含吩噻嗪金属配合物的合成及非线性光学性质研究

本文报道了一种新的配体:10-乙基-3-甲酰吩噻嗪缩肼基二硫代甲酸甲酯(HL)及其金属配合物的合成。采用了元素分析、质谱、核磁共振、红外光谱对配体及其金属配合物进行了表征。此外,并应用紫外、荧光和Z-扫描技术,测定了配体及其金属配合物的荧光最佳发射波长(λ_max^em)、荧光量子产率(Φ_f)、寿命(τ)和非线性光学性质。结果表明它们在DMF溶液中都能发射出较强的橄榄色荧光,配体及其金属配合物都有双光子吸收,并且金属配合物的非线性光学效应比配体明显增强。用半经验量子化学方法(RHF/PM3)计算结果与实验值较为吻合。     

以NaBrO_3/H_2SO_4氧化体系合成己二酰-1,′6′一双(4-卤偶氮苯)

取代酰肼化合物是制备偶氮化合物的原料,是一种非常重要的有机化合物,具有广泛的应用价值。它可以和金属形成稳定络合物,对聚烯烃等高分子材料的“铜害”有良好的防护,因而在电线、电缆、钢丝、轮胎等与铜及其它重金属相接触的高分子工业制品中得到广泛应用,被称为金属减活剂[2     

制备2，2′，4，4′-联苯四甲酸的新方法

氨基甲基苯甲酸;联苯四甲酸;合成;偶联;重氮盐     

POLYMER-PLATINUM COMPLEX CATALYSTS FOR OXIDATION OF METHANOL TO FORMALDEHYDE

Two kinds of polymer-platinum complexes: silica-supported poly-γ-diphenylphosphinopropylsiloxane-platinum complex and silica-supported polyphenylsilazane-platinum complex, have been found very active and selective in catalyzation of oxidation of methanol to formaldehyde at room temperature and under an atmospheric oxygen pressure. Their catalytic activities are greatly affected by P or N/Pt gram atomic ratio.     

RECOGNITION SEQUENCE SPECIFICITY OF SIGNAL PEPTIDASE I AND THE ROLE OF SIGNAL PEPTIDE IN SECRETION OF PROTEIN IN Bacillus subtilis

By recombinant DNA technology, the N-terminal of the β-protein encoding region of plasmid pUBHO is fused with the structure gene of α-amylase from Bacillus licheniformis. This gene fusion is called βAmy. It is able to transcribe and translate in phase. Protein fusion can be secreted into the medium mediated by β-signal peptide. The efficiency of secretion is about 10% of the synthesized pre-α-amylase. By comparing the secretion capacities and analysing the restriction sites on β-Amy genes and the molecular weights of the mature α-amylase secreted by B. subtilis harbouring different plasmids, it is indicated in vivo that the recognition and cleavage sequence for signal peptidase I of B. subtilis is Ala-Ala-Ala Ala. The results also indicate that the secretion of the α-amylase in B. subtilis is in accordance with the post-translational transportation mode.     

四氢键二聚体和分子组装

介绍了最近几年新的四氢键有机二聚体研究的进展及其在分子自组装和分子聚 集体化学研究中的应用。     

泡沫铅对VRLA电池负极活性物质结构及性能影响

0引言随着36V/42V汽车电源系统的提出,新一轮汽车用电池的竞争不断加剧。从目前情况看,铅酸电池由于具有成本低廉,使用可靠,原材料来源丰富,铅回收率可高达98%等优点,因此成为电动车电源最实际的选择之一[1]。但作为电动车用电池,需要克服其比能量低、充电接受能力差和负极硫酸盐化等缺点。为此各国科学家开展了大量的研究工作。最近报道用铸造多孔体作为敞口铅酸电池的集流体,它的比表面积为14cm2·cm-3,正极活性物质利用率上升到50%,远高于传统的铸造板栅[2]。在铅酸电池集流体研究领域里另一个重大进步,就是以R V C(R etic-ulated V i…     

甲烷磺酸盐的合成、表征及其催化酯化反应的性能

Methane-sulfonate of copper, cobalt, zinc, lanthanide, praseodymium and neodymium are synthesized and characterized by FTIR and TGA. Methane-sulfonates are used as the catalysts in the esterification of chloroacetic acid with isopropanol. Catalytic activity of methane-sulfonates is studied and compared with other Lewis acids. Under the condition of 1.2/1 molar ratio of isopropanol to chloroacetic acid, 1% catalyst (molar percent of chloroacetic acid), 2.5h reaction time, 80～85℃ temperature and benzene as water-carrying agent. The experi-mental results showed that catalytic activity of Lanthanide methane-sulfonate was the best, the yield of isopropyl chloroacetate reaches 88.7%. Copper methane-sulfonate can be reused for three times without distinct loss of catalytic activity.     

滂胺天蓝-氨基糖苷类抗生素的显色反应及其分析应用

在 pH2.0～7.0的条件下 ,滂胺天蓝(PSB)与硫酸卡那霉素(KANA)、硫酸庆大霉素(GEN)和硫酸新霉素(NEO)等氨基糖苷类抗生素反应生成蓝色离子缔合物 ,最大显色波长位于686～690nm ,线性范围分别为0～14.0、0～12.5、0～14.0mg/L ,摩尔吸光系数(ε)分别为1.53×104、1.12×104、1.47×104L/(mol·cm) ;最大褪色波长位于620～622nm ,线性范围分别为0～14.0、0～12.0、0～14.0mg/L ,摩尔吸光系数(ε)分别为1.41×104、1.43×104、2.42×104L/(mol·cm) ;当用双波长叠加法测定时 ,ε值分别为2.94×104、2.55×104、3.89×104L/(mol·cm) ;探讨了适宜的反应条件 ;该法用于市售药物中氨基糖苷类抗生素含量的测定 ,结果令人满意