首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   368篇
  免费   26篇
  国内免费   45篇
化学   318篇
晶体学   3篇
力学   15篇
综合类   3篇
数学   23篇
物理学   77篇
  2023年   13篇
  2022年   19篇
  2021年   31篇
  2020年   26篇
  2019年   20篇
  2018年   12篇
  2017年   14篇
  2016年   28篇
  2015年   20篇
  2014年   25篇
  2013年   23篇
  2012年   44篇
  2011年   42篇
  2010年   13篇
  2009年   24篇
  2008年   11篇
  2007年   10篇
  2006年   15篇
  2005年   11篇
  2003年   5篇
  2002年   3篇
  2001年   2篇
  2000年   1篇
  1999年   4篇
  1997年   1篇
  1996年   8篇
  1995年   3篇
  1994年   1篇
  1993年   2篇
  1992年   2篇
  1990年   1篇
  1989年   1篇
  1987年   1篇
  1986年   1篇
  1983年   1篇
  1957年   1篇
排序方式: 共有439条查询结果,搜索用时 31 毫秒
81.
以教育部提出"卓越工程师教育培养计划"为契机,结合我校培养应用型人才的办学定位,根据我校电子信息工程专业的人才培养特点和所具备的办学基础,选择性参照实施该计划的模式,提出校企联合培养模式,推进课程建设和课程教学改革,以赛促学,促教,促改,学科专业一体化建设,加强双师型教师队伍的建设等一系列举措,建设具有鲜明特色的电子信息工程专业,培养具备较强实践能力和创新意识的电子信息工程应用型人才.  相似文献   
82.
A pH-responsive surface molecularly imprinted poly(ionic liquids) (MIPILs) was prepared on the surface of multiwall carbon nanotubes (MWCNTs) by a sol-gel technique. The material was synthesized using a 3-aminopropyl triethoxysilane modified multiwall carbon nanotube (MWCNT-APTES) as the substrate, bovine serum albumin (BSA) as the template molecule, an alkoxy-functionalized IL 1-(3-trimethoxysilyl propyl)-3-methyl imidazolium chloride ([TMSPMIM]Cl) as both the functional monomer and the sol-gel catalyst, and tetraethoxysilane (TEOS) as the crosslinking agent. The molecular interaction between BSA and [TMSPMIM]Cl was quantitatively evaluated by UV–vis spectroscopy prior to polymerization so as to identify an optimal template/monomer ratio and the most suitable pH value for the preparation of the MWCNTs@BSA-MIPILs. This strategy was found to be effective to overcome the problems of trial-and-error protocol in molecular imprinting. The optimum synthesis conditions were as follows: template/monomer ratio 7:20, crosslinking agent content 2.0–2.5 mL, temperature 4 °C and pH 8.9 Tris–HCl buffer. The influence of incubation pH on adsorption was also studied. The result showed that the imprinting effect and selectivity improved significantly with increasing incubation pH from 7.7 to 9.9. This is mainly because the non-specific binding from electrostatic and hydrogen bonding interactions decreased greatly with the increase of pH value, which made the specific binding affinity from shape selectivity strengthened instead. The polymers synthesized under the optimal conditions were then characterized by BET surface area measurement, FTIR, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The adsorption capacity, imprinting effect, selective recognition and reusability were also evaluated. The as-prepared MWCNTs@BSA-MIPILs were also found to have a number of advantages including high surface area (134.2 m2 g−1), high adsorption capacity (55.52 mg g−1), excellent imprinting effect (imprinting factor of up to 5.84), strong selectivity (selectivity factor of 2.61 and 5.63 for human serum albumin and bovine hemoglobin, respectively), and good reusability.  相似文献   
83.
The High Altitude Detection of Astronomical Radiation (HADAR) experiment is a refracting terrestrial telescope array based on the atmospheric Cherenkov imaging technique. It focuses the Cherenkov light emitted by extensive air showers through a large aperture water-lens system for observing very-high-energy γ-rays and cosmic rays. With the advantages of a large field-of-view (FOV) and low energy threshold, the HADAR experiment operates in a large-scale sky scanning mode to observe galactic sources. This study presents the prospects of using the HADAR experiment for the sky survey of TeV γ-ray sources from TeVCat and provids a one-year survey of statistical significance. Results from the simulation show that a total of 23 galactic point sources, including five supernova remnant sources and superbubbles, four pulsar wind nebula sources, and 14 unidentified sources, were detected in the HADAR FOV with a significance greater than 5 standard deviations (σ). The statistical significance for the Crab Nebula during one year of operation reached 346.0 σ and the one-year integral sensitivity of HADAR above 1 TeV was ~1.3%–2.4% of the flux from the Crab Nebula.  相似文献   
84.
A noble metal (NM) can stabilize monolayer-dispersed surface oxide phases with metastable nature. The formed "oxide-on-metal" inverse catalyst presents better catalytic performance than the NM because of the introduction of coordinatively unsaturated cations at the oxide-metal boundaries. Here we demonstrate that an ultrathin NM layer grown on a non-NM core can impose the same constraint on the supported oxide as the bulk NM. Cu@Pt core-shell nanoparticles (NPs) decorated with FeO patches use much less Pt but exhibit performance similar to that of Pt NPs covered with surface FeO patches in the catalytic oxidation of CO. The "oxide-on-core@shell" inverse catalyst system may open a new avenue for the design of advanced nanocatalysts with decreased usage of noble metals.  相似文献   
85.
86.
Du J  Hu M  Fan J  Peng X 《Chemical Society reviews》2012,41(12):4511-4535
Mild chemical processes of various analytes and detection methods involving revolutionary strategies in the fields of analytical chemistry, biology and environmental sciences have been extensively developed. This critical review focuses on representative examples of mild chemical processes that can be used in fluorescent chemodosimeters for ion sensing (anions and cations). A systematisation according to the type of reaction mechanism is established. Numerous examples including extensions combined with catalytic and material sciences applicable in fluorescence imaging and water treatment are also discussed (151 references).  相似文献   
87.
以3-甲基-1,3-间苯二酚和异戊醛为原料分别合成亲双烯2-甲氧基-6-甲基对苯醌和双烯1-甲氧基-3-异丙基-1,3-丁二烯,通过Diels-Alder反应,高区域选择性地得到桉烷类倍半萜骨架中间体2c.  相似文献   
88.
光纤传感器在微机电系统振动测量中的应用   总被引:4,自引:3,他引:1  
本文介绍的光纤传感器根据Michelson干涉仪的原理,通过测量相干光的干涉条纹的移动来测量反射面的位移.同时,利用宽带光源,采用相位跟踪技术测量极微小的位移和位移的方向.从而,既能测量nm级极微小的振动,也能测量mm级的振动.为了适应高频振动的测量,引入DSP充当数据处理系统的核心,提高处理速度.该光纤传感器设计巧妙,精度高,使用方便.  相似文献   
89.
本文在化学教师审美素质教育研究 (之一 ) (之二 )的基础上,从建构化学教师审美心理结构的角度,论述了化学教师审美素质培养的方法。  相似文献   
90.
研究桥联多核配合物的磁性不仅有助于了解桥联多核配合物在生物体内所起的各种生物功能,而且可为分子铁磁体的设计和合成提供信息.某些过渡金属配合物已显示了体外抗艾滋病和抗癌活性,有关桥联多核配合物在这方面的研究甚少.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号