Studies on Insoluble Species of Gd(Ⅲ)in Human Blood Plasma by Computer Simulation

The insoluble species of Gd ( Ⅲ ) in human blood plasma were investigated by computer simulation. The distribution of the Gd(Ⅲ ) species was obtained. It was found that most of the Gd( Ⅲ ) ions were bound to phosphate to form precipitate GdPO4 at the concentration of 1. 000 10-7 mol/L and when the concentration of the Gd (Ⅲ ) increased to 3. 750 X 10-4 mol/L, in excess of the concentration of phosphate, the Gd ( Ⅲ ) ions were bound to carbonate to form another kind of precipitate, Gd2(CO3)3.     

青冈林的能量生态研究Ⅲ.青冈林的能量损耗

运用红外线分析仪在室外研究了青冈林的能量损耗及其与生理、生态因子的关系．结果表明：能量损耗为2829587．46kJ／（m2·a）,其中呼吸能量损耗为76288．06kJ／（m2·a）,蒸腾能量损耗为2753249．40kJ／（m2·a）．能量损耗以七月份最高．呼吸能量损耗日变化基本上呈“单峰”,其主导因子为温度．但亦出现“午休”,其日变化类型表现为“双峰”曲线．蒸腾能量损耗速率的变化亦有“单峰”、“双峰”和“杂合”三种类型,其主导因子为空气相对湿度．     

原子吸收法测定江西十种中成药

采用火焰原子吸收法和石墨炉子吸收法分析了１０种中成药中２１种无机微量元素的含量。并对所含的无机微量元素及其效用进行了初探,说明了中成药的功效与其所含的无机微量元素有一定关联。     

ICP-AES法中稀土元素间的相互干扰的研究

稀土元素的谱线较复杂.相互间存在着不同程度的干扰.本文着重研究了ICP-AES法中,它们间的干扰情况,并用几种校正方法进行了比较.     

非线弹性平面杆系的应力应变分析

以指数函数近似表示非线弹性材料的应力－应交关系,推导出了非线弹性材料平面杆系结构应力应变计算的普遍表达式,编制了通用程序,使这一类问题有了一个通用的解题方法．     

高功率微波场磁光传感技术研究

 本文介绍一种利用磁光晶体记录特性进行高功率微波场矢量测量的传感技术。对返波管振荡器微波场的多点阵列测试表明,该传感系统对被测场无影响,抗干扰能力强,空间分辨率为0.001m,可测出场的主要模式成份TM₀₁、TE₀₁和TE₁₁,以及各成份的场强和功率,对总功率的估算值与喇叭耦合测量结果有较好的一致性。     

Electrospray ionization multiple-stage tandem mass spectrometric analysis of diglycosyldiacylglycerol glycolipids from the bacteria Bacillus pumilus

Electrospray ionization (ESI) combined with multiple-stage tandem mass spectrometry (MS(n)) was used to directly analyze the glycolipid mixture from bacteria Bacillus pumilus without preliminary separation. Full scan ESI-MS revealed the composition of picomole quantities of glycerolglycolipid species containing C(14)-C(19) fatty acids, some of which were monounsaturated. Two main components were identified from their molecular masses and fragmentation pathways. The fragmentation pathway of the known compound compared with the investigated compound verified the proposed structure as 1(3)-acyl-2-pentadecanoyl-3(1)-O-[beta-D-glucopyranosyl-(1-->6)-O-beta-D-glucopyranosyl]-sn-glycerols. A comparison of the multiple tandem mass spectra of the different alkali-metal cation adducts indicates that the intensity of fragments and the dissociation pathways are dependent on the alkali-metal type. The basic structures of glycerolglycolipids were reflected clearly from the fragmentation patterns of the sodium cations. The intense fragments of the sugar residue from the precursor ions were obtained from the lithiated adduct ions. ESI-MS(n) spectra of [M + K](+) ions did not provide as much fragmentation as [M + Na](+) and [M + Li](+) adducts, but their spectra allow the position of glycerol acylation to be determined. On the basis of MS(2) spectra of [M + K](+) ions, it was established that all components have a C(15:0) fatty acid at the sn-2 position of the glycerol backbone and C(14)-C(19) acids at the sn-1 position of the glycerol backbone. Copyright 1999 John Wiley & Sons, Ltd.     

Synthesis,Structure and Fluorescence Property of New Cd-MOFs Based on a Tetraphenylethylene (TPE) Ligand

A very stable Cd^Ⅱ-organic framework,{[Cd₃(Tipe)_1.5(bpodc)₂Cl₂]·(H₂O)₂}_n(compound 1,Tipe=1,1,2,2-tetrakis(4-(imidazol-1-yl)phenyl)ethene,bpodc=benzophenone-4,4-dicarboxylic acid),has been successfully synthesized under hydrothermal conditions.Compound 1 crystallizes in the triclinic system,space group P1^-,with a=12.289(3),b=15.951(4),c=20.755(5)?,α=81.248(2)°,β=83.905(2)°,γ=89.452(2)°,V=3998.2(17)?³,Z=2,M_r=1839.59,D_c=1.528 g/cm³,μ=0.925 mm^-1,F(000)=1844,R=0.0508 and wR=0.1571 for 13998 observed reflections(I>2σ(I)).Its overall structure is a three-dimensional stacking with a porosity of 10.1%based on a calculation by PLATON.Compound 1 shows a blue fluorescence emission with the peak maximum of 501 nm(λ_ex=397 nm)by ligand-to-ligand charge transfer of TPE chromophore.And it exhibits excellent performance in detecting Fe³⁺and Cr₂O₇^2-ions in aqueous solutions as a multi-response sensor.     

红外非线性晶体ZnGeP2的生长及品质研究

采用高温元素反应法直接合成ZnGeP2多晶料,用竖式Bridgman法生长出ZnGeP2单晶,晶体棒毛坯尺寸达φ15×70mm3.对多晶料和单晶体进行了X射线粉末衍射(XRD)、低倍率红外显微镜、红外分光光度计检测;对晶体切片进行退火处理,使得在2μm吸收系数降到α＝0.10cm-1;加工出一块5×6×6.5mm3的晶体倍频元件,在一台射频激励CO2激光器上实现了从9.24μm到4.26μm的倍频.     

自适应多分辨率方法在反应多相流数值模拟中的应用

将自适应多分辨率方法应用到刚性气体状态方程CJ模型的数值模拟,采用多相流问题的守恒锐利界面格式,通过level-set方法和虚拟流体方法来追踪和处理界面,能够很好地处理时间尺度较大的界面交互问题.利用金字塔型数据结构和多分辨率自适应方法,提高算法的存储效率和计算效率.给出一维和二维的数值算例,证明该算法在反应多相流数值模拟中的稳定性和高效性.