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Zhou X Xiong C Xu G Liu H Tang Y Zhu Z Chen R Qiao H Tseng YH Peng WP Nie Z Chen Y 《Journal of the American Society for Mass Spectrometry》2011,22(2):386-398
The potential distribution in the curved quadrupole is exactly characterized by the Laplace equation, and an approximate solution to the Laplace equation is calculated. We represent the Laplace equation under the coordinates named minimal rotation frame (MRF) and derive an expression on the hexapole and octopole superposition. Our conclusion is in agreement with the results by the numerical (SIMION) method. Based on the Poincare-Lighthill-Kuo (PLK) method reported in our previous work, the nonlinear effects of ion motion are investigated in detail. The frequency shift of ion motion can be well eliminated by coupling the hexapole component with a positive octopole component, and the transmission efficiency of ions is found to decrease dramatically with the increase of the ionic kinetic energy in the z-direction. Furthermore, the transmission characteristics of ions are discussed with regards to the phase-space theory. The results show that the centrifugally introduced axis shift is mainly responsible for the ion losses. A modified direct current (dc) voltage supply pattern is hence proposed to compensate for this effect. 相似文献
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In this article, the charge detection quadrupole mass spectrometry (CD-ITMS) driven by rectangular and triangular waveforms (rect-CD-ITMS and tri-CD-ITMS) was developed for the characterization of microparticles. Since the frequency scan of rectangular and triangular waveform could be realized easier than that of sinusoidal waveform, this research intends to provide simpler operation modes for CD-ITMS. In order to demonstrate the feasibility of rect-CD-ITMS and tri-CD-ITMS, the discharge onset voltage, ejection point of analyzed particles, and the achieved mass resolution were analyzed and compared with the case in conventional sinusoidal CD-ITMS (sin-CD-ITMS). The results indicated that the rect-CD-ITMS and tri-CD-ITMS can work well for the mass measurement of microparticles by using frequency scan. Identical mass resolutions were achieved under the same root mean square (RMS) voltage of different waveforms. The mass resolution was further improved by increasing the applied voltage and signal-to-noise ratio (S/N) of charge detector. Moreover, the rect-CD-ITMS and tri-CD-ITMS were applied to characterize red blood cells (RBCs). According to the obtained mean masses and mass distributions, normal and anemic RBCs were distinguished successfully. 相似文献
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A blind quantum signature scheme with χ-type entangled states is proposed, which can be applied to E-voting system. In this scheme, the particles in χ-type state sequence are used for quantum key distribution first, and then for quantum signature. Our scheme is characterized
by its blindness, impossibility of forgery, impossibility of disavowal. In addition, our scheme can perform an audit program
with respect to the validity of the verification process in the light of actual requirements. The security of the scheme is
also analyzed. 相似文献
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In ethanol, a mononuclear cobalt(Ⅱ) complex incorporating 2′-(2-Thienylidene)-2-Hydroxybenzoylhydra-zide has been synthesized and characterized by IR, UV-Vis, elemental analysis and X-ray crystal structure analysis. The crystal belongs to triclinic system, space group P1 with cell constant, a=1.230 69(10) nm, b=1.329 18(11) nm, c=1.330 56(11) nm, α=113.702(2)°, β=91.590(2)°, γ=100.846(2)°, V=1.944 4(3) nm3, Z=2, μ=0.662 mm-1, Dc=1.482 g·cm-3, F(000)=896, Rint=0.048 7. The crystal structure shows an anionic didentate ligand O and N donors in this work. The cobalt(Ⅲ) atom is hexacoordinated with oxygen atom from keto group and nitrogen atom from amide to form a cobalt atom for the core octahedral structure. CCDC: 748882. 相似文献
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机翼后缘噪声是飞机重要的机体噪声源之一。本文基于CFD(Computational Fluid Dynamic)数值模拟和Ffcows Williams-Hall理论,研究应用了一种预测干净机翼后缘气动噪声的方法。采用Menter’s SSTκ-ω湍流模型对翼型和机翼进行N-S方程数值模拟得到后缘附近的湍流特征速度和特征长度,再利用Serhat Hosder的预估方法计算后缘噪声强度级。本文首先计算了NACA0012翼型在7种不同状态的后缘噪声,计算结果与实验值比较,符合很好,从而证明了本文采用的方法的可行性和正确性;然后研究了两个亚音速翼型(NACA 0009,NACA 0012),两个超临界翼型(SC(2)- 0710,SC(2)-0714),EET机翼的不同参数对后缘噪声强度级的影响,得出了对降低后缘噪声有参考意义的结论。 相似文献
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