全文获取类型
收费全文 | 298篇 |
免费 | 7篇 |
国内免费 | 2篇 |
专业分类
化学 | 250篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 2篇 |
物理学 | 50篇 |
出版年
2021年 | 2篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 2篇 |
2013年 | 22篇 |
2012年 | 8篇 |
2011年 | 5篇 |
2010年 | 7篇 |
2009年 | 8篇 |
2008年 | 6篇 |
2007年 | 9篇 |
2006年 | 9篇 |
2005年 | 15篇 |
2004年 | 17篇 |
2003年 | 25篇 |
2002年 | 14篇 |
2001年 | 5篇 |
2000年 | 2篇 |
1999年 | 6篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 2篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1972年 | 4篇 |
1971年 | 3篇 |
1968年 | 3篇 |
1967年 | 3篇 |
1962年 | 1篇 |
排序方式: 共有307条查询结果,搜索用时 31 毫秒
31.
Using p,p'-dimethoxydiphenyldiazomethane (DMDM) as initiator, the polymerization of methyl methacrylate (MMA) in benzene or in bulk was carried out. The initial rate of polymerization, Rp, was found to be expressed by the following equation: Rp = k[DMDM]0.53 [MMA]0.84 The polymerization was confirmed to proceed by a radical mechanism. The over-all activation energy for the polymerization in benzene was calculated as 19.3 kcal/mole. The rate of thermal decomposition of DMDM was also measured in benzene and the rate equation was obtained as follows: kd (sec?1) = 1.0 × 1015 exp (?29.1 kcal/RT) (for 50-80°C) Explanations of these observations are discussed in connection with those of the preceding papers. 相似文献
32.
Abstract The binary system of tetramethyl tetrazene (TMT) and Co(II) chloride was used as initiator of acrylonitrile (AN) in dimethylformamide. The initial rate of polymerization (Rp) was found to be expressed by Rp = k[TMT]0.62[Co(II) chloride]0.57 [AN]2.00 The polymerization was confirmed to proceed via a radical mechanism. The over-all activation energy for the polymerization was estimated as 15.1 kcal/mole. On the basis of these results and the product analysis of the reaction between the catalyst components in the absence of monomer, the initiation mechanism of the polymerization is discussed. 相似文献
33.
Synthesis of Substituted Phenyl Esters of Amino Acids and Polycondensation in Langmuirblodgett Films
Kenji Hanabusa Takekazu Oumi Toshiki Koyama Hirofusa Shirai Tadao Hayakawa Akio Kurose 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):1397-1413
Long-alkyl-chain phenyl esters of β-alanine, glycine, and L-valine were prepared, and their monolayer properties were correlated with their molecular structures. These compounds formed stable monolayers on acidic subphases. In particular, the p-hexadecylphenyl esters of β-alanine and glycine were remarkably stable, and their monolayers could be deposited on calcium fluoride plates as Y-type film by Blodgett's technique. The polycondensation of multilayers under an atmosphere saturated with triethylamine was investigated by changes in the IR spectra. It was determined that the polycondensation proceeded by a first-order reaction mechanism in the initial stage and that the rate in multilayers was faster than that in the bulk crystalline powder. These results suggest that the polycondensation is accelerated by a regular arrangement of the monomer in the multilayers, where the active sites are concentrated and located better for the polycondensation. In the case of the polycondensation in multilayers of the glycine ester, two kinds of condensation proceeded to afford poly(glycine) and 2,5-piperazinedione. 相似文献
34.
Several polyurethanes based on bis-(p-oxymethylphenyl) terephthalate (BOPT) were synthesized and studied with respect to some of their thermal properties. BOPT exhibits a mesomorphic phase at 252–264°C. Polymerization was carried out by equimolar reaction with hexamethyl-ene diisocyanate (HDI), 4,4-dicyclohexylmethane diisocyanate (H12MDI) α,α'-diisocyanate-1,3-dimethylcyclohexane (H6 XDI), 4,4′-diphenylmeth-ane diisocyanate (MDI), 2,4-tolylene diisocyanate (TDI), and phenylene diisocyanate (PDI). It became clear that polyurethanes obtained from BOPT with HDI, H12MDI, H6XDI, and TDI have mesomorphic phases at 243–291, 214–250, 172–229, and 180–234°C, respectively, as determined by DSC and polarized microscopy, and that all polyurethanes are crystalline as evidenced by x-ray diffraction. 相似文献
35.
The pigment, tecophilin, in blue flowers of Tecophilaea cyanocrocus was isolated and the structure was determined to be 3-O-(6-O-α-l-rhamnopyranosyl-β-d-glucopyranosyl)-7-O-(6-O-(4-O-(2-O-(4-O-β-d-glucopyranosyl-(E)-caffeoyl)-6-O-(4-O-β-d-glucopyranosyl-(E)-caffeoyl)-β-d-glucopyranosyl)-(E)-caffeoyl)-β-d-glucopyranosyl)delphinidin. The reproduction experiment of the same color as petals according to the results of chemical analysis and measurement of vacuolar pH of blue cells clarified that the blue color solely develops by tecophilin without interaction of metal ions nor co-pigments. 1H NMR analysis and CD spectrum indicate the co-existence of clockwise intermolecular self-association of the delphinidin nuclei and intramolecular π–π stacking between the chromophore and caffeoyl residues to derive bathochromic shift of the absorption spectrum and stabilize the color by preventing hydration reaction. 相似文献
36.
37.
Anisotropic optical absorption properties of single-walled carbon nanotubes (SWNTs) are determined from a vertically aligned SWNT film for 0.5-6 eV. Absorption peaks at 4.5 and 5.25 eV are found to exhibit remarkable polarization dependence and have relevance to optical properties of graphite. A method for determining a nematic order parameter for an aligned SWNT film based on the collinear absorption peak at 4.5 eV is presented, followed by the determination of the optical absorption cross section. 相似文献
38.
Kawai K Takada T Nagai T Cai X Sugimoto A Fujitsuka M Majima T 《Journal of the American Chemical Society》2003,125(52):16198-16199
The hole transfer causes the long-lived charge-separated state in DNA during the photosensitized one-electron oxidation of DNA. The combination of the transient absorption measurement and DNA damage quantification by HPLC clearly demonstrated that the yield of the DNA damage correlates well with the lifetime of the charge-separated state. 相似文献
39.
Shin‐Ichi Yusa Shigeki Awa Masanori Ito Takeshi Kawase Tadao Takada Kenichi Nakashima Dian Liu Shigeru Yamago Yotaro Morishima 《Journal of polymer science. Part A, Polymer chemistry》2011,49(13):2761-2770
Water‐soluble diblock copolymer, poly(N‐isopropylacrylamide)‐block‐poly(N‐vinyl‐2‐pyrroridone) (PNIPAMm‐b‐PNVPn), was found to associate with fullerene (C60), and thus C60 can be solubilized in water. The 63C60/PNIPAMm‐b‐PNVPn micelle formed a core‐shell micelle‐like aggregate comprising a C60/PNVP hydrophobic core and a thermoresponsive PNIPAM shell. The C60‐containing polymer micelle formation and its thermoresponsive behavior were characterized using light scattering and 1H NMR techniques. The hydrodynamic radius (Rh) of the C60‐bound polymer micelle increased with increasing temperature, which was ascribed to the hydrophobic association between dehydrated PNIPAM shells above lower critical solution temperature (LCST). 1H NMR data suggest that the motion of the PNIPAM block is restricted above LCST due to the dehydration of the PNIPAM shell in water. The generation of singlet oxygen by photosensitization by the C60‐bound polymer micelle was confirmed from photooxidation of 9,10‐anthracenedipropionic acid. Furthermore, DNA was found to be cleaved by visible light irradiation in the presence of the C60‐bound polymer micelle. Therefore, there may be a hope for a pharmaceutical application of the C60‐bound polymer micelle to cancer photodynamic therapy. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011. 相似文献
40.