Baker＇s Yeast Mediated Reduction of Optically Active Diketone

Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products.     

多小波子空间上的单小波表示

本文在较弱的条件下,建立了2重多小波子空间与单小波子空间的关系.即由2重多小波构造出单小波.一方面,这种单小波的平移伸缩与2重多小波的平移伸缩生成的子空间是完全相同的;另一方面,它具有插值性.因此通过构造出的单小波建立了多小波子空间上的Shannon型采样定理.     

Boundedness of Multilinear Operators on Herz Type Spaces： Extreme Cases

In this paper, two classes of closely related multilinear singular and fractional integrals,which include the commutators as special cases, are studied and their boundedness on Herz type spaces is discussed. In fact, it is proved that these operators are actually not bounded in certain extreme cases.     

辐射加热金X光再发射时间测量

利用星光Ⅱ三倍频激光打双盘靶，研究了辐射加热材料的Ｘ光发射时间。激光脉冲能量４０～６０Ｊ、脉冲宽度６００～７００ｐｓ。通过两台时间关联的亚千Ｘ光能谱仪分别监测双盘靶初、次级发射Ｘ光谱，给出了辐射加热次级Ｘ光再发射时间。     

A jet appearing when a black hole event horizon touches the rindler horizon

The Hawking effect of a nonuniformly rectilinearly accelerating Kinnersley black hole is studied. Its horizons are rotationally symmetric. Its Hawking temperature depends not only on the time, but also on the polar angle. When a Kinnersley black hole touches its Rindler horizon, the Hawking temperature at the contact point is reduced to zero. But at the opposite pole of the black hole, the Hawking temperature increases rapidly. A jet appears as a tail of the accelerating black hole.     

Variational treatment for the dynamical pseudo Jahn-Teller system

We present a variational treatment for the E × e pseudo Jahn-Teller system. Through canonical transformation the electron and phonon states are decoupled. An analytical form is obtained for the ground state energy by scaling transformation. Including both the dynamical displacement of phonon modes and the softening of phonon frequency, this approach yields fairly accurate results for the ground state energy. The energy splitting and Ham's reduction factor are calculated, which also generates fairly good results compared with other perturbation results. We argue that our variational wave function is valid for the weak and intermediate coupling range.     

合浦珠母贝(Pinctada martensii,Dunker)珍珠囊体外预培育的初步研究

０．３％胰蛋白酶液（２５℃）消化外套膜组织的第５～１５ｍｉｎ时间段所收获的细胞产物中，表皮细胞具有最高的纯度和贴壁活性；细胞悬液的体外短期培养过程中小牛血清和珠母贝组织提取物对于细胞在体外的生长和在珠核表面的贴附具有促进作用．     

DISTORTION THEOREM FOR BIHOLOMORPHIC MAPPINGS IN TRANSITIVE DOMAINS (III)

The distortion theorem for biholomorphic convex mappings in bounded symmetric domains are considered. Especially the distortion theorem for biholomorphic convex mappings in classical domain of type IV and two exceptional domains are given.     

钙钛矿型复合氧化物LaNi_(1-x)Mn_xO_3晶体结构与催化性能的关系

用XRD、IR和TPR等技术研究了钙钛矿型复合氧化物的晶体结构及其反应性能.整个组成范围内,LaNi_(i-x)Mn_xO_3(0.0≤x≤1.0)体系都生成单一钙钛矿相;x=0.0,0.6≤X≤1.0时为菱形晶系,0.2≤x≤0.5为立方晶系.IR和TPR研究表明,晶体结构对B—O键合作用存在较大影响.CO微反考察表明,本体系的催化活性与晶系存在密切关系,晶体对称性越高,反应活性越低.说明钙钛矿型复合氧化物的催化活性与体系活性中心的B—O键合作用能力有关.     

裂解气相色谱质谱法研究增塑剂邻苯二甲酸二甲酯的热降解机理

用裂解气相色谱-质谱联用方法研究了橡胶产品中使用的增塑剂邻苯二甲酸二甲酯(DMP)在不同温度条件下的热裂解行为.对不同温度条件下裂解产物的分析表明,在初始阶段DMP的裂解产物主要为二氧化碳、苯、甲苯和苯甲酸甲酯.随着温度的升高苯甲酸甲酯进一步裂解成为分子质量更小的自由基,并发生稠环化反应形成更稳定的菲、蒽、间-联三苯、三亚苯等芳香族多环化合物.根据分析实验提供的裂解产物信息和有机物热裂解化学反应的原理对DMP的热裂解反应机理作了探讨,表明在废旧合成橡胶热裂解回收过程中,增塑剂DMP的高温裂解会产生多环芳烃污染物.应选择合适裂解工艺和裂解温度,以减少对环境的污染.