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101.
Teng Fu Tao Wang Hongfang Sun Yida Xu Zhen Dong Xiangke Guo Luming Peng Yan Zhu Zhaoxu Chen Weiping Ding 《中国科学:化学(英文版)》2018,61(8):1014-1019
A new mechanism of catalyst has been demonstrated in this article. With the interaction between carbon nitride (CN) and encapsulated nickel, the CN in the catalyst has been endowed with new active sites for the adsorption and activation of hydrogen while nickel itself is physically isolated from the contact with reactive molecules. For the selective hydrogenation of acetylene in large amount of ethylene, the catalyst shows excellent ethylene selectivity than the nickel catalyst itself, which is almost totally unselective. Meanwhile, the CN itself is inactive for the reaction. The results of characterization demonstrate that pyridinic nitrogen doped in the carbon matrix should be the active sites for hydrogen dissociative adsorption. The theoretical calculations further confirm the results and provide with the detail in the electron transfer between nickel and CN in the catalyst. The current results supply a new concept for design of high performance catalyst. 相似文献
102.
Hongxiao Hu Zhidong Teng Haijun Jiang 《Nonlinear Analysis: Real World Applications》2009,10(4):2420-2433
We study the permanence of a class of nonautonomous two-species Lotka–Volterra competitive systems with infinite delay and feedback controls. New results on the permanence of solutions are obtained. The corresponding results given in [F. Chen, Z. Li, Y. Huang, Note on the permanence of a competitive system with infinite delay and feedback controls, Nonlinear Anal. RWA 8 (2007) 680–687] are improved and extended. 相似文献
103.
Liang Zhang Jinghua Teng Soo Jin Chua Eugene A. Fitzgerald 《Applied Physics A: Materials Science & Processing》2011,103(3):827-830
Linearly polarized light from InGaN green light emitting diode grown on (0001) oriented sapphire is demonstrated by using
subwavelength metallic nanogratings. Polarization ratio can reach 7:1 (∼88%), the highest ever reported from a single light
emitting device. We discuss the design and fabrication of this device in detail. 相似文献
104.
105.
106.
Dr. Gui‐Chao Kuang Ming‐Jun Teng Prof. Xin‐Ru Jia Prof. Dr. Er‐Qiang Chen Prof. Dr. Yen Wei 《化学:亚洲杂志》2011,6(5):1163-1170
There is a delicate balance for a low‐weight molecule to behave as a gelator or crystal. The synthesis of two novel amino acid‐based naphthalene‐dendrons, Nap ‐ G1 and Nap ‐ G2 is described. Both dendrons display polymorphic properties in organic solvents. Nap ‐ G1 developed a fibrous network with β‐sheet architecture in cyclohexane but exhibited a spherulitic network in mixed solvents (chloroform/petroleum ether 1:5, v/v). On the other hand, Nap ‐ G2 acted as an efficient organogelator in chloroform but formed crystalline fibers in relatively high polarity solvents (such as acetone and methanol). Combinations of characterizations have been employed to study the polymorphism. 相似文献
107.
25 fs pulses with energy up to 0.8 mJ from a multi-pass amplifier system have been spectrally broadened from 460 nm to 950
nm due to strong self-phase modulation (SPM) effect in a gas filled hollow fiber. Using a set of chirped mirrors, the ultra-broadband
dispersion compensation was achieved, and the compressed pulses reached their transform limit. Under optimized conditions
we achieved pulses with duration of 5.1 fs and with energy of 400 μJ, corresponding to the peak power up to 80 GW.
Supported by the National Natural Science Foundation of China (Grant Nos. 60608003, 60490280, 60225005 and 60621063) 相似文献
108.
Venkatraman S Anand VG PrabhuRaja V Rath H Sankar J Chandrashekar TK Teng W Senge KR 《Chemical communications (Cambridge, England)》2002,(16):1660-1661
First successful syntheses and structural characterization of new core modified meso aryl azuliporphyrins by a simple [3 + 1] methodology are reported. 相似文献
109.
师同顺 《光谱学与光谱分析》1998,18(3):293-297
研究了香兰素对甲苯胺希夫碱及其金属配合物在3800-200 cm^-1范围的傅里叶变换红外光谱光谱,对主要谱带进行了经验归属。 相似文献
110.
光学介质表面波度的计算机模型 总被引:3,自引:1,他引:2
任一光学介质表面波度对光散射具有不可忽视的影响.本文对用激光轮廓仪所测物体表面曲线进行研究,运用傅里叶级数和最小二乘法拟合光学介质表面波形形态分布,建立了光学介质表面波度的计算机一维模型. 相似文献