Study on removing calcium carbonate plug from near wellbore by high-power ultrasonic treatment

In this paper, the effects of ultrasonic wave on the removal of inorganic scaling and plugging in cores and the influence of the key wave field parameters, process parameters and core physical parameters on the plugging removal efficiency are systematically studied. The main dynamic mechanism of ultrasonic plugging removal is also systematically analyzed. Results show that the transducer frequency, transducer power, ultrasonic treatment time and initial permeability of core have great influence on the effect of ultrasonic scale removal. When the cumulative treatment time of ultrasonic wave exceeds 60 min, the recovery rate of core permeability tends to be stable. Best effect can be achieved when processing for 80–120 min cumulatively; the plugging removal effect is improved with the increase of ultrasonic transducer power and ultrasonic frequency, but the effect of plugging removal is not obvious with the further increasing of them. In addition, it is proved that the effect of removing calcium carbonate plug from near wellbore by hydrochloric acid solution is slightly better than that by ultrasonic treatment alone. Finally, the micro dynamic mechanism of removing inorganic scale plug by high-power ultrasonic treatment is discussed in view of ultrasonic inorganic scale body crushing, ultrasonic cavitation, ultrasonic friction, ultrasonic peristaltic transport operation and ultrasonic fracture-making and permeability-increasing effect.     

5-氨基异噁唑的4-位芳基化

在温和、简单条件下实现了5-氨基异噁唑C4位芳基化的反应，以中等到优秀的产率（最高达99%）合成了一系列4-芳基-5-氨基异噁唑类衍生物，产物结构经核磁与高分辨质谱确证。      

Toughening of poly(L‐lactide)/multiwalled carbon nanotubes nanocomposite with ethylene‐co‐vinyl acetate

Poly(L ‐lactide)/multiwalled carbon nanotubes (PLLA/MWCNTs) nanocomposite recently attracts much attention because of its excellent comprehensive properties including improved thermostability, tensile strength, and conductivity. However, the nanocomposite exhibits similar brittleness compared with unmodified PLLA. In this work, a polar elastomer, that is, ethylene‐co‐vinyl acetate (EVA), was introduced into PLLA/MWCNTs nanocomposite. The selective distribution of MWCNTs and the effects of EVA on crystalline structure of PLLA were investigated using scanning electron microscope, transmission electron microscope, differential scanning calorimetry, and wide angle X‐ray diffraction. The results show that the presence of EVA induces the change of the distribution of MWCNTs in the nanocomposites, and consequently, the cold crystallization of PLLA is prevented. With the increase of EVA content, both the ductility and the impact resistance of PLLA/FMWCNTs are improved greatly, indicating the toughening effect of EVA on PLLA/MWCNTs nanocomposite. The decreased tensile strength and modulus can be compensated through annealing treatment. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011     

Vortex shedding and three-dimensional behaviour of flow past a cylinder confined in a channel

A numerical investigation of the flow past a circular cylinder centred in a two-dimensional channel of varying width is presented. For low Reynolds numbers, the flow is steady. For higher Reynolds numbers, vortices begin to shed periodically from the cylinder. In general, the Strouhal frequency of the shedding vortices increases with blockage ratio. In addition, a two-dimensional instability of the periodic vortex shedding is found, both empirically and by means of a Floquet stability analysis. The instability leads to a beating behaviour in the lift and drag coefficients of the cylinder, which occurs at a Reynolds number higher than the critical Reynolds number for the three-dimensional mode A-type instability, but lower than a Reynolds number for any mode B-type instability.     

用代数-能量自洽法研究双原子分子解析势能函数

基于计算双原子分子完全振动能谱及离解能的代数方法 (algebraic method,AM)和研究双原子分子解析势能函数的能量自洽法(energy consistent method,ECM),建立了计算双核分子体系精确解析势能函数的代数-能量自洽法(AM-ECM).应用AM-ECM方法研究了7Li+2-23Σg,KH-X1Σ+,NaLi-X1Σ+和NaLi-A1Σ+电子态的解析势能表达形式,并与其他方法的研究结果进行了比较,获得了能正确描述这些电子态在渐近区和离解区的精确解析表达结果.     

Numerical simulation and convergence analysis of a high-order conservative difference scheme for SRLW equation

Coupled with the Richardson extrapolation, a new conservative Crank–Nicolson finite difference scheme, which has the accuracy of O(τ²+h⁴)$O({\tau }^2+h^4)$ without refined mesh for the symmetric regularized long wave equation is proposed. The corresponding conservative quantities are discussed, and the existence of numerical solution is proved by the Browder fixed point theorem. The convergence, unconditional stability and uniqueness of the scheme are also derived using the energy method. Numerical results are given to verify the accuracy and the efficiency of proposed algorithm.     

Ba0.98Bi0.02(Ti0.9Zr0.1)1-xCuxO3陶瓷的介电性能、弛豫行为与结晶化学特性

采用固相合成法, Bi3+作施主掺杂A位, Cu₂₊作受主掺杂B位, 制备了Ba_0.98Bi_0.02(Ti_0.9Zr_0.1)_1-xCu_xO₃(x=0, 0.01, 0.02, 0.03)陶瓷样品。借助XRD、LCR等研究了该陶瓷的结构与介电性能。结果表明:当x=0.03时, 陶瓷样品出现第二相。通过GULP模拟, 缺陷偶极子的稳定性从低到高依次为:[2Bi_Ba^·+V_Ba"]、[2Bi_Ba^·+Cu_Ti/Zr"]、[Cu_Ti/Zr"+V_O^··], 结合实验可知:介电弛豫程度与晶体中缺陷偶极子的存在形式相关, 其中x=0.01时, 晶体中以[2Bi_Ba^·+Cu_Ti/Zr"]为主。随Cu₂₊掺杂量的增加, 介电常数增加, 介电常数与B位键价和呈反比变化、与八面体BO₆的体积呈正比变化。     

销售商出售看跌期权的供应链优化研究

在由一个供应商和一个销售商组成的单期两级供应链中,处于主导地位的销售商以其卖场所具有的销售能力参与供应链合作,并从销售的每一个产品中获取既定收益。同时,销售商还向供应商出售建立在产品销售量保障基础上的看跌期权,以激励供应商参与供应链合作。论文对上述情形的销售商出售看跌期权的供应链合作问题进行了研究,通过建模与优化分析,证明了在销售商提供看跌期权的供应链合作中,供应商存在唯一的最优生产批量和看跌期权采购量,以及销售商存在最优的从每一单位产品销售中获取的既定收益。论文还揭示了销售商提供看跌期权,虽然无法实现供应链协调,但可以实现供应链参与企业所获得的收益与其所承担的风险相匹配。最后,论文论证了在销售商出售看跌期权机制下,供应链存在收益损失较小的理想合作区域。     

悬索桥竖向自由振动的传递矩阵解

该文将传递矩阵方法引入悬索桥竖向自由振动求解.首先,提出了悬索桥竖向自由振动微分方程的求解方法,由此求解方法可直接得到结构自由振动解析式.在此基础上,得出了悬索桥竖向自由振动分析的传递矩阵.应用此方法,该文研究了等截面悬索桥及变截面悬索桥竖向自由振动问题.研究结果表明,传递矩阵法能高效地进行悬索桥竖向自由振动分析,并对变截面问题的处理有独特的优势.研究工作对悬索桥在方案设计阶段的动力学分析有一定的参考价值和借鉴意义.