含色心BaMgF4晶体电子结构的研究

运用相对论性的密度泛函离散变分法(DV-X)研究BaMgF4晶体中F型色心的电子结构.计算中采用冻结原子核的H原子模拟F心,在DV-Xα源程序增加H原子2p态,使F心激发态的计算结果在物理上更加合理.计算结果表明,F心的基态和激发态均出现在禁带中;并用过渡态的方法计算得到F心的电子从基态到激发态的光学跃迁能量为5.12eV,对应242nm处的吸收带,计算结果与实验结果吻合得很好,因此,推测F心在BaMgF4晶体中引起236～274 nm的吸收.     

Multiplesite structure and photoluminescence properties of Eu3+ doped MgO nanocrystals

MgO:Eu³⁺ nanocrystals with average diameter around 15 nm were prepared via a facile combustion method under a weak reductive atmosphere at temperature as low as 300°C. The photoluminescence spectra showed that the MgO:Eu³⁺ nanocrystals emit white light, the hypersensitive transition (⁵ D ₀→⁷ F _j of Eu³⁺) emission was prominent in the emission spectra resulting from the noinversion symmetry local site at which Eu³⁺ ions were located. Two kinds of luminescence sites of Eu³⁺ are identified by means of the fluorescence decay and site-selective spectroscopy. The excitation and absorption spectra indicated that the absorption of surface state decreased with the increase of Eu³⁺ concentration, meaning that the surface defect decreased through Eu³⁺ doping for some of them located at the disordered sites near the surface or absorbed at the surface of MgO host. Meanwhile, absorptivity and CIE chromaticity coordinates of all samples were measured; the results were in accordance with the excitation and absorption spectra and photoluminescence spectra, respectively.     

Diffraction inhibition in two-dimensional photonic crystals

We show the existence of flat equal-frequency contour across the entire first Brillouin zone in two-dimensional photonic crystals. Under this condition, light diffraction can be inhibited. Moreover, the beam can be highly localized between two neighboring rows of the defect-free photonic crystal. Such a finding may have novel applications in light beam manipulations and on-chip integrated photonic devices.     

双螺旋与中间搭接螺旋折流板换热器性能研究

采用数值模拟方法研究了40°螺旋角时螺旋折流板换热器双螺旋和中间搭接两种折流板布置形式对壳程性能与螺旋流动的影响,并与30°和40°螺旋角时单螺旋连续搭接结构的进行了对比.结果表明,40°螺旋角时双螺旋和中间搭接结构会强化壳程流体的螺旋流动,使同流量下壳程换热系数与压降增加,但同压降下的换热系数显著下降且均低于30°螺...     

A microfluidic chip integrated with a microoptical lens fabricated by femtosecond laser micromachining

We report on the integration of microlens and microfluidic channels in fused silica glass chip using femtosecond laser micromachining. The main process includes three procedures: (1) femtosecond laser scanning for forming a hemispherical surface and a Y-shaped channel in the fused silica glass; (2) chemical etching of the sample for removal of the modified areas; and (3) oxyhydrogen (OH) flame polish for smoothening the surface of the microlens. In addition, we demonstrate that the fabricated microlens exhibits good imaging performance with a 5× magnification, showing great potential in future lab-on-a-chip applications.     

A modular approach to the synthesis of 1,4,5-substituted-2-aminoimidazoles

Diversified 1,4,5-substituted-2-aminoimidazoles were rapidly assembled via sequential N–H insertion and Grignard addition to α-diazoesters. Lead compounds were identified as antibiotics against Gram-positive bacteria with an MIC value as low as 2 μg/mL.     

KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead-Bromide Framework Exhibiting Strong Second-Harmonic Generation Response

The discovery of new nonlinear optical (NLO) crystals with excellent properties is in urgently demand because of their ability to generate coherent light. Herein, we report an unique NLO lead bromide formate, KCs₂[Pb₂Br₅ (HCOO)₂], which has been synthesized by a mix-solvothermal method. KCs₂[Pb₂Br₅(HCOO)₂] exhibits strong phase-matching second-harmonic generation (SHG) response (6.5×KDP), large birefringence (0.16@ 1064 nm), and a wide transparent window in most visible light and mid-IR region. Interestingly, KCs₂[Pb₂Br₅(HCOO)₂] features a polar 3D lead-bromide framework in which adjacent Pb−Br layers containing coplanar Pb₆Br₆ rings are not only parallel to each other, but also orient in the same direction. These oriented arrangements are responsible for the strong SHG response and large birefringence that are elucidated by both local dipole moment and theoretical calculations. This research provides a new strategy to explore subsequent NLO crystals.     

A Novel Amperometric Nitric Oxide Sensor Based on Polythionine / Nation Modified Glassy Carbon Electrode

A novel amperometric sensor for the determination of nitric oxide was developed by coating polythionine / nafion on a glassy carbon electrode. This sensor exhibited a great enhancement to the oxidation of nitric oxide. The oxidation peak currents were linear to the concentration of nitric oxide over the wide range from 3.6×10-7 to 6.8×10-5 mol.L-1, and the detection limit was 7.2×10-8 mol.L-1. Experimental results showed that this nitric oxide sensor possessed excellent selectivity and longer stability. NO releasing from rat kidney was monitored by this sensor.     

电阻性鱼骨模理论

托卡马克等离子体中高能粒子可以激发一种称为鱼骨模的内扭曲模。现有鱼骨模理论是建立在理想磁流体近似基础上的，它预言有两支不稳定分支。对于高能粒子的比压值，ω≈〈ωｄｍ〉的一支（Ｃｈｅｎ－Ｗｈｉｔｅ分支）的激发阈值较高，而ω≈ω＊ｉ的一支（Ｃｏｐｐｉｚ分支）的激发阈值很低，因而对托卡马克等离子体的加热效率及约束非常不利。不过，我们发现，电阻效应对这支模有实质性的影响。本文详细分析了电阻性鱼骨模理论，给