全文获取类型
收费全文 | 2732篇 |
免费 | 470篇 |
国内免费 | 600篇 |
专业分类
化学 | 1351篇 |
晶体学 | 3篇 |
力学 | 60篇 |
综合类 | 12篇 |
数学 | 1297篇 |
物理学 | 1079篇 |
出版年
2024年 | 5篇 |
2023年 | 91篇 |
2022年 | 78篇 |
2021年 | 123篇 |
2020年 | 136篇 |
2019年 | 92篇 |
2018年 | 109篇 |
2017年 | 89篇 |
2016年 | 98篇 |
2015年 | 118篇 |
2014年 | 208篇 |
2013年 | 270篇 |
2012年 | 208篇 |
2011年 | 221篇 |
2010年 | 245篇 |
2009年 | 244篇 |
2008年 | 177篇 |
2007年 | 242篇 |
2006年 | 243篇 |
2005年 | 110篇 |
2004年 | 100篇 |
2003年 | 90篇 |
2002年 | 88篇 |
2001年 | 99篇 |
2000年 | 59篇 |
1999年 | 53篇 |
1998年 | 46篇 |
1997年 | 33篇 |
1996年 | 9篇 |
1995年 | 18篇 |
1994年 | 19篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 10篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 37篇 |
1987年 | 11篇 |
1979年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有3802条查询结果,搜索用时 125 毫秒
101.
《Journal of Pure and Applied Algebra》2023,227(5):107271
In this paper, we give a numerical criterion of Reider-type for the d-very ampleness of the adjoint line bundles on quasi-elliptic surfaces, and meanwhile we give a new proof of the vanishing theorem on quasi-elliptic surfaces emailed from Langer and show that it is the optimal version. 相似文献
102.
103.
《Communications in Nonlinear Science & Numerical Simulation》2014,19(6):1935-1944
This paper addresses the epidemiological modeling of computer viruses. By incorporating the effect of removable storage media, considering the possibility of connecting infected computers to the Internet, and removing the conservative restriction on the total number of computers connected to the Internet, a new epidemic model is proposed. Unlike most previous models, the proposed model has no virus-free equilibrium and has a unique endemic equilibrium. With the aid of the theory of asymptotically autonomous systems as well as the generalized Poincare–Bendixson theorem, the endemic equilibrium is shown to be globally asymptotically stable. By analyzing the influence of different system parameters on the steady number of infected computers, a collection of policies is recommended to prohibit the virus prevalence. 相似文献
104.
Ultrasound-assisted deposition (USAD) of sol nanoparticles enables the formation of uniform and inherently stable thin films. However, the technique still suffers in coating hard substrates and the use of fast-reacting sol–gel precursors still remains challenging. Here, we report on the deposition of ultrathin titanium and titanium/silicon hybrid oxide coatings using hydroxylated silicon wafers as a model hard substrate. We use acetic acid as the catalyst which also suppresses the reactivity of titanium tetraisopropoxide while increasing the reactivity of tetraethyl orthosilicate through chemical modifications. Taking the advantage of this peculiar behavior, we successfully prepared titanium and titanium/silicon hybrid oxide coatings by USAD. Varying the amount of acetic acid in the reaction media, we managed to modulate thickness and surface roughness of the coatings in nanoscale. Field-emission scanning electron microscopy and atomic force microscopy studies showed the formation of conformal coatings having nanoroughness. Quantitative chemical state maps obtained by x-ray photoelectron spectroscopy (XPS) suggested the formation of ultrathin (<10 nm) coatings and thickness measurements by rotating analyzer ellipsometry supported this observation. For the first time, XPS chemical maps revealed the transport effect of ultrasonic waves since coatings were directly cast on rectangular substrates as circular shadows of the horn with clear thickness gradient from the center to the edges. In addition to the progress made in coating hard substrates, employing fast-reacting precursors and achieving hybrid coatings; this report provides the first visual evidence on previously suggested “acceleration and smashing” mechanism as the main driving force of USAD. 相似文献
105.
We construct silver–gold alloy nanoparticles (Ag–AuNPs) as the basis of a reagentless, sensitive and simple mercury sensor. Ag–AuNPs were electrodeposited directly on transparent indium tin oxide film coated glass. Hg(II) ions in aqueous solution could be reduced by Ag atoms existing in Ag–AuNPs; the deposition/amalgamation of Hg on the nanoparticles resulted in a blue shift of the localized surface plasmon resonance peak. Therefore, Hg2 + can be detected quantitatively by using a spectrophotometer. The sensor response is linear in the range from 0.05 to 500 ppb of Hg(II) concentration. No sample separation or preconcentration is required for detection of ultralow levels of mercury in water samples. The results shown herein have potential applications in the development of a new optical sensor for the detection of low concentrations of mercury. 相似文献
106.
107.
运用水热法合成了1个新的配合物[Ni(Phtpy)2](CH3COO)2(化合物1),(Phtpy=4′-苯基-2,2′∶6′,2″-三联吡啶),并通过X-射线单晶衍射方法确定了该化合物的晶体结构.结构分析表明化合物1属于三斜晶系,P-1空间群,晶胞参数a=0.905 60(8)nm,b=1.103 07(9)nm,c=2.020 14(15)nm,α=94.383 0(10)°,β=100.983 0(10)°,γ=106.312 0(10)°,V=1.883 1(3)nm3,Z=2,R1=0.087 2,wR2=0.183 1.配合物中存在3种氢键和多种π-π相互作用,使其成为一个3D配合物. 相似文献
108.
Entanglement of two distinguishable atoms in a rectangular waveguide: Linear approximation with single excitation
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
《中国物理 B》2021,30(9):90307-090307
We investigate the entanglement dynamics of two distinguishable two-level systems(TLSs) characterized by energy difference δ located inside a rectangular hollow metallic waveguide of transverse dimensions a and b. The effects of energy difference δ and the inter-TLS distance on the time evolution of the concurrence of the TLSs are examined in the single excitation subspace when the energy separation of the TLS is far away from the cutoff frequencies of the transverse mode. 相似文献
109.
A novel reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides was performed in the presence of silver nitrate or triflate.Conjugated vinyl sulfones as dramatic products were obtained in moderate yields and with Z-selectivity.A free radical mechanism has been proposed to account for the formation of the products. 相似文献
110.
The hydrohaloalkanes have attracted much attention as potential substitutes of chlorofluorocarbons (CFCs) that deplete the ozone layer and lead to great high global warming. Having a short atmospheric lifetime is very important for the potential substitutes that may also induce ozone depletion and yield high global warming gases to be put in use. Quantitative structure–activity relationship (QSAR) studies were presented for their lifetimes aided by the quantum chemistry parameters including net charges, Mulliken overlaps, E HOMO and E LUMO based on the density functional theory (DFT) at B3PW91 level, and the C-H bond dissociation energy based on AM1 calculations. Outstanding features of the logistic mapping, a simple chaotic system, especially the inherent ability to search the space of interest exhaustively have been utilized. The chaotic mapping aided genetic algorithm artificial neural network training scheme (CGANN) showed better performance than the conventional genetic algorithm ANN training when the structure of the data set was not favorable. The lifetimes of HFCs and HCs appeared to be greatly dependent on their energies of the highest occupied molecular orbitals. The perference of the RMSRE comparing to RMSE as objective function of ANN training was better for the samples of interest with relatively short lifetimes. C2H6 and C3H8 as potential green substitutes of CFCs present relatively short lifetimes. 相似文献