Pb_(1-x)Tb_xTi_(1-x)Mn_xO_3(0≤x≤0.10)固溶体的合成、结构与表征(英文)

用固相反应合成了Pb1-xTbxTi1-xMnxO3(0≤x≤0.10)固溶体,并用X射线粉末衍射进行了表征,室温下其空间群为P4mm.热分析仪测试结果显示,随着Tb和Mn掺杂量的增加,该固溶体的相变温度Tc降低.介电常数在Tc附近出现峰值,表明对应的相变是铁电相变.磁性测量显示,当x=0.08和x=0.10时,Pb1-xTbxTi1-xMnxO3分别在25和29 K附近有顺磁性向反铁磁性的转变.     

采用实时直接分析质谱法原位快速鉴别茶叶

采用近年来发展迅速的常温常压离子化技术——实时直接分析质谱法,建立了对茶叶中主要成分如茶氨酸、咖啡碱等的快速测定方法,通过特征的质谱信号离子,实现了对不同茶叶的快速鉴别。实时直接分析质谱法在大气压下进行,无需对茶叶进行任何的样品处理,大大缩短了分析时间,实现了原位、快速、准确且高通量的检测。     

阳离子和两性混合表面活性剂为模板合成三维六方介孔二氧化硅

用阳离子表面活性剂CnTAB(n=12,14,16,18)和两性生物表面活性剂SDG以8∶2的摩尔比混合作为模板剂,在酸性条件下晶化,碱性条件下老化合成了三维有序介孔二氧化硅。合成的产物用XRD、SEM、TEM和N2吸附进行表征。结果表明,在不同链长的表面活性剂CnTAB(n=12,14,16,18)中,C14TAB与SDG混合所得样品C14DG的有序度最好。而C16TAB和C18TAB与SDG混合所得样品的孔径约为9 nm。两性表面活性剂SDG对产物的形貌和三维六方结构都有影响。     

Palladium-catalyzed cross-coupling of polyfluoroarenes with simple arenes

The most efficient method to construct biaryls is the direct dehydrogenative cross-coupling of two different aromatic rings. Such an ideal cross arylation starting from distinct polyfluoroarenes and simple arenes was presented. The selectivity of the cross-coupling was controlled by both of the electronic property of fluoroarenes and steric hindrance of simple arenes. Diisopropyl sulfide was essential to promote the efficacy.     

Three critical points theorem and its application to quasilinear elliptic equations

In this paper, we prove a Pucci-Serrin type three critical points theorem for continuous functionals and study its application to quasilinear elliptic equations with natural growth.     

Design of controller for Lur’e systems guaranteeing dichotomy

In this paper, the problem of controller design for Lur’e systems guaranteeing dichotomy is investigated. On the basis of Kalman-Yakubovich-Popov (KYP) lemma and two frequency equalities, a new methodology for the dichotomy analysis of the Lur’e systems is proposed. A linear matrix inequality (LMI) based criterion is derived, which is equivalent to the Leonov’s frequency-domain one, while for the dichotomy analysis and synthesis which is more straightforward than the frequency-domain one. In virtue of this result, a dynamic output feedback controller ensuring the dichotomy property for Lur’e systems is designed. Finally a numerical example is included to demonstrate the validity and the applicability of the proposed approach.     

Approximation of bivariate copulas by patched bivariate Fréchet copulas

Bivariate Fréchet (BF) copulas characterize dependence as a mixture of three simple structures: comonotonicity, independence and countermonotonicity. They are easily interpretable but have limitations when used as approximations to general dependence structures. To improve the approximation property of the BF copulas and keep the advantage of easy interpretation, we develop a new copula approximation scheme by using BF copulas locally and patching the local pieces together. Error bounds and a probabilistic interpretation of this approximation scheme are developed. The new approximation scheme is compared with several existing copula approximations, including shuffle of min, checkmin, checkerboard and Bernstein approximations and exhibits better performance, especially in characterizing the local dependence. The utility of the new approximation scheme in insurance and finance is illustrated in the computation of the rainbow option prices and stop-loss premiums.     

Empirical likelihood for LAD estimators in infinite variance ARMA models

In this paper, we use an empirical likelihood method to construct confidence regions for the stationary ARMA(p,q) models with infinite variance. An empirical log-likelihood ratio is derived by the estimating equation of the self-weighted LAD estimator. It is proved that the proposed statistic has an asymptotic standard chi-squared distribution. Simulation studies show that in a small sample case, the performance of empirical likelihood method is better than that of normal approximation of the LAD estimator in terms of the coverage accuracy.     

Strain localization mechanism of interfacial failure in steel fiber/concrete specimens

The full strain field near the interface of steel fiber/concrete in a half-mold specimen was measured using a combined method of pullout test and digital image correlation. The strain localization mechanism of the interfacial failure is discussed. The strain distributions near the interface at a straight fiber under different loads show that the interfacial shear failure has a distinct characteristic of intervals in time and space directly related to the strain localization, which makes the interfacial failure initiate, develop and transfer successively. In particular, the local strain distributions around pores near the straight fiber interface demonstrate that the strain changes its sign at the irregular parts of the pore where the initial debonding took place and the deformation path is affected by the pore.