三角架结构席夫碱单核稀土配合物的合成、表征以及配体的抗氧化性

三角架结构席夫碱单核稀土配合物的合成、表征以及配体的抗氧化性     

含C60的聚电解质自组装膜微摩擦性能的研究

通过自由基引发溶液聚合反应,合成星状C₆₀-苯乙烯-丙烯酸聚合物,其钠盐作为高聚物负离子,与高聚物正离子的重氮树脂在云母上自组装成膜,利用紫外光照射反应,使膜层间连接的离子键转化成共价键.用原子力显微镜(AFM)和摩擦力显微镜(FFM)研究了不同链长和不同层数自组装膜的表面形貌及微摩擦性能.     

具有周期输入Hopfield型神经网络的全局渐近性质

在不假定非线性激励函数有界和可微的条件下,应用Mawhin的重合度理论及Liapunov函数法给出一类具有周期输入的Hopfield型神经网络存在周期解及其全局指数稳定的充分条件。     

风暴潮流运动的数值模拟

采用风暴潮全流运动方程组,对标准海域的风暴潮流运动进行数值模拟,利用以往的计算结果验证了数值模式,研究了开阔海域中,风暴气压、海域深度及底坡变化对风暴增水及流场的影响,分析了流速、潮位随时间和空间定量变化的规律。所建立的数值模型是进一步研究风暴潮流场中物质输运的基础。     

Aerodynamic force and flow structures of two airfoils in flapping motions

Aerodynamic force and flow structures of two airfoils in a tandem configuration in flapping motions are studied, by solving the Navier-Stokes equations in moving overset grids. Three typical phase differences between the fore- and aftairfoil flapping cycles are considered. It is shown that: (1) in the case of no interaction (single airfoil), the time average of the vertical force coefficient over the downstroke is 2.74, which is about 3 times as large as the maximum steady-state lift coefficient of a dragonfly wing; the time average of the horizontal force coefficient is 1.97, which is also large. The reasons for the large force coefficients are the acceleration at the beginning of a stroke, the delayed stall and the “pitching-up” motion near the end of the stroke. (2) In the cases of two-airfoils, the time-variations of the force and moment coefficients on each airfoil are broadly similar to that of the single airfoil in that the vertical force is mainly produced in downstroke and the horizontal force in upstroke, but very large differences exist due to the interaction. (3) For in-phase stroking, the major differences caused by the interaction are that the vertical force on FA in downstroke is increased and the horizontal force on FA in upstroke decreased. As a result, the magnitude of the resultant force is almost unchanged but it inclines less forward. (4) For counter stroking, the major differences are that the vertical force on AA in downstroke and the horizontal force on FA in upstroke are decreased. As a result, the magnitude of the resultant force is decreased by about 20 percent but its direction is almost unchanged. (5) For 90°-phase-difference stroking, the major differences are that the vertical force on AA in downstroke and the horizontal force on FA in upstroke are decreased greatly and the horizontal force on AA in upstroke increased. As a result, the magnitude of the resultant force is decreased by about 28% and it inclines more forward. (6) Among the three cases of phase angles, inphase flapping produces the largest vertical force (also the largest resultant force); the 90°-phase-difference flapping results in the largest horizontal force, but the smallest resultant force.     

铒掺杂富硅热氧化SiO2/Si发光薄膜的显微结构

利用金属蒸气真空弧 (MEVVA)离子源将稀土元素Er离子掺杂到富硅热氧化SiO2 /Si薄膜中。卢瑟福背散射 (RBS)和X 射线电子能谱仪 (XPS)分析表明 ,Er浓度可达原子百分数 (x)～ 10 ,即Er的原子体浓度为～ 10 2 1·cm-3 。XPS研究发现 ,随着Si注量增大 ,退火态样品表面硅含量增多 ,热氧化硅含量减少。反射式高能电子衍射 (RHEED)和原子灵敏度因子法 (AFM)研究表明 ,样品表面没有大量Er析出或铒硅化物形成 ,退火后表层中Si外延再生长、有针状微晶硅颗粒形成。在 77K及室温下 ,研究了Er掺杂富硅热氧化SiO2 /Si薄膜的近红外区 1 5 4μm附近光致发光光谱     

混合Heisenberg自旋体系动态相变的滞后标度

采用Monte Carlo方法对离散混合经典Heisenberg自旋体系在周期性外场驱动下动态相变行为进行了模拟计算.在典型Heisenberg自旋体系的哈密顿量基础上,引入表征非晶相的随机各向异性能项(比例为X)和表征晶体相的单轴各向异性能项(比例为1-X),考察了该混合自旋体系磁滞后回线面积A_area随X和单轴各向异性常数A及随机各向异性常数D的变化规律,并确定了该类自旋体系动态相变新的滞后标度关系A_area-A^δD^{η关键词： 海森堡模型 Monte Carlo模拟 磁滞标度 非晶纳米晶}     

卡维地洛印迹聚合物的合成及其识别性能的研究

以卡维地洛药物分子为模板,甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂,采用紫外光引发聚合的分子印迹技术,成功制备出卡维地洛分子印迹聚合物。用热重分析、扫描电镜对聚合物进行了表征,通过Scatchard方程研究了印迹聚合物对模板分子的结合特性。结果表明,在所研究的浓度范围内,印迹聚合物存在一类等价的结合位点,并计算出印迹聚合物与模板分子的平衡离解常数为0.5642 mmol/L,最大表观吸附量为97.44μmol/g,为理论值的63.53%。对不同底物的结合实验表明,该聚合物对卡维地洛具有优良的吸附选择性。     

基于截断δ-冲击模型的不完全维修更换策略

本文在截断δ-冲击模型的基础上,考虑了因系统劣化而导致的冲击失效门限值与维修时间的变化,扩充失效状态,从而提出一种新的截断δ-冲击模型。以最小费用为目标,稳态可用度为约束条件,建立N型更换策略的不完全维修更换策略模型,并给出三种常用冲击到达间隔分布的期望寿命。最后通过算例验证模型的有效性,并对参数进行灵敏度分析。     

光电耦合对InGaN/GaN量子阱光学性能的影响

围绕高性能GaN基垂直腔面发射激光器(VCSELs),设计了两种具有不同光电耦合强度的InGaN/GaN量子阱(QWs)样品,研究了它们的光学性质。样品A在腔模的两个波腹处各放置两个InGaN耦合量子阱,而样品B在腔模的一个波腹处放置5个InGaN耦合量子阱。计算表明样品A具有较大的相对光限制因子1.79,而样品B为1.47。光学测试发现样品A有着更高的内量子效率(IQE)和更高的辐射复合效率。使用两种样品制作了光泵VCSEL结构,在光激发下实现激射,其中基于样品A的VCSEL有着更低的激射阈值。结果表明有源区结构会显著影响量子阱与光场的耦合作用、外延片的内量子效率、辐射复合寿命和VCSEL激射阈值,同时也说明样品A的有源区结构更有利于制作低阈值的VCSEL器件。