同位素稀释气相色谱-质谱法测定茶叶中5种杀菌剂残留

建立了使用固相萃取-气相色谱/质谱联用结合同位素稀释技术准确测定3种茶叶(红茶、绿茶和普洱茶)中敌菌丹、克菌丹、灭菌丹、百菌清和苯氟磺胺等杀菌剂农药残留的新方法。茶叶试样中加入同位素内标D6-克菌丹,经乙腈匀浆提取,提取液离心后取上清液经Forisil固相萃取柱浓缩、净化。GC-MS采用选择离子监测(SIM)模式进行定性定量分析,内标法定量。方法的添加回收率为74.1%～100.6%;相对标准偏差为1.2%～12%;6种农药的检出限为0.002～0.14μg/mL。     

Octupole deformation for Ba isotopes in a reflection-asymmetric relativistic mean-field approach

The potential energy surfaces of even-even 142-156Ba are investigated in the constrained reflectionasymmetric relativistic mean-field approach with parameter set PK1. It is shown that for the ground states, 142Ba is near spherical,156Ba well quadrupole-deformed, and in between 144-154Ba octupole deformed. In particular, the nuclei 148,150Ba with N=92, 94 have the largest octupole deformations. By including the octupole degree of freedom, energy gaps N = 88, N = 94 and Z = 56 near Fermi surfaces for the singleparticle levels in 148Ba with β2 ～ 0.26 and β3 ～ 0.17 are found. Furthermore, the performance of the octupole deformation driving pairs （ν2f7/2, ν1i13/2） and （π2d5/2, π1h11/2） is demonstrated by analyzing the singleparticle levels near Fermi surfaces in 148Ba.     

Quasi-Classical Trajectory Study on Ar＋H2＋/D2＋/T2＋ Reactions

In order to explore the isotope effect on stereo dynamics, we investigate the trajectory calculations of Ar＋H2＋/D2＋/T2＋ and Ar＋T2＋ reactions on the ab initio potential energy surface constructed by us and calculate the distributions of product polarization P（θr）, P（r） and four generalized polarization-dependent differential cross-sections. The product rotational alignment parameters （P2（j＇ · k）） for the title reactions are compared and discussed with mass factors. Furthermore, the angular distributions of the product rotational vectors in the form of polar plot in θr and r are presented. The results indicate that the stereo dynamics properties of the title reactions are sensitive to the mass factor.     

碰撞能和同位素取代对H+BrF→HBr+F反应立体动力学影响的理论研究

基于拟合得到的London-Eyring-Polanyi-Sato势能面,运用准经典轨线方法对H+BrF→HBr+F反应的立体动力学性质进行了理论研究.计算了反映矢量相关的角分布和对光诱导的双分子反应实验敏感的四个极化微分散射截面.结果表明:随着碰撞能的增加,产物的转动极化变强,并且产物的后向散射占主导地位.通过比较D+BrF→DBr+F和H+BrF→HBr+F反应的产物极化,揭示了明显的同位素效应.     

强激光场中氘团簇的离子能谱与团簇尺度

在SILEX-Ⅰ装置上进行了超短超强激光与氘团簇相互作用的实验。采用法拉第筒测量了激光与氘团簇靶相互作用后发射出的氘离子能谱,并根据氘离子能谱计算出氘团簇的尺寸和分布。由于激光预脉冲的影响,得到了团簇的尺度比瑞利散射测量的结果小。这些结果对团簇源制备系统的改进和优化激光打靶有着重要的参考意义,而且可以为团簇尺度的测量提供一种新的方法。     

飞秒强激光场中异核团簇的爆炸动力学

 利用Bathe过势垒模型,对飞秒强激光场中异核分子团簇((CH₄)_n,(CD₄)_n,(D₂O)n）的爆炸动力学过程进行了理论研究。结果表明:异核团簇爆炸后产生的离子能量与团簇初始半径的平方呈线性关系,爆炸机理为典型的库仑爆炸。研究发现,异核分子团簇发生库仑爆炸后的氘离子能量高于飞秒强激光和单核的(D)>)_n团簇相互作用后产生的氘离子能量,显示异核团簇中高Z元素电离后产生的高价离子对低Z元素离子有很强的加速作用。     

α粒子散射对爆炸物检测时间分辨的影响

对爆炸物检测中伴随α粒子技术的时间谱进行了研究,建立了一套基于伴随α粒子技术的时间谱测量装置,分析了影响时间谱分辨的若干因素。采用60μm厚的铜箔设计了一个锥形准直筒对散射的α粒子进行屏蔽,以500 g尿素为样品测量了α-γ符合时间谱。结果表明,α粒子在靶室内壁的散射是影响时间谱分辨的重要因素,锥形准直筒抑制了与α散射相关中子产生的γ射线,提高了α-γ符合时间谱的分辨。在有无锥形准直筒的条件下,符合时间谱特征瞬发峰γ的半高宽分辨力分别为1.8 ns和6.4 ns。分辨力高的时间谱可用于获取爆炸物样品的特征瞬发γ能谱。     

压缩氘氚球的热核燃烧特性研究

本文利用LARED-S程序模拟了等密度和等压力条件下压缩氘氚球的热核反应燃烧过程.对于等密度模型,模拟了两个具体算例,与国外计算结果进行了比较,验证了程序的可靠性.对于等压力模型,利用数值模拟给出了热核反应燃烧与压缩氘氚球初始状态之间的关系曲线,分析发现,氘氚装量、压力和主燃料密度的增加有利于提高热核反应放能和燃耗,中心热斑的温度和面密度分别达到70—80 MK和3—4 kg·m^-2时热核反应才有显著的放能,提高主燃料密度,可以适当放宽对中心热斑的点火要求.最后对实际点火靶进行了数值模拟并且与等压力模拟计算结果进行了比较分析.     

Impact Parameter Dependence of the Double Neutron/Proton Ratio of Nucleon Emissions in Isotopic Reaction Systems

Within the transport model IBUU04, we investigate the double neutron/proton ratio of free nucleons taken from two reaction systems using two Sn isotopes at a beam energy of 50 MeV/nucleon and with impact parameters 2fm, 4fm and 8fm, respectively. It is found that the double neutron/proton ratio from peripheral collisions is more sensitive to the density dependence of the symmetry energy than those from mid-central and central collisions.