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61.
Ersan Ronak Haj Alagoz Mehmet Abdullah Ertan-Bolelli Tugba Duran Nizami Burmaoglu Serdar Algul Oztekin 《Molecular diversity》2021,25(4):2247-2259
Molecular Diversity - In the present work, a series of bisbenzazole derivatives were designed and synthesized as antiproliferative agents. The antiproliferative activity of these compounds was... 相似文献
62.
Overview of finite elements simulation of temperature profile to estimate properties of materials 3D-printed by laser powder-bed fusion 下载免费PDF全文
Habimana Jean Willy 李辛未 Yong Hao Tan 陈哲 Mehmet Cagirici Ramadan Borayek Tun Seng Herng Chun Yee Aaron Ong 李朝将 丁军 《中国物理 B》2020,(4):98-109
Laser powder bed fusion(LPBF),like many other additive manufacturing techniques,offers flexibility in design expected to become a disruption to the manufacturing industry.The current cost of LPBF process does not favor a try-anderror way of research,which makes modelling and simulation a field of superior importance in that area of engineering.In this work,various methods used to overcome challenges in modeling at different levels of approximation of LPBF process are reviewed.Recent efforts made towards a reliable and computationally effective model to simulate LPBF process using finite element(FE)codes are presented.A combination of ray-tracing technique,the solution of the radiation transfer equation and absorption measurements has been used to establish an analytical equation,which gives a more accurate approximation of laser energy deposition in powder-substrate configuration.When this new analytical energy deposition model is used in in FE simulation,with other physics carefully set,it enables us to get reliable cooling curves and melt track morphology that agree well with experimental observations.The use of more computationally effective approximation,without explicit topological changes,allows to simulate wider geometries and longer scanning time leading to many applications in real engineering world.Different applications are herein presented including:prediction of printing quality through the simulated overlapping of consecutive melt tracks,simulation of LPBF of a mixture of materials and estimation of martensite inclusion in printed steel. 相似文献
63.
We obtained the azo‐imine ligand (2,2′‐[4‐(5‐methoxy salicylidene‐4‐iminophenylazo)phenylimino]diethanol) (HL) and its Cu (II) complex (CuL) from the ethanol solution. The complex Cu(L)2 was obtained as single crystals from the CH3OH solution and structurally characterized. The electronic and photoluminescence properties of the ligand and its Cu (II) complex were investigated both in DMF solution and solid state. The oxidation and reduction behaviours of the compounds were studied in the solution and found that the redox processes are irreversible. Thermal studies show that the ligand has higher thermal stability than the CuL complex. Single crystals of the complex were obtained from slow evaporation of a DMF solution of the complex. Crystals of the complex showed a diffraction pattern; however, the structure of the complex was able to be solved. 相似文献
64.
Positivity - In this paper we investigate the distance of convergence in measure whenever the measure is not $$\sigma $$ -finite and identify the topological coreflection of this approach structure... 相似文献
65.
Selma Bal Sedat Salih Bal Abdullah Erener Hatice Nur Halipci Seyhan Akar 《Chemical Papers》2014,68(3):352-361
Four water soluble azo dyes, 4-(isopropyl)-2-[(E)-(4-chlorophenyl)diazenyl]phenol (L 1), 4-(isopropyl)-2-[(E)-(2,4-dichlorophenyl)diazenyl]phenol (L2), 4-(sec-butyl)-2-[(E)-(4-chlorophenyl) diazenyl]phenol (L 3), 4-(sec-butyl)-2-[(E)-(2,4-dichlorophenyl)diazenyl]phenol (L 4), and their Cu(II) and Ni(II) complexes were synthesized and characterized using spectroscopic methods. Examination of their thermal stability revealed similar decomposition temperature of approximately 260–300°C and that they were more thermally stable than their metal complexes. Ni(II) complexes of ligands L2 and L4 were more stable than the other coordination compounds. Among the synthesized ligands, L2 and the complexes Cu(L3)2 and Ni(L4)2 showed both antimicrobial and antifungal activity. However, the other ligands and the complexes were poorly active against selected microorganisms. 相似文献
66.
67.
A novel amperometric hydrogen peroxide biosensor based on pyrrole-PAMAM dendrimer modified gold electrode 总被引:1,自引:0,他引:1
Horseradish peroxidase (HRP) was immobilized into an electrochemically prepared copolymer of pyrrole–PAMAM (PAMAM; polyamidoamine) dendrimers for the construction of amperometric hydrogen peroxide biosensor. First, second, and third generation amidoamine–pyrrole dendrons having branched amine periphery and focal pyrrole functionality were synthesized via divergent pathway. Pyrrole dendrimers were covalently attached onto the electrode surface and polymerized by electrochemical copolymerization with pyrrole monomer. The synthesized dendrimers and copolymers have been characterized by FTIR-ATR and NMR. These copolymers have been utilized as conducting films for amperometric hydrogen peroxide sensing. The HRP retains its bioactivity after immobilization into the dendronized pyrrole-copolymers. Amperometric response was measured as a function of concentration of hydrogen peroxide, at fixed potential of +0.35 V vs. Ag/AgCl in a phosphate buffered saline (pH 7.5). The effect of pH and temperature of the medium, storage, and reusability properties were investigated. The results indicate an efficient immobilization of enzyme onto the PAMAM type dendrimer modified surface containing pyrrole monomer, which leads to high enzyme loading, and increased lifetime stability of the electrode. 相似文献
68.
Radiation induced copolymerizations of electron donating such as allyl phenol (AP) and electron withdrawing such as allyl isothiocyanate (AITC) monomers with styrene (Sty) as a comonomer were studied in order to correlate the electronic behavior with copolymerization yield and molecular weight. The allyl monomers and comonomer were mixed in the same mol ratios under Ar atmosphere and copolymerized by using gamma radiation in various absorbed doses (55, 110, 165 kGy) obtained from a Co-60 source. Poly(AP-co-Sty), and poly(AITC-co-Sty) could have been prepared at all of the absorbed doses. The maximum copolymerization yields were calculated as a 16.35 and 6.52 percent for poly(AP-co-Sty) and poly(AITC-co-Sty), respectively. The molecular weights of poly(AP-co-Sty) copolymers are found to be higher in comparison to those of poly(AITC-co-Sty). Both results indicate that, under the same irradiation conditions, AP is more reactive on styrene than AITC is. Thus, the monomers having electron withdrawing (EW) substituents attached to allyl group may result in better copolymerization yield and molecular weight than those with electron donating (ED) substituents. Thermal stabilities of the poly(AP-co-Sty) copolymers are also higher than those of poly(AITC-co-Sty). 相似文献
69.
The syntheses of four aza-15-crown-5 ethers bearing phenyl and phenoxymethyl moieties attached to a stereogenic centre on the crown ring were achieved. Macrocycles have exhibited strong binding ability (Ka = 5364–12,969 M? 1) and modest enantiomeric discrimination towards the enantiomers of amino acid methyl ester salts by UV titration method in CHCl3 at 25°C. Computer modelling results supported experimental data providing a detailed understanding of the molecular recognition mode between hosts and guests and the likely binding sites involved. Macrocycles were used for chiral discrimination of amino acids in their zwitterionic forms or as potassium and sodium salts in transport experiments across a bulk chloroform membrane with satisfactory selectivity. 相似文献
70.