全文获取类型
收费全文 | 556篇 |
免费 | 9篇 |
国内免费 | 132篇 |
专业分类
化学 | 218篇 |
晶体学 | 7篇 |
力学 | 71篇 |
综合类 | 1篇 |
数学 | 206篇 |
物理学 | 194篇 |
出版年
2023年 | 8篇 |
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 22篇 |
2019年 | 6篇 |
2018年 | 2篇 |
2017年 | 11篇 |
2016年 | 28篇 |
2015年 | 11篇 |
2014年 | 38篇 |
2013年 | 18篇 |
2012年 | 15篇 |
2011年 | 19篇 |
2010年 | 17篇 |
2009年 | 16篇 |
2008年 | 11篇 |
2007年 | 17篇 |
2006年 | 28篇 |
2005年 | 20篇 |
2004年 | 12篇 |
2003年 | 20篇 |
2002年 | 32篇 |
2001年 | 76篇 |
2000年 | 60篇 |
1999年 | 60篇 |
1998年 | 39篇 |
1997年 | 18篇 |
1996年 | 16篇 |
1995年 | 19篇 |
1994年 | 7篇 |
1993年 | 11篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 1篇 |
排序方式: 共有697条查询结果,搜索用时 31 毫秒
1.
2.
《Solid State Ionics》2006,177(37-38):3267-3273
New series of oxides, La3MMo2O12 (M = In, Ga and Al), have been prepared by the solid-state reaction. The composition and elemental distribution were analyzed by the energy-dispersive X-ray (EDX) analysis. As determined by the X-ray diffraction (XRD), these compounds have similar crystal structures that can be indexed on a monoclinic cell at room temperature. AC impedance spectra and the DC electrical conductivity measurements in various atmospheres indicate that they are oxide ion conductors with ionic conductivities between 10− 2 and 10− 3 S/cm at 800 °C. The conductivity decreases in the order of La3GaMo2O12 > La3AlMo2O12 > La3InMo2O12, implying that the effect of cell volume and polarization associated with In3+, Ga3+ and Al3+ play an important role in the anion transport of these materials. The reversible phase transition was observed in all these compounds as confirmed by the differential thermal analysis (DTA) and dilatometric measurements. 相似文献
3.
§ 1 IntroductionA triple system of order v and indexλ,denoted by TS(v,λ) ,is a collection of3- ele-mentsubsets Aof a v- set X,so thatevery 2 - subsetof X appears in preciselyλ subsets of A.L etλ≥ 2 and (X,A) be a TS(v,λ) .If Acan be partitioned into t(≥ 2 ) parts A1,A2 ,...,Atsuch that each (X,Ai) is a TS(v,λi) for 1≤ i≤ t,then (X,A) is called de-composable.Otherwise it is indecomposable.If t=λ,λi=1for 1≤ i≤ t,the TS(v,λ) (X,A) is called completely decomposable.It … 相似文献
4.
For structural parameters with uncertainties, interval mathematics can, in the case where the probabilistic distribution density
of uncertain variables is unavailable, deal with the influence of uncertainties in structural parameters on the response of
structures. In order to evaluate the region containing natural frequencies of structures with interval parameters, the interval
parameter perturbation method is presented in this paper. The advantage of the present method is its computational efficiency
in evaluating the region containing natural frequencies. A numerical example is used to illustrate the efficiency of the method
proposed.
The project is supported by National Youth Natural Science Foundation of China and National Outstanding Youth Science Foundation
of China. 相似文献
5.
《Electrochemistry communications》2007,9(9):2196-2201
For many years, polypyrrole films have appeared to be the most studied conducting polymer. Unfortunately, shadows still remain concerning the electrochemical mechanisms of these films and in particular, the aspect which concerns the limiting step which governs the electrochemical response. Different possibilities are available such as the transport of ionic species in the film, the electron transfer at the electrode/film or the electron motion in the film, the ionic exchanges at the film/interface electrolyte. Classical electrochemical methods do not permit to discriminate between these effects. Ac-electrogravimetry technique was used here to demonstrate that the electrochemical behaviour of thin pPy films is governed by the ionic insertion without any doubt. Particular parameters were modified as the ionic atomic weight or the electrolyte concentration to corroborate this idea. 相似文献
6.
7.
In this paper, we discuss the representation-finite selfinjective artin algebras of classB
n andC
n and obtain the following main results:
For any fieldk, let Λ be a representation-finite selfinjective artin algebras of classB
n orC
n overk.
相似文献
(a) | We give the configuration ofZB n andZC n. |
(b) | We show that Λ is standard. |
(c) | Under the condition ofk being a perfect field, we describe Λ by boundenk-species and show that Λ is a finite covering of the trivial extension of some tilted algebra of typeB n orC n. |
8.
《Journal of photochemistry and photobiology. A, Chemistry》2006,177(2-3):261-268
TiO2 nanocrystallites were prepared from precursors tetra-n-butyl titanate (Ti(OC4H9)4) and titanium tetrachloride (TiCl4). The precursors were hydrolyzed by gaseous water in autoclave, and then calcined at predetermined testing temperatures. The samples were characterized by X-ray diffraction (XRD), thermogravimetry–differential thermal analysis (TG–DTA), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectra (FT-IR), and UV–vis diffuse reflectance spectra (DRS). The photocatalytic activities of the samples were evaluated by the photobleaching of methylene blue (MB) in aqueous solution and the photocatalytic oxidation of propylene in gas phase at ambient temperature. The results showed that the anatase phase nanocrystalline TiO2 could be obtained at relatively low temperatures (for precursor Ti(OC4H9)4 at 110 °C and for TiCl4 at 140 °C, respectively), and that the as prepared samples exhibited high photocatalytic activities to photobleach MB in aqueous solution. As the calcination temperatures increasing, the decolor ratio of MB increased and reached the maximum value of nearly 100% at 600 °C, and then decreased. The photobleaching of MB by all samples followed the pseudo-first-order kinetics with respect to MB concentration. The photodecomposition amount of propylene by TiO2 nanocrystallites calcined at 600 °C from precursor of Ti(OC4H9)4 is 21.6%, which is approaching to that by Degussa P25 TiO2 (24.9%). 相似文献
9.
确定了N-[(4-二甲基氨基)-苄叉基]-2-氨基苯并咪唑(1),N-[(4-二甲基氨基)-苄叉基]-2-氨基苯并噻唑(2)和N-苄叉基-1-氨基-萘(3)的晶体结构。利用AM1,RHF,DFT方法和STO-3G,4-31G,6-311G及6-311G基组,优化每个分子的23个扭曲构象(θ=0°~-89°)。尽管不同方法得到的最优构象的扭角不同,分子扭曲的驱动力总是起因于电子作用,在任一分子、任何电子态中,离域的π体系总是失稳定的,全平面构象不是π体系最稳定的构象。π电子的离域是分子扭曲的驱动力之一,与经典观点相反,非键原子间的核排斥作用是分子扭曲的阻力,而不是动力。 相似文献
10.
I demonstrate photochemically induced crystallization of metastable hen egg-white lysozyme solution by weak UV irradiation for several tens seconds. The most effective irradiation time range is 10–60 s, and in this range the enzyme activity is maintained. Intermediates, neutral radicals at tryptophan residual produced by one-photon absorption, enhance nucleation. When the intermediate is selectively excited by visible light, the intermediate is denatured. At that time the light-induced nucleation is inhibited. This result indicates the intermediate induces nucleation. The radical forms lysozyme dimer that is detected by an SDS-PAGE electrophoresis experiment. An addition of polyethylene glycol (PEG) greatly enhances light-induced nucleation. PEG affects to shorten the intermediate radical lifetime, which suggests that PEG assists to form dimer. We consider that the photochemical dimer behaves as smallest cluster to grow critical nucleus. The smallest cluster formation is the rate determining step in classical nucleation theory due to surface energy disadvantage. The photochemical dimer is formed by a covalent bond, and the nucleation is initiated from stable dimer. The nucleation enhancement is reasonably explained. The present researches results point out the development of a new method for controlling nucleation and growth that could be applied for structural genomics and pharmaceutical industry for instance. 相似文献