Statistical theory for hydrogen bonding fluid system of A a D d type (I): The geometrical phase transition

The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of A _a D _d type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed.     

新型AFM探针的制备及应用

采用熔拉 -腐蚀复合方法 ,将普通单模石英光纤制成直锥形光纤探针。利用自制工具将探针打弯 ,制成悬臂式光纤探针 ,在AFM上取得了较理想的测试结果。将自制光纤探针和商用硅材料探针获得的两种扫描图像进行了对比 ,分析了悬臂式光纤探针的特点     

Asymptotic distributions of nonparametric regression estimators for longitudinal or functional data

The estimation of a regression function by kernel method for longitudinal or functional data is considered. In the context of longitudinal data analysis, a random function typically represents a subject that is often observed at a small number of time points, while in the studies of functional data the random realization is usually measured on a dense grid. However, essentially the same methods can be applied to both sampling plans, as well as in a number of settings lying between them. In this paper general results are derived for the asymptotic distributions of real-valued functions with arguments which are functionals formed by weighted averages of longitudinal or functional data. Asymptotic distributions for the estimators of the mean and covariance functions obtained from noisy observations with the presence of within-subject correlation are studied. These asymptotic normality results are comparable to those standard rates obtained from independent data, which is illustrated in a simulation study. Besides, this paper discusses the conditions associated with sampling plans, which are required for the validity of local properties of kernel-based estimators for longitudinal or functional data.     

Charge density fluctuation of low frequency in a dusty plasma

The charge density fluctuation of low frequency in a dusty plasma, which is derived from the longitudinal dielectric permittivity of the dusty plasma, has been studied by kinetic theory. The results show that theP value, which describes the relative charge density on the dust in the plasma, and the charging frequency of a dust particle Ω _c , which describes the ratio of charge changing of the dust particles, determine the character of the charge density fluctuation of low frequency. For a dusty plasma ofP≪1, when the charging frequency Ω _c , is much smaller than the dusty plasma frequency ω_d, there is a strong charge density fluctuation which is of character of dust acoustic eigenwave. For a dusty plasma ofP≫1, when the frequency Ω _c , is much larger than ω _d there are weaker fluctuations with a wide spectrum. The results have been applied to the ionosphere and the range of radius and density of dust particles is found, where a strong charge density fluctuation of low frequency should exist.     

类金钢石非晶碳薄膜的光吸收和光致发光研究

我们用激光轰击石墨靶成功地制备出类金刚石无氢非晶碳薄膜.测量了光学吸收、光致发光及其随入射光强度的变化关系.结果表明,这种薄膜具有类金刚石的性质,光学带隙在1.67-2.25eV,发光在可见光区呈宽带结构.低激发强度下发光强度超线性变化,而在高激发强度下则为线性发光.我们用非成对载流子复合的模型对结果给出了合理的解释.用带尾态饱和的模型解释了发光峰值随激发光强增加而蓝移的现象.     

─族亚纯函数的正规定则

本文讨论亚纯函数族的正规性，推广并改进了杨乐￣［２，３］，陈怀惠￣［５］和朱秀蓉，龚向宏￣［７］等人的结果。     

教师课堂教学质量的多元统计分析

应用多元统计分析中的聚类分析法和主成分分析法对教师高等数学的课堂教学质量进行了统计分析,通过对数据的聚类分析结果提出教师应注重启发性教学并善于引导学生解决实际问题.同时利用主成分分析将原先众多的评价指标用三个指标代替,为进一步提高教学质量提供科学的依据.     

石墨-六角氮化硼微晶混合物与水高压反应产物分析

 利用球磨法制备石墨-六角氮化硼微晶混合物，并在6.1 GPa、800~1 500 ℃条件下与水进行高压反应，以便研究用水作触媒合成B-C-N三元化合物的可能性。通过对反应产物的XRD、XPS谱分析发现：高压下随着温度的升高，反应产物中出现再结晶石墨，其晶化程度逐渐提高；但没有出现再结晶六角氮化硼，也未出现立方氮化硼。在球磨不充分条件下，石墨-六角氮化硼混合物的XRD谱没有完全弥散，它们与水高压反应时，能观察到石墨与立方氮化硼分别结晶的现象，但都没有形成B-C-N晶化结构。     

Density functional theory study on antiferromagnetic interactions in a silver (I) complex of nitronyl nitroxide

A one-dimensional (1D) silver (I) complex of nitronyl nitroxide with fairly strong antiferromagnetic interaction, in which the metal ions are diamagnetic, is investigated by means of the ab initio crystal orbital method based on the density functional theory. The calculated values of the magnetic coupling constant (J) are close to the experimental measured J value in the periodic system. The magneto-structural correlation reveals that the existence of an antiferromagnetic coupling pathway along nitronyl nitroxide units via silver (I) ion in this system. The spin population distribution also shows the existence of spin delocalization along the ONCNO–Ag–ONCNO, which affords a rational interpretation for the antiferromagnetic interaction mechanism.     

串列加速器头部电极改进方案

通过改变头部电极的局部形状来改善头部电场, 运用Poisson程序计算几种可能形状下表面电场的分布, 并以此给出最佳的改进方案.