Synthesis and Characterization of Model Complexes of Catechol Dioxygenases Supported by the Anionic Hydrotris-3,5-dimethyl-pyrazolylborate Ligand

An iron(Ⅲ) complex [FeIII(TpzMe2)(HpzMe2)Cl2](1) has been synthesized at a low temperature,which contains tripodal ligand,namely,the anionic hydrotris-3,5-dimethyl-pyrazolylborate(TpzMe2). A series of iron(Ⅲ) catecholate complexes 2―5 has been obtained via the reaction of compound 1 with catecholate or substituted catecho-lates. These complexes were characterized by X-ray crystallographic analysis,mass spectrometry and elemental analysis,and the results show that TpzMe2 ligand has the beneficial effect on t...     

一致凸模糊映射及其有关性质

讨论了模糊映射的一致凸性及其有关性质,给出了模糊映射为一致凸的几个判别准则,并得到了可微一致凸模糊映射在某一点达到最小值的充分条件.     

计算非负不可约矩阵Perron根的对角变换(英文)

计算非负矩阵Perron根一般通过矩阵的对角变换,但是有的时候是不可行的.本文为非负不可约矩阵的计算给了一列对角变换.此种变换对所有的非负不可约矩阵实用,并且方便计算,最后给出了数值例子.     

二茂铁基功能化的氮杂环卡宾银配合物的合成及催化活性

通过N-二茂铁基甲基-N-吡啶基甲基咪唑盐与氧化银在相转移催化条件下反应, 合成了4个二茂铁基功能化的氮杂环卡宾银配合物(NHC)₂AgX(X=PF₆或BF₄), 并利用NMR及X-射线单晶衍射对其结构进行了表征. 在这4个化合物中, 银为二配位结构, 吡啶氮原子并未参与配位. 催化活性测试结果表明, 合成的4个化合物具有高的催化炔、 醛和胺三组分偶联反应活性.     

Constructing infinite sequence exact solutions of nonlinear evolution equations

To construct the infinite sequence new exact solutions of nonlinear evolution equations and study the first kind of elliptic function, new solutions and the corresponding Bäcklund transformation of the equation are presented. Based on this, the generalized pentavalent KdV equation and the breaking soliton equation are chosen as applicable examples and infinite sequence smooth soliton solutions, infinite sequence peak solitary wave solutions and infinite sequence compact soliton solutions are obtained with the help of symbolic computation system Mathematica. The method is of significance to search for infinite sequence new exact solutions to other nonlinear evolution equations.     

基于碘化银固定相的薄层色谱-红外光谱联用研究

在分析复杂混合物方面原位薄层色谱-红外光谱联用有巨大潜力,二者联用能够相互取长补短,极大地提高对复杂混合物的解析能力。但因固定相自身的红外吸收能够对样品的检测造成干扰,使该方法进展缓慢。实验应用对中红外光透明的碘化银纳米微粒作为固定相制备薄层层析板,并对碘化银薄层板的层析效果及原位红外光谱检测的可行性进行了初步的研究。通过正交设计实验法优化反应条件,制备出粒径为100 nm左右的碘化银颗粒;应用沉降-挥发法制备薄层层析板,实验表明该薄层板具备分离混合物的能力,且原位红外光谱检测结果表明碘化银作为固定相不干扰样品检测。     

Charge pumping in nanotube filled with electrolyte

Charge transport in nanotube filled with an incompressible viscous electrolyte is considered. The flow is induced by elastic soliton wave in the nanotube wall. The soliton appears as an axisymmetric local deformation of the wall boundary propagating along the length of a nanotube. The Stokes approximation is used for the flow. As for the charge transport, different factors (identical charges repulsion, diffusion, convection) are taken into account. Picture of the streamlines and charge distribution are described. We estimate a value of charge transported by single solitary wave.     

Temperature and hydrogen-like impurity effects on the excited state of the strong coupling bound polaron in a CsI quantum pseudodot

With hydrogen-like impurity(HLI) located in the center of Cs I quantum pseudodot(QPD) and by using the variational method of Pekar type(VMPT), we investigate the first-excited state energy(FESE), excitation energy and transition frequency of the strongly-coupled bound polaron in the present paper. Temperature effects on bound polaron properties are calculated by employing the quantum statistical theory(QST). According to the present work's numerical results, the FESE, excitation energy and transition frequency decay(amplify) with raising temperature in the regime of lower(higher)temperature. They are decreasing functions of Coulomb impurity potential strength.     

利用GEANT4和FLUKA研究质子诱发散裂反应出射中子双微分截面

在中高能质子诱发散裂反应相关核工程设计中,可靠的蒙特卡罗模拟程序结合核反应理论模型具有较好的理论指导意义。本工作中,利用GEANT4耦合INCL4和ABLA理论模型以及FLUKA耦合PEANUT模型模拟计算了几百MeV至几个GeV质子轰击Be,Al,Fe,W,U等靶后30°,60°,120°,150°出射角产生的散裂中子双微分截面,并与现有实验数据进行了比较。结果发现,FLUKA和GEANT4模拟计算较好地再现了Al,Fe,W,U等靶实验测量数据。然而,模拟结果明显低估了Be靶出射中子能量小于10 MeV能区的实验数据。For the design of nuclear engineering related with medium-high energy proton induced spallation reaction,the reliable Monte Carlo simulation codes coupled with nuclear reaction models have a good theoretical guidance.In this work,the production spallation neutron double differential cross sections at 30°,60°,120°,150°emission angle for Be,Al,Fe,W,U target materials at incident proton energies between several hundred MeV and GeV are theoretically calculated by using the GEANT4 coupled INCL4 and ABLA,and the FLUKA coupled PEANUT.The calculated results were compared with the available experimental data.It is found that the GEANT4 and FLUKA calculations well reproduced the experimental measurement of Al,Fe,W,U target materials.However,calculations obviously underestimated the emission neutrons of Be target for lower than 10 MeV energy range.     

Interactions of charged particle beams with double-layered two-dimensional quantum electron gases

We investigate the interactions of external charged particles with a double-layered two-dimensional quantum electron gas (2DQEG), describing its collective or plasmon excitations by using the linearized quantum hydrodynamic (QHD) model. General expressions are derived for electron densities in the two layers, the induced potential, and the stopping and image forces on an external charged particle. Our calculations indicate that an oscillatory wake effect arises in the induced potential for a particle moving parallel the 2DQEG layers. In addition, double peaks are found in the stopping and image forces due to plasmon hybridization between the two 2DQEG layers. Finally, the induced number density in the double-layered 2DQEG is compared with the case of a single-layer 2DQEG supported by an insulating substrate.