Mass Spectral Fragmentation of (S,S)-N,N′-Bis [1-(hydroxymethyl)alkyl]anthracene/Naphthalene-1,8-dicarboxamides under Electron Impact Ionization Conditions

IntroductionN,N′-Bis [1-( hydroxymethyl) alkyl] dicarboxa-mides are important intermediates for the syntheses ofbis-oxazolines, which are a class of the most importantand widely used ligands in catalytic asymmetric reac-tions[1,2]. On determining the str…     

Studies on the Model Synthesis of the Brassinolide and Dolicholide‘s Side Chains

A highly stereoselective synthesis of the side Chain enantiomers of brassinolide and dolicholide through an aldol reaction of 2-(4-methoxy benzyloxyl) proplonylaldehyde (5) with the anion of 1- ( tert -butyldimethylsiloxy )-3-methyl-2-butanone ( 6 ) is described.     

利用模式的对称性研究光子晶体光纤的色散

由光子晶体光纤的对称性可以得到模式分布的对称性，根据模式的对称性选择适当的展开函数，可以使计算量大大减少。计算了六角结构光子晶体光纤的色散特性，得到了波长在1．55pm处色散为零时，光子晶体光纤的结构参量所满足的方程。     

可调谐液晶法-珀滤光片的研究

提出了一种可用于密集波分复用系统中的新型可调谐滤光片的设计方法,该设计利用了液晶的双折射现象,以及液晶盒内法-珀效应,从理论上分析了器件的光谱特性,计算了液晶分子的折射率调制和其分子转动角度的关系.并对器件进行了性能测试.实验结果与理论吻合较好.     

深能级杂质对光导半导体开关非线性特性的影响

建立了非线性GaAs光导开关深能级杂质瞬态模型的基本方程,获得了与实验现象定性吻合的电流输出,给出了平均载流子随时间演化的情况.分析结果表明,在考虑了深能级杂质的俘获、发射和碰撞电离后,有可能对非线性光导开关中发生的一系列现象做出解释,进一步的仔细分析将对非线性光导开关的设计和制作提供理论指导.     

半导体中多光子吸收跃迁速率的全量子理论分析

本文从非线性光学中辐射跃迁速率的表达式出发,在全量子理论下,导出了半导体中任意阶多光子吸收跃迁速率的一般表达式。理论分析结果表明,n光子吸收跃迁速率与光强的n次方和n阶光子相干度成正比。本文在多能带及二能带理论模型下,对多光子吸收跃迁速率的一般表达式进行了化简,并对非线性相互作用项对跃迁速率的贡献,作了讨论。     

Two New Diterpene Acetylxylosides from Aster veitchianus

Two new acetylxylosides,ent-manool-13-O-β-D-2′-acetylxylopyranoside(1)and entmanool-13-O-β-D-2′,4′-diacetylxylopyranoside(2)were isolated from Aster veitchianus.Their structures were elucidated by spectroscopic methods.     

Measurement of the neutron electric form factor via recoil polarimetry

The ratio G _e ⁿ /G _m ⁿ of the electric to the magnetic form factor of the neutron has been measured by analyzing the polarization of the recoiling neutron in quasi-elastic scattering of longitudinally polarized electrons from deuterium at the Q ² values of 0.45, 1.15, and 1.47 (GeV/c)². The experiment has been performed in Hall C of the Thomas Jefferson National Accelerator Facility. With G _m ⁿ being known G _e ⁿ can be deduced. The preliminary results show that the lowest Q ² points follow the Galster parametrization and that the 1.47 (GeV/c)² point rises above this parametrization.Received: 30 September 2002, Published online: 22 October 2003PACS: 13.40.Gp Electromagnetic form factors - 14.20.Dh Protons and neutrons - 24.70. + s Polarization phenomena in reactions