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101.
罗布麻活性成分与人血清白蛋白结合的光谱学研究 总被引:8,自引:0,他引:8
应用荧光和紫外光谱研究了人血清白蛋白与罗布麻活性成分槲皮素(QUE)、芸香苷(RUT)和儿茶素(CAT)的结合机理. 在QUE与蛋白质浓度比小于3.5时, 其荧光猝灭机理主要是静态猝灭, 在药物浓度较高时动态猝灭所占的比例增加; RUT在整个实验浓度范围内对蛋白质的荧光猝灭机理为静态猝灭; CAT与蛋白质之间不能形成复合物, 其荧光猝灭主要由动态猝灭产生. QUE和RUT分别与蛋白质形成1∶1的复合物, 结合常数分别为(1.51±0.13)×105和(0.81±0.08)×105 L•mol-1. 由于激发态质子转移, 与蛋白质的相互作用引起QUE和RUT内源荧光发射峰强度的明显增加, 进一步证实了它们与蛋白质的结合. 与蛋白质的结合也引起了QUE紫外吸收带的明显红移, 说明药物分子中的酚羟基发生了解离, 以离子形式与蛋白质发生作用. RUT的紫外吸收谱带没有明显移动, 说明它主要以中性状态与蛋白质结合. 应用与蛋白质作用后药物分子紫外吸收光谱的二阶导数谱, 对药物与蛋白质的结合模式进行了深入探讨. 相似文献
102.
应用仪器中子活化(INAA)、电感耦合等离子体原子发射光谱(ICP AES)和原子吸收光谱(AAS)对神华集团马家塔露天矿2-2#煤层中Hg、As、Se、Pb、Be、Cr、Cd、Ni、Th、U、Mn、Mo、Co、Sb和Br共15种有害痕量元素的质量分数进行测定。结果表明,绝大部分痕量元素的质量分数都明显低于中国煤中元素质量分数的平均值,只有Hg和Mn的质量分数偏高,其中Hg的质量分数异常高;通过分析痕量元素在煤层垂向剖面上的质量分数变化特性,揭示出痕量元素在煤层中分布的非均一性,分析了影响痕量元素分布与富集的因素;通过痕量元素之间以及与黄铁矿硫、Fe、Al、Ca、P的聚类分析,研究了痕量元素之间以及与煤中不同矿物组分之间的亲和特性。 相似文献
103.
应用原子吸收光谱法测定了内蒙古地产的笃斯茎、叶中的Cu,Fe,Zn,Mn,Ca,Mg等六种人体必需微量元素及宏量元素的含量。从而为评价笃斯的品质及其药理、药效提供了具有一定价值的数据。 相似文献
104.
Novel macrocyclic monooxa-diselkylene-1,ω-dioxy substituted calix[4]arene derivatives 1a-5a were synthesized by the reaction of calix[4]arene dibromides 1-5 with the disodium salt of bis(2-selenylethyl)ether in the yields between 28% and 64%. Their structures were characterized by proton and carbon NMR spectra. X-Ray structure analysis of la further confirmed the cone conformation of compounds 1a-5a. An interesting host-guest complex of la with dichloromethane via CH/π and C1/π interactions was elucidated. Extraction experiments showed that these novel monooxa-diselkylene-1,ω-dioxy substituted calix[4]arene derivatives 1a-5a had strong extraction ability towards mercury ion. The interaction of Hg^2+with the calix ligand has also been investigated by 1^H NMR titration. 相似文献
105.
Study of the rare and forbidden decays of η/η offers a sensitive probe to test fundamental symmetries of quantum chromodynamics and search for new physics beyond the Standard Model. To study the rare decays of η/η to π + π - e + e - , π + π - μ + μ - and e + e - μ + μ - at the BES detector, we developed several event generators based on the vector meson dominant model with finite-width corrections and the pseudoscalar mesons mixing theory. The various distributions from event generators are in good agreement with the theoretical predictions, which indicates that the event generators work very well after implemention in the BES Monte Carlo simulation package. In the BES physics analysis, the performance of the event generators will be improved in accordance with the distributions of different variables of η/η from data and the improvement on the theoretical calculations. 相似文献
106.
Studies on the Molecular Chain Conformation Stability of Aminated Konjac Glucomannan 总被引:2,自引:0,他引:2
Konjac glucomannan (KGM) was aminated by 2-chloroethyl-amine (CEA) as reagent so as to study the influence of concentration of CEA (based on the amount of KGM), concentration of NaOH, reaction time and temperature on the extent of amination. And the molecular simulation technology was adopted to analyze the conformation stability of aminate (AKGM). The results indicate that when the amount of CEA is higher, the extent of amination is higher. The optimum concentration of NaOH, reaction time and temperature are 10% NaOH, 70 ℃ and 45 rain, respectively. IR shows KGM is successfully aminated. The conformation of AKGM is in a random clew-like shape. 相似文献
107.
The research on aggregation-induced emission (AIE) has drawn increasing interests in the past decade. With the efforts scientists paid, a variety of AIE systems have been developed, among which the tetraphenylethelene and silole derivatives are the most studied. Development of new AIE systems could further enrich the AIE molecules and promote the development of AIE area. In this communication, we prepared a new AIE system based on 1,2,4,6-tetraphenylpyridinium ions according to the restriction of intramolecular rotation mechanism. These molecules could be facilely synthesized via one-step and one-pot reaction. The ionic AIE-active molecules could find wide application in sensing and optoelectronic areas. 相似文献
108.
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110.
A Simple Interconnection Layer for Tandem Organic Solar Cells with Improved Efficiency and Fill Factor 下载免费PDF全文
We demonstrate a simple interconnection layer (ICL) that can be employed in tandem organic solar cells. An ICL with an optimized structure of Ca/Au/MoO3 is used between two sub cells composed of identical regioregularpoly(3-hexylthiophen) (P3HT):[6,6]-phenyl C61-butyric acid methylester (PCBM) photoactive layers. Power conversion efficiency (PCE) of 3.24% and fill factor (FF) of 68.0% are achieved with such an ICL under simulated sunlight (1 O0 m W. cm- 2 ). Compared with the best values of devices with ICLs of Ca/Al/MoOa, PCE is improved by 68.9% and FF is improved by 15.5%. The improved performances are attributed to the optical and electrical balances in both sub cells. The presented ICL extracts free charges efficiently from both sub cells thereby suppressing the exaction recombination in each sub cell. 相似文献