic bulky magnetic susceptibility (BMS) and dipole-field effects. In the absence of paramagnetic isotropic shifts, the 29Si and 27Al nuclei observed in the single-pulse NMR spectra have been assigned to nuclei remote from paramagnetic centers. It has been demonstrated that the 29Si and 27Al nuclei, which are in the vicinity of the manganese ions, can be detected by the Hahn-echo MAS NMR experiments at different carrier frequencies.     

(27)Al NMR and Raman spectroscopic studies of alkaline aluminate solutions with extremely high caustic content - Does the octahedral species Al(OH)(6)(3-) exist in solution?

²⁷Al NMR and Raman spectra of alkaline aluminate solutions with 0.005 M ≤ [Al(III)]_T ≤ 3 M in various M′OH solutions (M′⁺ = Na⁺, K⁺ and Li⁺) were recorded and analysed. Caustic concentrations up to 20 M were used to explore whether higher aluminium hydroxo complexes are formed at extremely high concentrations of hydroxide. A single peak was observed on the ²⁷Al NMR spectrum of each solution. The chemical shift of this peak shifts significantly upfield with increasing [M′OH]_T in solutions with [Al(III)]_T < 0.8 M. This variation shows a strong dependence on the cation of the solution and practically disappears in systems with [Al(III)]_T ≥ 0.8 M. For Raman spectra of solutions with [Al(III)]_T = 0.8 M and [NaOH]_T ≥ 10 M, the peak maximum of the symmetric ν₁-AlO₄ stretching of Al(OH)₄⁻ shifted progressively from ∼620 to ∼625 cm⁻¹ and decreased in intensity with increasing [NaOH]_T. In parallel, modes centred at ∼720 and ∼555 cm⁻¹ (cf. ∼705 and ∼535 cm⁻¹ at lower [NaOH]_T, ascribed to a dimeric aluminate species appeared, and their intensities increased with increasing [NaOH]_T. These variations in the ²⁷Al NMR and Raman spectra can be interpreted in terms of contact ion-pairs formed between the cation of the medium and the well-established Al(OH)₄⁻ or the dimeric aluminate species. Assumption of higher aluminium hydroxo complex species (e.g., Al(OH)₆³⁻) is not necessary to explain the spectroscopic effects observed.     

Aluminium speciation in environmental samples: a review

Because of its toxic effects on living beings, Al may represent an environmental hazard, particularly under increased acidic conditions. Growing environmental concern over the presence of increased Al concentrations in soil solutions and fresh waters resulted in the development of numerous analytical techniques for the determination of Al species. Al has a very complex chemistry that is significantly influenced by pH. Different Al species are present in environmental solutions, and many of them are unstable. Contamination of samples and reagents by extraneous Al represents an additional problem in speciation of Al at trace concentrations. Due to these reasons quantitative determination of particular chemical forms of Al is still a very difficult task for analytical chemists. The most important analytical methodologies of the last decade and new trends for the speciation of Al in environmental samples are comprehensively reviewed here.     

基于MCMC模拟方法的带变点的NHPP软件可靠性模型

本文主要讨论软件测试过程中NHPP模型参数发生变化的情形,并用Bayes方法对GGO模型进行变点分析,运用基于Gibbs抽样的MCMC方法模拟出参数后验分布的马尔科夫链,最后借助于BUGS软件包对软件故障数据集Musa进行建模仿真,其结果表明该模型在软件可靠性变点分析中的直观性和有效性。     

La^p（M）空间及其嵌入性质

引进一类新的Banaeh函数空间La^p（M）,并讨论了La^p（M）空间的嵌入性质,得到La^p（M）空间可以成为相对La^p空间较大的空间Bloch空间和La^p空间的中间空间．     

On corepresentations of multiplier Hopf algebras

We present a general construction producing a unitary corepresentation of a multiplier Hopf algebra in itself and study RR-corepresentations of twisted tensor coproduct multiplier Hopf algebra. Then we investigate some properties of functors, integrals and morphisms related to the categories of the crossed modules and covariant modules over multiplier Hopf algebras. By doing so, we can apply our theory to the case of group-cograded multiplier Hopf algebras, in particular, the case of Hopf group-coalgebras.     

The Hyers-Ulam stability of a functional equation deriving from quadratic and cubic functions in quasi-��-normed spaces

In this paper, we investigate the Hyers-Ulam stability of the following function equation 2f（2x ＋ y） ＋ 2f（2x - y） = 4f（x ＋ y） ＋ 4f（x - y） ＋ 4f（2x） ＋ f（2y） - Sf（x） - 8f（y） in quasi-β-normed spaces.     

A characterization of some weighted inequalities for the vector-valued weighted maximal function

We give in this paper a necessary and sufficient condition of weighted weak and strong type norm inequalities for the vector-valued weighted maximal function.     

扰动Fej\'{e}r点上复Hermite插值的联合逼近

$D$是复平面中由闭Jordan曲线$\Ga$围成的单连区域. 考虑在$\Ga$上扰动Fej\''er点的 Hermite插值一致逼近、平均逼近和联合逼近于函数$f\in A^{(q)}(\o D)$. 该文中的逼近阶一般说来是不可再改进的, 区域的边界限制条件到目前为止是最少的. 以往的全部同类结果都包括在该文中作为特殊情形, 由于该文方法上的改进, 简化和省去了以往 某些证明过程.     

壳聚糖-纳米金复合膜修饰电化学发光免疫传感器检测人免疫球蛋白G

利用壳聚糖与纳米金良好的生物相容性及蛋白固定能力,制备了兼具导电性和透光性的人免疫球蛋白G(IgG)修饰膜,用于修饰玻碳电极,研制了新型电化学发光免疫传感器,并通过扫描电镜(SEM)及交流阻抗技术(EIS)考查了传感器表面性质.基于竞争免疫分析模式,以Ru(bpy)32+标记的羊抗人IgG为发光示踪物,采用新型共反应剂二丁基乙醇胺(DBAE)对光信号进行放大,建立了人IgG的检测方法,线性范围20ngmL-1～1.0μgmL-1,检测限6.5ngmL-1.将该电化学发光传感器应用于人血中IgG的检测,结果令人满意.