pH Dependence of Surface Enhanced FT-Raman Scattering of Ω-Mercaptoalkanols on Silver Surface

Fourier transform surface enhanced Raman spectrometer is used to characterize Ω-mercaptoalkanols (HO(CH₂)_nSH, n=2, 6) chemisorption on silver surface from their aqueous solution of different pH values.     

Langford系统Hopf分叉的线性反馈控制

分析Langford系统的Hopf分叉现象，并研究采用线性反馈控制方法控制该系统的Hopf分叉.从理论上推导出受控系统产生Hopf分叉的条件，给出了某些极限环的解析表达式，对该系统进行了分叉点的转移与极限环的稳定性控制.数值模拟说明本文采用的方法对Langford系统的Hopf分叉控制是有效的. 关键词： Langford系统 反馈控制 Hopf分叉 极限环     

Effect of acoustic resonance on the dynamic lift forces acting on two tandem cylinders in cross-flow

Direct measurements of the dynamic lift force acting on two tandem cylinders in cross-flow are performed in the presence and absence of acoustic resonance. The dynamic lift force is measured because it represents the integrated effect of the unsteady wake and therefore it is directly related to the dipole sound source generated by vortex shedding from the cylinder. Three spacing ratios inside the proximity interference region, L/D=1.75, 2.5 and 3 are considered. During the tests, the first transverse acoustic mode of the duct housing the cylinders is self-excited. In the absence of acoustic resonance, the measured dynamic lift coefficients agree with those reported in the literature. When the acoustic resonance is initiated, a drastic increase in the dynamic lift coefficient is observed, especially for the downstream cylinder. This can be associated with abrupt changes in the phase between the lift forces and the acoustic pressure. The dynamic lift forces on both cylinders are also decomposed into in-phase and out-of-phase components, with respect to the resonant sound pressure. The lift force components for the downstream cylinder are found to be dominant. Moreover, the out-of-phase component of the lift force on the downstream cylinder is found to become negative over two different ranges of flow velocity and to virtually vanish between these two ranges. Acoustic resonance of the first mode is therefore excited over two ranges of flow velocity separated by a non-resonant range near the velocity of frequency coincidence. It is therefore concluded that the occurrence of acoustic resonance is controlled by the out-of-phase lift component of the downstream cylinder, whereas the effect of the in-phase lift component is confined to causing small changes in the acoustic resonance frequency.     

打水漂与物理学规律

打水漂是人类最古老的游戏之一.通过对打水漂进行简化定量分析得出,石块弹跳,只有在抛掷的初速度超过某个临界值时才会发生,并且给出了石块的最大弹跳次数.     

Effects of rubbing angle on maximum transmittance of in-plane switching liquid crystal display

Measurements of the maximum transmittance of an in-plane switching liquid crystal display showed that it increases as rubbing angle is increased from 10 to 20°. This dependence was analysed in terms of the local variation of electric field intensity between electrodes, which in turn makes liquid crystal at various positions between the electrodes rotate to different angles. The local variation of electric field becomes prominent, especially in the case that the distance between the electrodes is much larger than the cell gap or electrode width.     

Effect of nanoscale size and medium on metal work function in oleylamine-capped gold nanocrystals

The work function is an important material property with several applications in photonics and optoelectronics. We aimed to characterize the work function of clusters resulting from gold nanocrystals capped with oleylamine surfactant and drop-casted onto gold substrate. We used scanning Kelvin probe microscopy to investigate the work function, and complemented our study mainly with X-ray diffraction and X-ray photoelectron spectroscopy. The oleylamine works as an electron blocking layer through which the electrical conduction takes place by tunneling effect. The surface potential appears to depend on the size of the clusters, which can be ascribed to their difference in effective work function with the substrate. The charge state of gold clusters is discussed in comparison with theory, and their capacitance is calculated from a semi-analytical equation. The results suggest that at the nanoscale the work function is not an intrinsic property of a material but rather depends on the size and morphology of the clusters, including also effects of the surrounding materials.     

微生物批式流加发酵脉冲系统的参数辨识及稳定性

针对微生物批式流加发酵生产1,3-丙二醇的非线性脉冲系统,建立敏感参数的优化辨识模型(PDP),论述了模型解的性质、解与参量的关系以及辨识问题最优解的存在性.通过构造算法求得辨识问题最优解,并讨论了新参数下脉冲系统解的稳定性.     

The Existence of Solutions of （k, n - k） Conjugate Boundary Value Problems in Banach Spaces

In this paper,by use of the Schauder fixed-point theorem,the existence of solution of (k,n-k) Conjugate boundary value problems in Banach spaces is investigated.     

Fission fragment mass yields of Th to Rf even-even nuclei

Fission properties of the actinide nuclei are deduced from theoretical analysis. We investigate potential energy surfaces and fission barriers and predict the fission fragment mass yields of actinide isotopes. The results are compared with experimental data where available. The calculations were performed in the macroscopic-microscopic approximation with the Lublin-Strasbourg Drop (LSD) for the macroscopic part, and the microscopic energy corrections were evaluated in the Yukawa-folded potential. The Fourier nuclear shape parametrization is used to describe the nuclear shape, including the non-axial degree of freedom. The fission fragment mass yields of the nuclei considered are evaluated within a 3D collective model using the Born-Oppenheimer approximation.