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991.
复合结构剪切板的屈曲与后屈曲研究 总被引:11,自引:0,他引:11
基于Reissner剪切板理论,本文将现有理论模型推进了一步,导出了控制复合材料和构造矩形板平衡的广义Karman大挠度方程。此外,运用摄动技术,构造了一个单向压缩简支剪切矩形板的后屈曲渐近解,适用于面板和夹心材料都具正交各向异性的夹层板以及计及横向剪切变形对称铺设的层合板。文中给出了典型算例,并将当前结果与其它理论或数值解作了比较,显示出相当好的一致性。 相似文献
992.
沿海软粘土取土质量的对比分析 总被引:2,自引:0,他引:2
本文在简要介绍固定活塞式薄壁取土器取土技术基础上,详尽分析了在连云港、赤湾港和广深路所进行的软粘土取土技术对比试验结果。试验结果表明,土样扰动对于室内所测定的力学性指标影响极大,但对物理性指标影响不大。研究结果还有力地证明,只要操作正确,采用薄壁取土器能取得高质量土样,而采用敞口式厚壁取土器取出的土样扰动较大。 相似文献
993.
应用固载表面毛细流自组装环荧光显微成像技术,建立了Ca2+增敏米诺环素荧光体系测定牛奶中米诺环残留量的分析方法。将米诺环素溶液与一定量的氯化钙溶液,pH 8.50的氨性缓冲溶液及PVA-124溶液充分混合均匀。反应10 min后,滴在疏水性载玻片表面上,微波加热,溶剂受热挥发后,形成直径约为1.7 mm,环带宽约为45.3μm的自组装环。当点样体积为0.3μL时,线性范围为5.6×10-13~1.8×10-11mol,方法的检出限(3σ)为5.6×10-14mol。应用于米诺环素胶囊中米诺环素和牛奶中残留米诺环素的检测,回收率分别为104.3%~105.0%和96.0%~105.9%,相对标准偏差(n=5)小于3.5%。 相似文献
994.
李志梅 《理化检验(化学分册)》2010,(4)
<正>砷为毒性元素,监测聚合氯化铝净水剂中砷的含量对保证水厂出厂水中砷的含量不超标至关重要。聚合氯化铝中砷的测定方法报道较少,大多数都是食品及药品中砷的测定方法报道。现行国家标准GB 15892—2003中砷斑法是半定量法, 相似文献
995.
996.
Oxidative dehydrogenation of propane under steady-state and transient regimes over alumina-supported catalysts prepared from mixed V_2W_4O_(19)~(4-) hexametalate precursors 下载免费PDF全文
Sébastien Paul Elise Berrier Marcia Cristina Kaezer Frana Jean-Guillaume Eon 《天然气化学杂志》2010,19(2):123-133
An integrated approach combining the development of an innovative catalyst and the research of a set of adequate operating conditions for the propane oxidative dehydrogenation (ODH) is described. The experimental set-up, specially designed for steady-state and transient studies is presented. The preparation method, the characterization and the performances in steady-state and transient regimes of catalysts based on V_2W_4O_(19)~(4-) Lindqvist isopolyanion used as a precursor and supported on alumina are reported. The influence of the preparation method of the catalyst and the role of water in the feed gas are more particularly discussed. 相似文献
997.
Mixed ammonium-transition metal salts with formula of (NH4)xMyHzPMo12O40 (M = Ni2+, Co2+ or Fe 3+) denoted as MPMo12 have been investigated for the oxidation of propane, with molecular oxygen, at temperature range between 380℃ and 420℃ after in-situ pre-treatment performed at two heating rate of 5 or 9℃/min. They were characterized by BET method, XRD, UV-Vis and IR techniques. The catalysts were found to be active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-t... 相似文献
998.
Tetrahydrofuran (THF) hydrate was formed in bulk as well as in glass beads pack with a mean diameter of 3.0 mm by controlling the temperature under ambient pressure. Images of THF hydrate formation procedure were obtained using the magnetic resonance imaging (MRI) technique. The experiment results showed that MRI is an effective method for the detection of hydrate formation. Saturation of hydrate formed both in bulk and glass beads can be confirmed by intensity integration of MRI images. 相似文献
999.
The plasma technology served as a tool in unconventional catalysis has been used in natural gas conversion, because the traditional catalytic methane oxidative coupling reaction must be performed at high temperature on account of the stability of methane molecule. The focus of this research is to develop a process of converting methane to C2 hydrocarbons with non-equilibrium plasma technology at room temperature and atmospheric pressure. It was found that methane conversion increased and the selectivity of C2 hydrocarbons decreased with the voltage. The optimum input voltage range was 40-80 V corresponding to high yield of C2 hydrocarbons. Methane conversion decreased and the selectivity of C2 hydrocarbons increased with the inlet flow rate of methane. The proper methane flow rate was 20-40 ml/min (corresponding residence time 10-20 s). The experimental results show that methane conversion was 47% and the selectivity of C2 hydrocarbons was 40% under the proper condition using atmospheric DBD cold plasma technology. It was found that the breakdown voltage of methane VB was determined by the type of electrode and the discharge gap width in this glow discharge reactor. The breakdown voltage of methane VB,min derived from the Paschen law equation was established. 相似文献
1000.