固定漆酶聚苯胺-CoC2O4纳米复合物修饰电极的直接电化学

采用循环伏安法、微分脉冲伏安法、交流阻抗谱以及计时电流法等电化学方法,结合红外光谱、紫外-可见分光光度法、原子力显微镜、透射电子显微镜以及原子吸收光谱等辅助手段,表征了固定漆酶的聚苯胺-草酸钴纳米复合物的化学组成、结构和形貌,测试了纳米复合物固酶前后的导电性能的变化,研究了纳米复合物修饰电极上固定漆酶的直接电化学行为,评估了该电极的催化氧还原效能以及作为电化学传感器检测氧分子的性能。实验结果表明该电极在不含电子介体的溶液中以酶活性中心T2作为首要电子受体,将得到电子传递给化学吸附的氧气使其被电还原,其表观电子迁移速率为0.017 s~(-1),且具有良好的催化氧还原性能(氧还原起始电位:460 m V vs NHE,转化氧分子为水的表观速率常数为2.6×10-4 s~(-1)),酶电催化氧还原为水分子步骤为反应的速控步。该电极作为电化学传感器对氧具有极低检测限(0.20μmol·L~(-1)),宽线性响应范围(0.4~7.5μmol·L~(-1))以及对底物高亲和力(KM=122.4μmol·L~(-1))等优势。     

(Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ-Ce0.9Gd0.1O2-δ复合阴极的制备及电化学性质

采用EDTA-柠檬酸盐法制备了(Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ(PLNCG),并与Ce0.9Gd0.1O2-δ(CGO)形成复合阴极PLNCG-CGO。XRD和SEM分析结果表明PLNCG与CGO在1 000℃具有较好的化学相容性。电化学阻抗测试结果表明PLNCG-30%CGO复合阴极在700℃的极化电阻为0.092Ω·cm2;过电位为39.3 m V时,电流密度达到113.3 m A·cm-2。氧分压分析表明电极反应的速率控制步骤为电荷转移过程。阳极支撑单电池(Ni-CGO/CGO/PLNCG-30%CGO)在700℃的最大输出功率密度达到569 m W·cm-2,开路电压(OCV)为0.76 V。     

高温高压下纳米金刚石粉的特性研究

 研究了炸药爆轰合成的纳米金刚石粉在高温（约1 600 K）、高压（5.2 GPa）条件下的行为。将纳米金刚石粉与粉末合金（Ni₇₀Mn₂₅Co₅、100^#）混合、压制成圆片,与合金片 （Ni₇₀Mn₂₅Co₅）和人造石墨片一起交替放入高温高压合成腔体内,进行高温高压实验。实验结果表明：在高温高压条件下,纳米金刚石粉不能长大,反而石墨化了;在相同的高压和保温时间条件下,随着温度的降低,纳米金刚石粉的石墨化程度减弱,纳米金刚石粉的纳米颗粒长大,可长成0.1 mm尺寸的金刚石颗粒（温度为1 070 K左右）。而在此条件下,人造石墨不能合成金刚石,一般金刚石晶体要变成石墨相。这进一步表明,纳米金刚石颗粒表面的活性使得它可以在较低的温度下长成较大颗粒的金刚石。     

Direct Radiative Capture to Continuum States

A formula for the calculation of the cross sections,of nuclear transition to continuum states induced by direct radiative capture of intermediate-energy proton is deduced.The transition amplitude includes two terms corresponding to potential-scattering to potential-scattering transitions and potential-scattering to resonance-scatting transitions,respectively.The model is compard with available experimental data of the ¹¹B(p,γ₁₉)¹²C reaction,and the results show that the direct capture mechanism is capable to account for the main features of the measured data within the reasonable parameter scope,and,in the present case,the contributions from two terms are of the same order of magnitude.The physical significance of the results is also discussed.     

Calculation of Binding Energies of the Ground and Excited States of a Donor in GaAs-A1xGal-xAs Step Quantum Wells

In this paper we present for the first time completely analytical variational expressions for calculating the binding energies of the low-lying bound states of a hydrogenic donor in a quantum well (QW). These expressions can be used for the problem of the binding energy of an impurity in a general manner, e.g. for calculating the binding energies of a donor associated with subband states of any order in the QW with any arbitrary potential profile. 70 demonstrate the utilization of these expressions we have theoretically studied the binding energies for the ground and a few low-lying excited etates of a hydrogenic donor in a stepped quantam well (SQW). The variations of the binding energies for these donor etates with impurity positions are investigated for different heights of the step potential. The numerical calculation results show that the binding-energy curves in the SQW, in contrast to the case of the flat quantum wells (FQW's), exhibit a non-symmetrical structure relative to the center of the QW and depend on the sub-barrier potential. The peak position in the binding energy curves shifts away from the region occupied by the sub-barrier as increasing sub-barrier height. The maximum in the binding energies increases as the step potential increaaes. These effects can be interpreted by referring to the variation of the electron probability-density distribution and of the lowest subband in the SQW. The shape of the binding-energy curves related to the 2po-like state is different from the other states. It is associated with the particular feature of the wave function of the 2po state in the QW.     

原 子 光 刻

介绍了根据量子光学的最新成果——激光冷却和捕陷中性原子的原理而发展出的一种新型纳米级刻印技术——原子光刻.介绍了该项技术的基本原理、总体方案、单元技术及刻印结果,将这项新技术与其他微刻印方法进行了比较,展望了其应用于微电子学等领域的前景. 关键词：     

大北窑地铁隧道顶板稳定性控制研究

分析大北窑地铁隧道饱水粉细砂层顶板的地质环境及其工程特性,用超细水泥注浆加固新工艺稳定流砂段及其扰动段的顶板。运用地质工程观点,充分利用顶板底部的粉砂薄层,用钢管加固未扰动段顶板。地面监测资料说明,本文的措施对其顶板稳定性控制非常有效。     

THE VERTICAL INTEGRATED MOMENTUM SPECTRUM OF THE MUON WITH MOMENTUM LARGER THAN 4 GeV/c AT 3220m ABOVE SEA-LEVEL

At an altitude of 3220 meters above sea level in Yunnan Province, we measured, by using a G-M counter-magnetic spectrometer, the vertical integratted momentum spectrum of the cosmic muon with momentum larger than 4 GeV/c. The spectrum obtained from this experiment is expressed by a power function in the form of I（>p）=Q （p+4）^-1.86±0.06(cm^-2·sr^-1·s^-1), where p is in GeV/c and Q is a constant. We also measured the charge ratio of muon in the 4—23 GeV/c momentum range. The result is N_μ/N_μ-=1.26±0.11. The error in the momentum measurement with spectrometer has been discussed and calculated.     

FEB-E动态气靶偏滤器的研究

在ＦＥＢ－Ｅ设计阶段,偏波器从开放式固定板靶优化为封闭式气体靶,以改善偏滤器的杂质控制和增加离子与气体的相互作用,通过喷气和注入杂质获得的部分脱靶等离子体形成了动态气体靶,喷气能降低删削层（ＳＯＬ）处等离子体温度,沪入的杂质增加了ＳＯＬ处的辐射功率,使靶板的负载降低,用ＮＥＷＴ１Ｄ编码模拟了ＳＯＬ处等离子体和杂质（硼杂质）的输运,得到了杂质、等离本温度和等离了体密度分布。着眼于杂质的滞留物辐射,优     

调液阻尼器对结构扭转耦联振动控制的优化设计

提出了利用调液柱型阻尼器(Tuned Liquid Column Dampers,简称TLCD)和环形调液阻尼器(Circular Tuned Liquid Column Dampers,简称CTLCD)来控制偏心结构在多维地震作用下扭转耦联振动的方法。采用遗传算法,在双向地震作用下,对调液阻尼器的相关参数进行优化。选取了两种目标函数,一种只考虑最大的楼层反应,另一种考虑结构所有自由度的反应。用一个12层的偏心结构作为算例,进行优化计算,结果表明,采用第二种目标函数得到的阻尼器的参数,能有效降低结构的平动反应和扭转反应。