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给出了复函数的高阶微分中值公式,并利用Stirling数这个工具获得了该公式"中值点"的渐近性. 相似文献
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在水热条件下合成了一种具有Keggin结构的有机-无机复合的单铈取代夹心型磷钨酸盐[H2dap]2.5H5-[Ce(α-PW11O39)2].11.5H2O(1);利用元素分析、红外光谱和单晶X射线衍射表征了其结构.结果表明,化合物1属于三斜晶系,P-1空间群,晶胞参数为:a=1.254 9(7)nm,b=1.915 9(11)nm,c=2.129 0(12)nm,α=68.426(10)°,β=88.320(10)°,γ=89.853(10)°,V=4.758(5)nm3,Z=2,Dc=4.116g/cm3,GOOF=1.022,R1=0.111 2,wR2=0.218 9.化合物1分子由1个晶体学独立单铈取代夹心型[Ce(α-PW11-O39)2]10-磷钨酸多阴离子,2.5个双质子化的[H2dap]2+阳离子,5个质子及11.5个结晶水分子组成. 相似文献
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《Spectrochimica Acta Part B: Atomic Spectroscopy》2004,59(10-11):1675-1680
This work reports on the measurements of elemental profiles in teeth collected from patients with renal insufficiency. Elemental concentrations of Ti, Mn, Fe, Co, Ni, Cu, Zn, Se, Br, Rb Sr and Pb in different parts of teeth from patients with renal insufficiency are discussed and correlated with the corresponding values for healthy citizens. Both situations, patients with and without dialysis treatment were studied. The purpose of this work is to point out the influence of renal insufficiency together with long dialysis treatment, on teeth elemental content. An X-ray fluorescence set-up with microprobe capabilities, installed at the LURE synchrotron (France) was used for elemental determination. The resolution of the synchrotron microprobe was 100 μm and the energy of the incident photons was 19 keV. Teeth of citizens with renal insufficiency and those submitted since several years to dialysis treatment show a similar concentration with teeth of healthy subjects in what concerns the elemental distribution for Mn, Fe, Cu, Zn and Sr. However, higher levels of Pb were found in pulp region of diseased citizens when compared to values of healthy people. Very low concentrations of Ti, Co, Ni, Se, Br and Rb were found in all the analysed teeth. No difference was found in patients with and without dialysis treatment. 相似文献
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微晶酚酞预富集-分光光度法测定痕量Co(Ⅱ) 总被引:1,自引:0,他引:1
建立了一种以微晶酚酞作为固态吸附剂对样品中痕量的Co(Ⅱ)分离富集的新方法,富集后的co(Ⅱ)可直接用光度法测定。控制一定条件,Co(Ⅱ)能与常见阳离子Ni(Ⅱ)、Cd(Ⅱ)、Al(Ⅲ)、Ca(Ⅱ)、Mg(Ⅱ)、Pb(Ⅱ)、Mn(Ⅱ)、Fe(Ⅲ)、Bi(Ⅲ)等完全分离,且富集时基本不受SO4^2-、NO3^-、Br^-、Cl^-、I^-等阴离子影响。微晶酚酞对Co(Ⅱ)的吸附容量为23.5mg/g;富集因数可达200倍,回收率在97.6%以上,RSD为1.1%~2.3%。已用于环境水样及日常用水中Co(Ⅱ)的富集测定。 相似文献
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N-[5-(对三氟甲基苯基)-1,3,4-噻二唑-2-基]-N′-芳氧乙酰基硫脲的合成与生物活性 总被引:2,自引:1,他引:1
2-氨基-5-(对三氟甲基苯基)-1,3,4-噻二唑与芳氧乙酰基异硫氰酸酯反应,合成了10种新的芳氧乙酰基硫脲。其结构经1H NMR,IR和元素分析确证。初步的生物活性实验结果表明,部分化合物具有较好的植物生长调节活性。 相似文献
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MIAO Ti-Fanga ZHANG Jian-Fub LI Shuanga a 《结构化学》2005,24(10):1169-1175
1 INTRODUCTION Pyrazoline compounds have been widely used in industry due to their good photoconductivity and high fluorescence quantum productivity[1]. In recent years, pyrazoline derivatives with high vitrification temperature Tg have been found to act as hole trans- fer materials in the electroluminescence device, which has captured the intensive interest of che- mists[2]. But so far, the electron transfer mechanism of these compounds is still unclear[3~7]. Some resear- ches have attr… 相似文献
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