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31.
32.
《Tetrahedron: Asymmetry》2006,17(19):2726-2729
Several thioaryl- and phosphino-phosphoramidite ligands have been synthesized from commercially available β-aminoalcohols. This new family of bidentate ligands are highly active in the enantioselective copper-catalyzed conjugate addition of diethylzinc to both cyclic and acyclic enones showing moderate to good enantiomeric excesses of up to 81%. 相似文献
33.
《Physica A》2006,362(1):42-47
We present the numerical results of simulations of complex fluids under shear flow. We employ a mixed approach which combines the lattice Boltzmann method for solving the Navier–Stokes equation and a finite difference scheme for the convection–diffusion equation. The evolution in time of shear banding phenomenon is studied. This is allowed by the presented numerical model which takes into account the evolution of local structures and their effect on fluid flow. 相似文献
34.
《Solid State Ionics》2006,177(13-14):1129-1135
The conductivity of acceptor-doped LaNbO4 has been investigated in the temperature range 300 to 1200 °C as a function of the oxygen pressure and water vapor pressure by means of impedance spectroscopy and EMF measurements. The conductivity is predominantly ionic below 800 °C in air and for higher temperatures under reducing conditions. Protons are the major ionic charge carrier in the presence of water vapor. A maximum in proton conductivity of ∼ 0.001 S/cm was obtained at 950 °C in atmospheres containing ca 2% H2O. At high temperatures (> 1000 °C) under oxidizing conditions, electron hole conduction prevails. The conductivity has been modeled assuming that oxygen vacancies and protons compensate the acceptor doping. Transport coefficients describing mobility of defects and thermodynamic constants for the incorporation of protons have been derived. 相似文献
35.
Spectroscopy Investigation on Conformational Transition of Tea Glycoconjugate from Green Tea 总被引:5,自引:0,他引:5
The conformational transition of a new glycoconjugate, tea glycoconjugate (TGC), was investigated by spectroscopy techniques including circular dichroism (CD) and ultraviolet (UV) spectroscopy. The solution behaviors of TGC in the mediums of different temperature, pH value, and ions were compared. Results showed that the native conformation of TGC was partially ordered. The CD value and UV absorbance of TGC altered with the change of pH value, temperature, the addition of ions, and also accompanied order-disorder transition. Especially the conditions with temperature higher than the glass transition temperature (Tg=62℃), higher pH value or lower pH value will have the most impact on the conformation of TGC, which will destroy the hydrogen bonds between the TGC molecules. The results indicated that the outside factors play important roles on the stability of the conformation of TGC. 相似文献
36.
IntroductionRecently ,thecompoundscontaining 1H 1,2 ,4 tria zolegrouphaveattractedmuchinterestbecausetheyex hibitsomefungicidalactivity ,plantgrowthregulatingac tivity ,1antibacterialactivityagainstPucciniareconditeandrootsgrowthregulationforcucumber .2 Also ,suchcom poundsareincreasinglybeingstudiedbecauseofthecoor dinationchemistryoftriazolesactingasligandsintransi tionmetalcompounds .Asamatteroffact ,thetriazolederivativeshavebeenextensivelyusedasterminalandbridgingligands ,andtheyleadto… 相似文献
37.
通过键合不同数量的H2PO4^-离子构造了H4P2O8^2-和H4P4O16^8-两种阴离子集 团。利用密度泛函理论对它们的构型进行优化并计算其振动频率和喇曼散射效率。 测量了固—液界面边界层的喇曼光谱并与理论计算结果进行对比分析,进一步研究 了阴离子集团的结构、聚合及脱水等过程。实验和理论研究均表明阴离子二聚体是 KDP晶体的生长基元,他们在固液界面将进一步形成多聚体分子集团,而离子集团 的脱水过程则发生在距KDP晶体表面约50μm的固—液界面边界层中。随着生长层向 界面的推进,这些分子集团将变得越来越有序。本文的研究结果对确定晶体生长界 面动力学过程、发展和完善晶体生长理论有重要意义。 相似文献
38.
An unsymmetrical organic compound with carbazole (Cz) as donor and benzothiadiazole (BTD) as acceptor (D-π-A-π∗-D∗) was designed and synthesized via simple Heck reaction. The unique crystal structure of Cz-BTD-Cz∗ shows a ladder-like packing mode. A two molecule pair stacks parallelly with each other in each packing unit. In each cell, one Cz moiety is connected with BTD by vinylene bond in same plane. However, the other Cz group is connected to BTD by a one-end vinyl bond in almost perpendicular position to the coplanar part of the molecule. The shortest intermolecular plane distance is 3.48 ± 0.1 Å. The photophysical properties of Cz-BTD-Cz∗ in solution and in bulky crystalline powder state were studied. In bulk crystalline powder state, it has a red-shifted emission band peaked at 609 nm relative to that in solution, and the FWHM was reduced to only 58 nm. Electrochemical properties were also investigated. 相似文献
39.
40.
The oscillating conditions for a series piezoelectric quartz crystal (SPQC) are proposed and verified experimentally. The influence of the cell constant and oscillator phase on the oscillational ability of the SPQC was investigated. It is shown that the SPQC possesses excellent oscillational ability in low or high conductivity solutions, but in solution of intermediate conductivity, the oscillational ability decreases with increasing oscillator phase or decreasing cell constant, sometimes resulting in a cease-to-oscillate zone. The SPQC was applied to determine the urease activity in plant seeds with a detection limit of 0.004 U ml−1, based on the change in conductivity. 相似文献