一种基于偶氮水杨醛酰腙的CN-探针

设计合成了一种基于偶氮苯基团的简单而高效的比色探针L1,并利用紫外-可见吸收光谱考察其对阴离子(F-,Cl-,Br-,I-,AcO-,H2PO4-,HSO4-,ClO4-和CN-)的识别性能。结果表明:探针L1在DMSO/H2O(5∶5,V/V)的含水体系中,可以实现对CN-单一选择性识别;且加入CN-时,溶液颜色立刻由无色变为红色,而加入其它阴离子则无变化,说明该探针能够实现对CN-的裸眼识别。另外,该探针对CN-的检测灵敏度较高,最低检测限达到了1.3μmol·L-1。此外,我们制作了负载有探针分子L1的试纸条,能够更加方便快捷的检测CN-。     

磁控溅射法制备Au薄膜及真空载流摩擦学行为研究

针对空间滑动电接触金基润滑涂层在制备方法以及失效机理认识方面存在的不足,探索采用绿色磁控溅射法制备金薄膜. 研究了偏压对薄膜微观结构、力学以及真空载流摩擦学性能的影响规律;建立了真空载流服役工况摩擦试验评价条件,可实现接触电流噪音的实时监测,进一步对比传统电镀金涂层,研究了其真空载流摩擦磨损行为差异、主要影响因素及作用机制. 结果表明:在适中的偏压下,薄膜晶粒尺寸小,结构致密光滑,具有高的结合力、硬度、耐磨性以及低的接触电流噪音. 相比于电镀法,磁控溅射法制备的金膜表现出明显光滑致密的结构特征,硬度、磨损率和接触电流噪音大幅改善. 其中光滑致密的结构是抑制微电弧产生的关键因素,可有效减少电弧侵蚀失效.      

变宽截面箱梁剪力滞效应研究

将变宽度截面箱梁的剪力滞翘曲位移函数定义为三次抛物线形式,用能量变分原理建立了分析变宽截面箱梁剪力滞效应的控制微分方程,并用差分法求解此方程。分别计算了简支箱梁在集中荷载和均布荷载作用下的正应力,并用有限元法作了验证。将计算结果与等截面箱梁的应力进行对比,总结变宽箱梁剪力滞效应的分布规律。结果表明,均布荷载作用下,相对于等截面梁,变宽箱梁的顶板应力变化幅度更大,峰值更高,箱梁的顶板宽度变化对剪力滞效应影响较大;在集中荷载作用下,等截面与变宽度箱梁跨中截面的应力相近,应力分布曲线吻合较好,说明顶板宽度变化对剪力滞效应影响较小;分别在集中和均布荷载作用下,箱梁跨中截面应力均为正剪力滞分布状态。当箱梁顶板、底板和悬臂板宽度相等时,剪力滞效应控制微分方程也适用于等截面箱梁。     

A Facile Method to 1,4-Diacyl Semicarbazides: Syntheses of 1-Aryloxyacetyl-4-(4-Chlorobenzoyl)-Thiosemicarbazides and Semicarbazides

A facile method to diacyl semicarbazides is described. Reactions of 4-chlorobenzoyl chloride with ammonium thiocyanate first, then with aryloxyacetic acid hydrazides under phase transfer catalysis give 1-aryloxyacetyl-4-(4-chlorobenzoyl)-thiosemicarbazides (Ia-h). Compounds Ia-h on treatment with potassium iodate under reflux result in the formation of 1-aryloxyacetyl-4-(4-chlorobenzoyl)-semicarbazides (IIa-h) in excellent yields.     

Microwave Assisted Synthesis of 2-(4-Methoxylbenzoylamido)-5-Aryloxymethyl-1,3,4-Thiadiazoles

4-Methoxylbenzoyl chloride reacting with ammonium thiocyanate and aryloxyacetic acid hydrazides under phase transfer catalysis at room temperature gives 1-aryloxyacetyl-4-(4-methoxylbenzoyl)-thiosemicarbazides (Ia-m). Compounds Ia-m together with glacial acetic acid on exposure to microwave irradiation lead to the formation of 2-(4-methoxylbenzoylamido)-5-aryloxymethyl-1,3,4-thiadiazoles (IIa-m) in excellent yields.     

Microwave-assisted synthesis,crystal structure and toxicity of L-aspartic acid zinc spiral linear supramolecular polymer

~~Microwave-assisted synthesis,crystal structure and toxicity of L-aspartic acid zinc spiral linear supramolecular polymer~~     

A computer simulation of nucleation and growth of thin films

~~A computer simulation of nucleation and growth of thin films~~     

An Equivalent Condition for （K） Integrability of Fuzzy-valued Mappings

In this paper, we first discuss the relationship between the McShane integral and Pettis integral for vector-valued functions. Then by using the embedding theorems for the fuzzy number space E^1, we give a new equivalent condition for （K） integrabihty of a fuzzy set-valued mapping F ： [a, b] → E^1.     

Continuous Dependence of Bounded Φ-Variation Solutions on Parameters for Kurzweil Equations

The continuous dependence of bounded Φ-variation solutions on parameters for Kurzweil equations are established by using the functions of bounded Φ-variation that were introduced by Musielak-Orlice. These results are essential generalizations of continuous dependence of bounded variation solutions on parameters for Kurzweil equations.     

半线性椭圆型问题爆炸解的存在性与渐近行为

设Ω是RN（N≥3）中的C2有界区域,f是单调非减的非负连续可微函数满足f＇（a）∫a∞1/f（s）ds≤C0,　a>0.应用一种新型的非线性变换w（x）=∫u（x）∞　ds/f（s）将爆炸解问题△u=k（x）f（u）,u>0,x∈Ω,u|　Ω=∞转化成等价的带奇异项的Dirichlet问题,不仅得到了爆炸解问题解的最小爆炸速度,而且揭示了两类典型非线性爆炸解问题基本上是相同的.应用摄动方法,上下解方法得到了爆炸解的存在性.特别允许非线性项的系数不仅在Ω的内部子区域恒为零而且在Ω上可适当无界.随后再应用摄动方法,将所得结果推广到无界区域,得到了整体爆炸解的存在性以及在无穷远附近的最小爆炸速度（有关文献参见[1-33]）.