直接法共聚改性聚乳酸研究新进展

聚乳酸(PLA)是一种重要的生物降解材料.广泛应用于生物医学、纤维、塑料等领域.为了改善PLA的性能,人们进行了大量的共聚改性研究.其中,直接从乳酸出发不经丙交酯中间体路线的共聚改性方法,因其简单易行、经济实用,越来越引起科学家的重视.针对直接法共聚改性聚乳酸物中物质种类的不同,结合本课题组的一些乳酸直接熔融共聚研究工...     

X射线荧光分析钒钛铁矿中主次量元素

四硼酸锂为熔剂 ,硝酸锂为氧化剂防止硫元素挥发损失 ,溴化锂作脱模剂 ,玻璃熔片法制备样品。干扰曲线法结合理论α系数法对谱线重叠干扰和基体效应进行校正 ,建立了 XRF测定钒钛铁矿中 Mg,Al,Si,P,S,Ca,Ti,V,Mn,TFe等主次量元素的分析方法。该方法经标准样品验证 ,与推荐值符合较好。 10次制样测量各组分 RSD在 0 .2 7%— 5 .2 4 %范围内     

反应性单体改性PP/PS共混物结晶与熔融行为

制备了三种反应性单体和两种PP接枝物改性的PP／PS共混物,用DSC研究了改性PP／PS共混物的结晶与熔融行为。结果表明：PS的加入提高了PP的结晶温度,两种接枝物的加入进一步提高共混物中PP的结晶温度,少量反应性单体对结晶温度影响不大,但高用量时则明显提高共混物的结晶温度;外加接枝物或者反应性单体对共混物中PP的熔融温度影响不大,但是熔融峰形与结晶温度高低有关。     

熔融盐(LiNO3)强制对流换热实验

由于熔融盐使用温度高、热稳定性和传热性能好,被认为是太阳能塔式发电系统和新一代槽式发电系统中最有前途的传热蓄热介质之一.本文通过搭建高温熔融盐传热试验台,成功实现了 LiNO3熔融盐与导热油的强制对流换热试验循环,得到了总的对流换热系数,初步得到了在旺盛紊流区熔融LiNO3在不同雷诺数下对应的努塞尔数.     

Effects of Vacuum on Fused Silica UV Damage

Damage points induced by 355 nm laser irradiation increase more quickly on the surface of fused silica in vacuum of about 10^-3 Pa than in atmospheric air at the same fluence. The larger concentration of point defects in vacuum is confirmed by photoluminescence intensity. X-ray photoelectron spectroscopy and infrared absorption indicate the formation of sub-stoichiometric silica on the surface. The degradation mechanism of fused silica in vacuum is discussed.     

基于光纤耦合器的声发射传感器

为检测变压器内局部放电产生的声发射信号,介绍了一种基于特殊光纤熔融拉锥耦合器型声发射传感器。它是利用声波引起的扰动改变耦合器两臂光功率输出的特点来检测声发射信号。实验结果表明：此种传感器在10kHz～250kHz范围内对声发射信号有良好响应,在155kHz灵敏度为5.6×10^-6V/Pa,噪声为1.8Pa声压,有望在复合材料与结构、电力无损检测方面得到应用。     

Infrared Femtosecond Laser Direct-Writing Digital Volume Gratings in Fused Silica

We demonstrate that digital volume gratings can be fabricated in fused silica glass conveniently by direct femtosecond laser writing. The diffraction efficieneies of volume gratings can be essentially modulated by simply stacking and offsetting the unit structure. A series of volume gratings, which have the pitches of 5 μm and the size of 1 mm × 1 mm, have been fabricated with the writing speed of 500μm/s, with which the processing period of each grating layer could be reduced to several minutes with a 1-kHz femtoseeond laser system. Results show that the power spectrum of the diffracted waves of the volume gratings are dependent on the layer gap and layer offsetting.     

Fabrication of Optical Fiber Bragg Grating Assisted Mismatched Coupler

We report the fabrication of an optical fiber Bragg grating assisted mismatched coupler based on the fused biconical tapered technology. The investigation of the spectrum properties shows that the coupler has a good filtering property. The drop filtering efficiency as much as 94.2% at 1553.5nm is achieved. Furthermore, using the fabricated coupler, a wavelength de-multiplexing transmission experiment is carried out in a 10Gbps system with NRZ optical signals. Experimental results show that the coupler basically realizes the function of wavelength de-multiplexing.     

Ce3+/Tb3+/Sm3+共掺CaO-B2O3-SiO2玻璃的光学性能调控

采用高温熔融法制备了Ce³⁺/Tb³⁺/Sm³⁺掺杂的CaO-B₂O₃-SiO₂（CBS）发光玻璃。通过傅利叶红外光谱仪、荧光光谱仪表征了该系列发光玻璃的微观结构和发光性质,并对Ce³⁺到Tb³⁺、Ce³⁺到Sm³⁺之间的能量传递机制进行了研究。结果表明,在339,378,407 nm激发下,单掺Ce³⁺、Tb³⁺和Sm³⁺的CBS玻璃分别发射紫蓝光、绿光和红光,恰好符合混合合成白光的条件。Ce³⁺/Tb³⁺和Ce³⁺/Sm³⁺双掺CBS玻璃的发射光谱以及Ce³⁺衰减寿命的变化证实了Ce³⁺→Tb³⁺和Ce³⁺→Sm³⁺之间存在能量传递,随Tb³⁺和Sm³⁺浓度增加,Ce³⁺的寿命减小,且传递效率由5.4%和5.7%分别增加至24.0%和27.1%。调节3种稀土离子的掺杂浓度并选择合适的激发波长,实现了发光颜色可调,并最终获得白光发射。     

链缠结对高聚物热转变行为的影响

用冷冻升华方法,由等规聚苯乙烯、聚环氧乙烷的稀溶液制备单链、寡链附聚粒子．附聚粒子的热分析表明,冷结晶温度降低、结晶速度加快、晶体增厚明显．这些结果是因为附聚粒子没有或有很少链间缠结．附聚粒子形成较小尺寸的晶体,因而熔点较低,相应的热结晶温度移向低温．在平衡熔点以上放置短时间,链相互贯穿、缠结,又回复到本体的熔融、结晶行为