一元强碱滴定二元弱酸的林邦滴定曲线方程及pH_(sp)计算

用质子条件式PBE、物料平衡式MBE、副反应系数和条件稳定常数等知识,推导出一元强碱滴定二元弱酸溶液的林邦滴定曲线方程,并用其推导出第一、第二化学计量点pH_(sp1)和pH_(sp2)的计算公式。     

丙烯酰基苯并三氮唑及其聚合物光物理过程的研究

1-N-丙烯酰基苯并三氮唑(ABT)及其聚合物-聚丙烯酰基苯并三氮唑(PABT)作为功能高分子材料的母体和重要原料已引起人们的重视。如报道[1]利用PABT可制备聚丙烯酸及其各种不同的酯类、带芳酰胺或脂肪酰胺侧基的各种聚酰胺化合物等。     

Nonlinear problems of current-carrying round plates with varying thickness in the electromagnetic field

I.IntroductionInrecentdecades,thescholarsinphysicalmechanicscircleshavegivenmuchmoreattentiontothequestionsofthestressesanddeformationsoftheelasticbodiesunderthecoupledinfluenceofthemechanicalfieldandelectromagneticfield,whichresultsinthefoeinganddevelopm…     

正十二烷醇与环氧乙烷的加成反应动力学研究──最佳反应时间的确定

正十二烷醇与环氧乙烷的加成反应动力学研究──最佳反应时间的确定张仁权,张维冰,李葵英,王万兴（齐齐哈尔轻工学院化工系,齐齐哈尔,１６１００６）关键词正十二烷醇聚氧乙烯醚,碱催化,聚合度在工业生产中脂肪醇与环氧乙烷的加成反应多采用ＫＯＨ和ＮａＯＨ等强碱...     

Synthesis and spectroscopic characterisation of copper(II) complexes with 5-methyl-1-(2′-pyridyl) pyrazole-3-carboxamide (MPyPzCA): X-ray crystal structure of [Cu(MPyPzCA)2(H2O)](ClO4)2

The coordination mode of the title ligand, MP_yP_zCA (synthesised for the first time and characterised by elemental analyses, mass, IR and PMR spectral parameters), is reported by solid state isolation and physicochemical identification of copper(II) complexes, Cu(MP_yP_zCA)₂X₂.H₂O (X=Cl/Br/NO₃/ClO₄). Magnetic and electronic spectral features classify the reported complexes as six coordinate distorted octahedral ones. IR spectra (4000–200 cm⁻¹) of MP_yP_zCA and its complexes indicate different denticity of the two ligand moities namely neutral bidentate function through pyrazolyl ²N and pyridyl ^1′N of one ligand (A) and the neutral tridentate behaviour through pyrazolyl ²N, pyridyl ^1′N and the amidic oxygen of the second ligand system (B). The sixth apical coordination site is occupied by a water molecule in the perchlorate complex (as evident by X-ray data) or by the counter ion, X (X=Cl/Br/NO₃). The electrochemical studies demonstrate easy oxidative nature of Cu(II) in the reported species. X-ray crystallographic studies of the perchlorate complex, [Cu(MP_yP_zCA)₂(H₂O)](ClO₄)₂, (Pna2₁, orthorhombic), has substantiated the conjecture that the geometry is distorted octahedral. The Cu-N (pyrazolyl) and Cu-N (pyridyl) bond lengths are 2.001(3) and 1.969(3) Å and 2.020(4) and 2.206(4) Å in the ligand systems, A and B. respectively; Cu-O (amidic oxygen) for ligand system B and Cu-O (water) bond lengths are 2.783(3) and 2.010(3) Å, respectively. The crystal structure is highly stabilised through extensive hydrogen bonding.     

Domaines fictifs, éléments finis H(div) et condition de Neumann: le problème de la condition inf-sup

Approximation of the Neumann problem for a second order elliptic operator by a fictitious domain method with a Lagrange multiplier on the boundary is considered. The problem is written in its vectorial dual formulation and H(div) mixed finite elements for the vector unknown and H^1/2 conforming elements for the multiplier are used. The uniform inf-sup condition is demonstrated under a compatibility condition between surface and volume meshes.     

Design and Synthesis of Novel Betulin Derivatives Containing Thio-/Semicarbazone Moieties as Apoptotic Inducers through Mitochindria-Related Pathways

Two new series of betulin derivatives with semicarbazone (7a–g) or thiosemicarbazone (8a–g) groups at the C-28 position were synthesized. All compounds were evaluated for their in vitro cytotoxicities in human hepatocellular carcinoma cells (HepG2), human breast carcinoma cells (MCF-7), human lung carcinoma cells (A549), human colorectal cells (HCT-116) and normal human gastric epithelial cells (GES-1). Among these compounds, 8f displayed the most potent cytotoxicity with an IC₅₀ value of 5.86 ± 0.61 μM against MCF-7 cells. Furthermore, the preliminary mechanism studies in MCF-7 cells showed that compound 8f could trigger the intracellular mitochondrial-mediated apoptosis pathway by losing MMP level, which was related with the upregulation of Bax, P53 and cytochrome c expression; the downregulation of Bcl-2 expression; activation of the expression levels of caspase-3, caspase-9, cleaved caspase-3 and cleaved caspase-9; and an increase in the amounts of intracellular reactive oxygen species. These results indicated that compound 8f may be used as a valuable skeleton structure for developing novel antitumor agents.     

Analysis of Electromagnetic Information Leakage Based on Cryptographic Integrated Circuits

Cryptographic algorithm is the most commonly used method of information security protection for many devices. The secret key of cryptographic algorithm is usually stored in these devices’ registers. In this paper, we propose an electromagnetic information leakage model to investigate the relationship between the electromagnetic leakage signal and the secret key. The registers are considered as electric dipole models to illustrate the source of the electromagnetic leakage. The equivalent circuit of the magnetic field probe is developed to bridge the output voltage and the electromagnetic leakage signal. Combining them, the electromagnetic information leakage model’s function relationship can be established. Besides, an electromagnetic leakage model based on multiple linear regression is proposed to recover the secret key and the model’s effectiveness is evaluated by guess entropy. Near field tests are conducted in an unshielded ordinary indoor environment to investigate the electromagnetic side-channel information leakage. The experiment result shows the correctness of the proposed electromagnetic leakage model and it can be used to recover the secret key of the cryptographic algorithm.