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991.
通过溶剂热法,成功制备了准凹面体状Pt-Ni合金纳米结构.不同角度的透射电镜照片和三维模型图表明,准凹面体与以立方八面体为基底,在其十二个顶点进行外延生长所形成的结构相对应.高分辨电镜(HRTEM),选区电子衍射(SAED)和X射线粉末衍射(XRD)表征结果表明,外延部分与内核部分组成成分不同.在进行系统对照实验的基础上提出了同步刻蚀-过生长机理来解释准凹面体的形成过程.电化学测试表明,准凹面体对甲醇氧化具有很高的催化活性,按质量归一的催化活性是相同条件下制备所得纯Pt颗粒的3倍,是商用Pt/C的13.6倍.X射线光电子能谱数据表明,Ni的引入有效降低了Pt的原子结合能,这可能对催化活性的提高起到了关键作用.  相似文献   
992.
王莉  赵勇  江雷 《无机化学学报》2014,30(1):155-162
制备了具有响应性的仿蛛丝周期纺锤节TiO2纤维。通过改变纤维表面微观结构、紫外光照和超声波等手段,仿蛛丝结构TiO2纤维表面浸润性会发生响应性变化。纤维表面的这种浸润性变化,不仅实现了水滴从纺锤节两端到中心处的定向运动,而且可以使得水滴被纤维纺锤节粘附。当仿蛛丝结构TiO2纤维表面为亲水状态时,无论纺锤节光滑还是粗糙,水都是从纺锤节两端向中心方向运动;当仿蛛丝结构TiO2纤维表面疏水时,水滴会被具有粗糙表面的纺锤节两端粘附。  相似文献   
993.
A Co3 O4 nanorod supported Pd electro-catalyst for the methanol electro-oxidation (MEO) has been fabricated by the combination of hydrother-mal synthesis and microwave-assisted polyol reduction process...  相似文献   
994.
本文简要综述了本课题组近年来在单晶氧化铁空心纳米结构制备与生长机理研究方面的相关工作.通过采用磷酸根与硫酸根的双阴离子调节,结合反应时间、反应温度等条件的改变,实现了对α-Fe2O3单晶空心纳米结构形貌、尺寸和表面结构的良好调控,并提出一种针对非层状结构纳米环/纳米管新颖生长机理,即"配位辅助的定向溶解机理".以所制备的α-Fe2O3为前驱体,采用气相还原方法,成功制备得到了系列单晶Fe3O4和γ-Fe2O3管状及环状纳米结构,并对单个Fe3O4纳米环的磁学行为进行了考察.  相似文献   
995.
大脑神经系统具有从慢到快多种不同的振荡节律, 这些节律振荡被认为参与了大脑多种功能的实现, 其中高频的伽马同步振荡被认为与大脑的认知功能最为相关. 本文阐述了生物学实验方面关于伽马振荡及其功能的研究进展, 并针对实验中伽马振荡的频率敏感依赖于外部刺激特征的现象, 综述了基于神经网络模型进行变频伽马振荡及其认知功能的动力学建模研究工作, 解释了视觉刺激调控的变频率伽马振荡动力学产生机理, 提出了基于同步抑制增强全局放电率对比度的神经认知机制. 研究成果有助于理解神经系统同步振荡的产生机理及其认知作用, 为大脑认知原理以及类脑智能的研究奠定基础.   相似文献   
996.
在牙科种植领域常使用的种植体材料多为纯钛或钛合金, 然而钛金属种植体存在美学缺陷及潜在的致敏可能等问题. 氧化锆陶瓷由于其高强度、美观性与生物相容性被认为是钛金属种植体的理想替代品, 但目前国内对于氧化锆种植体的研究仍处于起步阶段. 本文通过对氧化锆种植体及骨组织进行有限元建模, 并对种植体的动态植入过程进行仿真, 分析了骨组织内部的应力-应变状况. 结果发现, 随着植入深度的增加, 种植体与骨组织的接触面积增大, 松质骨内应力增加. 考虑到骨组织的具体结构, 将松质骨内的最大应力-应变作为分析的主要对象, 结合损伤分析, 对种植体模型进行了优化. 此外, 还设计了3种具有自攻刃设计的种植体模型, 分别进行应力应变分析后确定了最优设计. 之后建立了具有自攻刃设计的种植体模型, 并模拟了临床的3种植入方案: 螺纹成形、螺纹切割、螺纹成形与切割进行分析, 通过分析得到螺纹成形与切割种植方案更为安全的结论. 本文结果可以指导氧化锆种植体的结构设计以及植入时的条件设定等, 为我国自主研发的氧化锆种植体进行了理论指导, 为其早日进行临床应用指明了方向.   相似文献   
997.
Tian  Yuzhou  Huang  Bo 《Nonlinear dynamics》2022,109(2):1135-1151

The three-dimensional Muthuswamy–Chua–Ginoux (MCG, for short) circuit system based on a thermistor is a generalization of the classical Muthuswamy–Chua circuit differential system. At present, there are only partial numerical simulations for the qualitative analysis of the MCG circuit system. In this work, we study local stability and Hopf bifurcations of the MCG circuit system depending on 8 parameters. The emerging of limit cycles under zero-Hopf bifurcation and Hopf bifurcation is investigated in detail by using the averaging method and the center manifolds theory, respectively. We provide sufficient conditions for a class of the circuit systems to have a prescribed number of limit cycles bifurcating from the zero-Hopf equilibria by making use of the third-order averaging method, as well as the methods of Gröbner basis and real solution classification from symbolic computation. Such algebraic analysis allows one to study the zero-Hopf bifurcation for any other differential system in dimension 3 or higher. After, the classical Hopf bifurcation of the circuit system is analyzed by computing the first three focus quantities near the Hopf equilibria. Some examples and numerical simulations are presented to verify the established theoretical results.

  相似文献   
998.
Sun  Xiucong  Bai  Shengzhou 《Nonlinear dynamics》2022,110(1):313-346

The low-thrust Lambert transfer refers to that the spacecraft achieves the orbital transfer whose boundary conditions are represented by two sets of orbital elements at initial and final time by the low-thrust propulsion system. The modulus and direction of the low-thrust solutions in previous methods change with time, which leads to high control requirements for the engine. In this paper, to reduce the requirements of the engine, a practical two-stage constant-vector thrust control method is proposed, in which the magnitude and direction of the thrust are deemed as segmental constant value in TNH frame, where three components of the thrust are ft, fn, and fh. First, the mathematical model of the two-stage constant-vector thrust is formulated, and a rapid algorithm is presented to obtain the solution based on the linearized sensitivity matrix, which describes the relationship between the constant-vector thrust and the change of the orbital elements approximately. Furthermore, two low-thrust Lambert strategies based on the two-stage constant-vector thrust are presented for cases of short-time transfer and long-time transfer. A sequence of numerical simulations demonstrated the efficiency of the proposed approaches. The proposed control strategies are solved rapidly, and they are also suitable for different types of orbits with J2 perturbation, which are practical options for engineering applications.

  相似文献   
999.
In this paper, the nonlinear vibration and instability of a fluid-conveying nanopipe made of functionally graded (FG) materials with consideration of the initial geometric imperfection are investigated. The material properties are assumed to vary smoothly along the radial direction according to a power-law exponent form. The fluid-conveying FG nanopipe is modeled as a Euler-Bernoulli beam, and the governing equation is derived based on the nonlocal strain gradient theory incorporating the effects of Von-Karman geometrical nonlinearity and initial imperfection. The nonlinear frequency and critical fluid velocity are achieved via He's Hamiltonian approach. After verifying the present model with comparison of several previous studies, the effect of several different system parameters including the amplitude of the nonlinear oscillator, the initial geometric imperfection, size-dependent parameters, and the power-law index on the frequency response of the fluid-conveying FG nanopipe are explored. Moreover, the critical velocity of the conveying fluid under different system parameters is also investigated and discussed in detail. The developed size-dependent nonlinear model is expected to provide a possible theoretical way to guide the application of FG nanopipe as micro/nanofluidic devices.  相似文献   
1000.
Silicon-based microelectromechanical system (MEMS) and nanoelectromechanical systems (NEMS) have been used to design and fabricate sensitive sensors and actuators. Recent research trends show that graphene and carbon nanotubes (CNTs) have been used to change the surface properties of silicon-based MEMS and NEMS to improve different mechanical, optical and electrical properties of silicon-based composites. In this paper, we focus on analyzing the vibrational characteristics of silicon-based devices when the surface of silicon is coated with single-layer graphene and horizontally aligned carbon nanotubes (HACNTs). To perform the analysis, we use multi-scale finite element approach for developing graphene–silicon nanocomposites (GSNCs) and carbon nanotube-silicon nanocomposites (CSNC) composites in which interface layer of silicon with graphene or CNT is modeled using bonded contact element. Subsequently, we performed modal analysis to find the first transverse mode frequency of GSNC and CSNC composites for beam with smaller as well as longer lengths. The numerical model is compared with classical beam theory with and without surface effect. For GSNCs composites, we take a fixed-free case with lengths in the range of (20 Å–120 Å) and (400 Å–2000 Å), respectively. For CSNC composites, CNT diameter is varied from (5 Å–30 Å) for single walled nanotube. Subsequently, we analyze the influence of HACNTs-on-silicon on its vibrational characteristics. The analysis presented in the paper demonstrate that GSNCs offer a higher bending stiffness compared to single layer graphene (SLGs) and isolated silicon nanosheet which lead to higher natural frequency. A similar trend is found in the case of HACNTs on silicon NS when the number of tubes increases.  相似文献   
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