Comparison of Gasoline-Ranged <Emphasis Type="Italic">n</Emphasis>-Alkanes Conversions Using Dielectric Barrier Discharge: A Kinetic Study

Here, we compared the conversion of gasoline-ranged n-alkanes (C₆–C₉) using dielectric barrier discharge. For an energy density of ~68 J/L and an initial n-alkane concentration of ~230 ppm, when carbon number increased from 6 to 9, the energy efficiency of n-alkane conversion increased from 117 to 240 mmol/kWh, CO _x selectivity decreased from 46 to 20%, and ozone concentration increased from 216 to 240 ppm. The effect of energy density and initial n-alkane concentration were also investigated. The understanding of initial step of conversion was greatly aided by a proposed kinetic model. The pathways of consecutive reactions from the initiation to products were also discussed.     

浙江苍岭隧道岩爆工程地质特征分析与防治措施研究

根据在浙江苍岭隧道施工中发生的岩爆,通过现场地质观测资料,具体地分析了其形成的规模、位置、诱发因素以及地质条件,从地质工程的角度,对岩爆发生地段隧道的岩石组成、地质构造、地应力特征以及地下水情况进行了探讨,发现在苍岭隧道施工中发生岩爆的岩石具有岩体结构面发育适中、弹性模量大、P波波速高、地质构造简单、现代水平构造应力强且主压应力轴σ1大角度相交于隧道中轴线和地下水不发育的特征,并在此基础上,提出了掌子面喷水、布设释放地应力锚杆、减少隧道壁聚能结构等有效的岩爆防治措施。     

填料特性对聚乙烯基复合材料性能的影响

在高密度聚乙烯中分别添加粒状，纤维状和层状填料，制备了结构和性能不同的几种聚乙烯基复合材料。利用Ｃｅａｓｔ仪器化冲击试验机，Ｉｎｓｔｏｒｏｎ４３０２万能材料试验机，ＳＲＶ摩擦磨损试验机，ＭＨＫ－５００型环－块磨损试验机等，研究了填料的形态、性质对聚乙烯基复合材料之机械性能和摩擦磨损性能的影响。     

GCr15钢-CVDCr_7C_3镀层摩擦副摩擦振动的研究

本文系统地研究了GCr15钢球-CVDCr_7C_3镀层钢盘摩擦副滑动干摩擦引起的摩擦力(切向力)振动特性及其对材料摩擦磨损性能的影响。试件系统在垂直和水平方向上均处于低刚度、小阻尼状态。试验信号由微机采集、处理并进行频谱分析。结果表明,摩擦力振动的类型与正压力有关,而与拖动速度无关;摩擦力呈周期性自持振动时具有与相对滑动速度典型的非线性关系,振动频率接近(略低)于系统在切向的固有频率,而与拖动速度无关;摩擦力呈非平稳随机振动时,振动频率与系统在法向的振动频率有关,而与系统在切向的固有频率及拖动速度都无关;摩擦偶件运动的平稳性与摩擦力振动的类型有关,而与平均摩擦系数无关;摩擦力所耗费的能量与正压力呈比例关系。     

岩石爆破的粉碎区及其空腔膨胀

本文根据爆炸冲击波的理论分析,讨论了柱形装药和球形装药的粉碎区半径、炮孔近区的压缩比、爆破空腔及其空腔的发展时间。通过分析,给出柱形装药的爆炸近区参数。计算结果表明:2号铵梯岩石炸药柱形装药在岩石介质中产生的粉碎区半径一般是炮孔半径的1.65～3.05倍,球装药在岩石介质中产生的粉碎区半径是球形装药半径的1.28～1.75倍;柱形装药在孔壁处的冲击波波长与炮孔半径属于同一量级;粉碎区内的平均压缩比为1.05～1.10。     

α-Fe2O3空心球的水热法制备及其对苯酚的吸附性能

以铁氰化钾、磷酸二氢铵等为反应物,采用水热法合成了α-Fe₂O₃空心球,并用XRD,TEM,FESEM(场发射扫描电镜)、UV-Vis和低温氮吸附脱附对其进行了表征。结果表明,α-Fe₂O₃空心球直径在200～560 nm之间,其BET比表面积为80 m²·g^-1,平均孔径为8.5 nm。考察了反应时间、反应物用量和反应温度等对α-Fe₂O₃空心球形貌和大小的影响,提出了其可能的形成机理。研究了室温下α-Fe₂O₃空心球吸附苯酚的性能,吸附达平衡时,其吸附苯酚的量达97 mg·g^-1。     

Excited State Intramolecular Proton Transfer of New Diphenylethylene Derivatives Bearing Imino Group: A Combination of Experimental and Theoretical Investigation

In this paper, we described the synthesis and characterization of new diphenylethylene bearing imino group. We concentrated particularly on the investigation of the possibility of the excited state intramolecular charge transfer (ESIPT) of the new dyes experimentally and theoretically. The absorption and fluorescence spectroscopy of the dyes were determined in various solvents. The results showed that the maximal absorption wavelength of 2‐[(4′‐N,N‐dimethylamino‐diphenylethylene‐4‐ylimino)methyl]phenol ( C1 ) and 4‐[(4′‐N,N‐dimethylamino‐diphenylethylene‐4‐ylimino)methyl]phenol ( C2 ) exhibited almost independence on the solvent polarity. While as contrast, the maximal fluorescence wavelength of the dyes showed somewhat dependence on the solvent polarity. In particular, C1 displayed well‐separated dual fluorescence spectroscopy. The second fluorescence peak was characterized with an "abnormal" fluorescence emission wavelength in aprotic solvents with large Stokes shift (ca. 140 nm in THF), which was much more than normal Stokes shift (ca. 30 nm in THF). This emission spectroscopy could be assigned to ESIPT emission. On the other hand, the ESIPT fluorescence of C1 was much reduced or lost in the protic solvents. While, only normal fluorescence emission was detected in various solvents. Although the absorption maxima of C1 exhibited about 10 nm red‐shift with respect to those of C2 , the normal fluorescence maxima of C1 and C2 were almost identical in various solvents. These results suggested that C1 could undergo ESIPT, but C2 was not able to proceed ESIPT. The molecular geometry optimization of phototautomers in the ground electronic state (S₀) was carried out with HF method (Hartree‐Fock) and at DFT level (Density Functional Theory) using B3LYP both, while the CIS was employed to optimize the geometries of the first singlet excited state (S₁) of the phototautomers of C1 and C2 respectively. The properties of the ground state and the excited state of the phototautomers of C1 and C2 , including the geometrical parameter, the energy, the frontier orbits, the Mulliken charge and the dipole moment change were performed and compared completely. The data were analyzed further based on our experimental results. Furthermore, the absorption and fluorescence spectra were calculated in theory and compared with the measured ones. The rate constant of internal proton transfer (9.831×10¹¹ s^?1) of C1 was much lower than that of salicylidene methylamine ( C3 , 2.045×10¹⁵ s^?1), which was a typical Schiff base compound and was well demonstrated to undergo ESIPT easily under photoexcitation.     

Polyacrylamide hydrogels with phenylboronic acid moieties for the imprinting of proteins

<正>In this letter,N-acryloyl-3-aminophenylboronic acid(AAPBA) was synthesized and then examined as a new functional monomer for protein imprinting.It was allowed to be copolymerized with acrylamide to produce hemoglobin- or lysozyme-imprinted hydrogels.In template rebinding tests,the imprinted gels showed significant increase in the specific binding with the increase of the AAPBA amounts in the prepolymerization recipes.These results indicate that AAPBA may be a useful functional monomer for its moderate interactions with protein molecules.     

Retention behaviors of novel ionic liquid stationary phases and their selectivity for capillary gas chromatography

<正>One chloride-terminated ionic liquid(CTIL) and two hydroxyl-terminated ionic liquids(HTILs) were synthesized and used as stationary phases for capillary gas chromatography(CGC).Molecular interactions of these stationary phases were evaluated by Abraham solvation parameter model,indicating that the CTIL exhibits remarkably strong H-bond basicity and the HTILs possess both H-bond basicity and acidity.The molecular interactions were further confirmed by separation of a complex mixture consisting of ketones,aldehydes,esters,alcohols and aromatic compounds.It was found that the obtained solvation parameters correlate well with the chromatographic performances of the analytes in terms of elution order and resolution.The well correlated relationship between the solvation parameters and the selectivity of the CTIL and HTILs stationary phases is quite helpful in predicting and understanding the retention behaviors of different types of analytes on these stationary phases.     

Synthesis and Structural Characterization of Lanthanide Amides Stabilized by an N-Aryloxo Functionalized β-Ketoiminate Ligand

The synthesis and characterization of dimeric lanthanide amides stabilized by a dianionic N‐aryloxo functionalized β‐ketoiminate ligand are described in this paper. Reactions of 4‐(2‐hydroxy‐5‐tert‐butyl‐phenyl)imino‐2‐pentanone (LH₂) with Ln[N(SiMe₃)₂]₃(µ‐Cl)Li(THF)₃ in a 1:1 molar ratio in THF gave the dimeric lanthanide amido complexes [LLn{N(SiMe₃)₂}(THF)]₂ [Ln=Nd ( 1 ), Sm ( 2 ), Yb ( 3 ), Y ( 4 )] in good isolated yields. These complexes were characterized by IR spectroscopy, elemental analysis, and ¹H NMR spectroscopy in the case of complex 4 . The definitive molecular structures of complexes 1 , 3 , and 4 were determined. It was found that complexes 1 to 4 can initiate the ring‐opening polymerization of L‐lactide.