MgO缺陷和不规则表面吸附Cl2的电子结构研究

采用从头算程序对MgO表面 3种不同配位位置吸附Cl2 的构型进行优化 ,并用扩展休克尔紧束缚 (EHT)晶体轨道方法对MgO的缺陷和不规则表面吸附Cl2的可能构型进行能带计算 ,讨论了吸附前后能带组成和成键性质的变化。研究表明 :MgO表面吸附Cl2 将更趋向于吸附在O原子上而非Mg原子上 ,而且在 3种配位中MgO表面三配位氧最有利于吸附Cl2 ;吸附时 ,电子从O原子转移到Cl2 分子的反键轨道 ,但是各种吸附构型的MgO表面对Cl2 的吸附作用均比较微弱 ,是典型的物理吸附。     

自发参量下转换双光子场的产生及其在光学计量中的应用

讨论自发参量魃光子场的产生机理，提出一种基于自发参量下转换双光子场绝在量子效率新方法。基于这一方法地光子计数型电倍增管的量子效率进行测量，并将实验结果与常规方法没得的结果进行比较。     

一个多因子信用违约互换定价模型

考虑一个违约互换的多因子的简化模型,通过测度的转化并求解一个多变量Riccati常微分方程而得出了这个模型的解析解.此模型是Duffie-Pan-Singleton(2000)模型的特例,但是这个模型存在解析解,而Duffie-Pan-Singleton模型并不存在解析解.模型的解析解对获得直觉的判断和进行模型的计算都非常有帮助,而且模型的解析解对实证检验也是有帮助的.     

Classical Risk Model with Threshold Dividend Strategy

In this article, a threshold dividend strategy is used for classical risk model. Under this dividend strategy, certain probability of ruin, which occurs in case of constant barrier strategy, is avoided. Using the strong Markov property of the surplus process and the distribution of the deficit in classical risk model, the survival probability for this model is derived, which is more direct than that in Asmussen（2000, P195, Proposition 1.10）. The occupation time of non-dividend of this model is also discussed by means of Martingale method.     

A 1.107 μm Yb3+-doped Phosphate Fiber Laser Pumped by a Ti:sapphire

Lasers and amplifiers in a single fiber have been developed rapidly, especially for optical fiber communication and various sensors, in the recent years. However, remarkable progress and achievement have been made mainly in silica fiber doped with rare earth elements. In this paper, we report the progress on the development of the Yb3+-doped phosphate fiber laser.     

钯-碳/NaHCO3催化下2,4-二氯嘧啶的区域选择性脱氯反应：一种合成2-氯嘧啶的有效方法

本文报道了一种合成2-氯嘧啶的有效方法。易得原料2,4-二氯嘧啶在钯-碳/NaHCO3作用下可以区域选择性地脱除2位氯原子得到2-氯嘧啶。2-氯嘧啶可以用作多种复杂嘧啶衍生物的有效合成砌块。     

A MIXED FINITE ELEMENT METHOD ON A STAGGERED MESH FOR NAVIER-STOKES EQUATIONS

In this paper, we introduce a mixed finite element method on a staggered mesh for the numerical solution of the steady state Navier-Stokes equations in which the two components of the velocity and the pressure are defined on three different meshes. This method is a conforming quadrilateral Q1 × Q1 - P0 element approximation for the Navier-Stokes equations. First-order error estimates are obtained for both the velocity and the pressure. Numerical examples are presented to illustrate the effectiveness of the proposed method.