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51.
Chen Youcun Liu Guangxiang Xu Heng Zhou Hong Ren Xiaoming 《Russian Journal of Coordination Chemistry》2003,29(4):251-255
Two complexes [PyH][Ni(Mnt)2] (I) and [QlH][Ni(Mnt)2] (II) (Mnt2– = maleonitriledithiolate, [PyH]+ = pyridinium, [QlH]+ = quinolinium) were synthesized and characterized by elemental analysis and IR spectra. ESR spectra of polycrystalline samples collected at room temperature are isotropic with g = 2.039 for Iand anisotropic with g
z = 1.997, g
y g
x = 2.102 (g
av = 2.068) for II. The magnetic susceptibility data of I and II have been measured in the temperature range of 2–300 K. The results obtained suggest the antiferromagnetic coupling interactions between neighboring Ni3+ ions for I and ferromagnetic coupling interactions for II, respectively. Based on the crystal structure analysis of I, the magnetic properties of two complexes were discussed. 相似文献
52.
Wanghua Xu 《大学化学》2020,35(2):135-139
Through the analysis of several valuable chemical contest problems, the students' spatial visualization and divergent thinking abilities were improved, and the teaching's advice was provided. 相似文献
53.
在状态空间是可数情形下,本文给出了时间随机环境下随机游动的一个一般模型.随后,在环境是独立同分布情形下得到了直线上时间随机环境下紧邻随机游动的一个常返与暂留准则和强大数定律;最后讨论了其中心极限定理,它类似与简单随机游动的相应结果. 相似文献
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PbS nanotubes were synthesized by the tiny water channels in bicontinuous microemulsions consisted of p-octyl polyethylene glycol phenylether (OP)/n-amyl alcohol/cyclohexane/water. The possible formation mechanism of PbS nanotubes is also discussed based on their shape evolutions. The results indicate that the formation of PbS nanotubes is probably via the process of the nucleation, growth, assemblage and crystallization. 相似文献
56.
A novel compound [(IBz)2Im](TCNQ) [(IBz)2Im=1,3-bis(4-iodobenzyl) imidazole cation, TCNQ-=7,7,8,8-tetracyanoquinodimethanide anion] was synthesized by the reaction of [(IBz)2Im]Br and LiTCNQ in CH3OH and its structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/c with a=1.147 35(18) nm, b=2.028 1(3) nm, c=1.264 1(2) nm, β=104.73(0)°, V=2.666(65) nm3, Z=4, C29H19I2N6, Mr= 705.30, Dc=1.757 g·cm-3, R1=0.053 2 and wR2=0.111 2. The structure analysis shows that the anions are stacked into column with isolated π-dimers, and there is one type of TCNQ entries (TCNQ-), in agreement with the IR spectra analysis of the compound. The most prominent structural features are the completely segregated stacking columns of the TCNQ-anions and [(IBz)2Im]+ cations. CCDC: 759523. 相似文献
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59.
利用非线性最小二乘法拟合在CCSD(T)/aug-cc-pVQZ理论水平下计算的相互作用能,得到了基态Ne-HBr复合物相互作用势的解析表达式.基于拟合的从头算CCSD(T)势,通过收敛的密耦计算得到了入射能量分别为40,60,80和100 meV时,Ne-HBr散射的微分截面和分波截面,详细讨论了态-态转动激发截面对总非弹性散射截面的影响和散射截面随能量的变化趋势.希望研究结果对该体系的散射实验和进一步的理论研究能提供参考信息. 相似文献
60.
Partial Wave Cross Sections for Collisions between Helium Atoms and Hydrogen Halide Molecules 总被引:5,自引:0,他引:5
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The close-coupling method is utilized to calculate partial cross sections for elastic and inelastic scattering of He atoms with HX (X=F, Cl, Br) molecule based on the CCSD (T) potential energy surfaces obtained in the previous research. The calculation is performed at the incident energy of 200 me V. The rationality of our results has been confirmed by comparison with the available theoretical results. The tendency of the elastic and inelastic rotational excitation partial wave cross sections varying with the reduced mass of the three systems is obtained. 相似文献