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101.
为了利用微尺度热效应的热致飞高控制(TFC)磁头技术实现磁头飞行高度的精确控制,分析了工作状态下TFC滑块在多物理场综合作用下所呈现出来的传热特性及其主要影响因素,考虑了磁头磁盘间超薄气膜的稀薄效应,建立滑块导热、空气轴承表面传热、气膜流动等模型,利用有限元法,对磁头热变形作用机理及热传导特性对滑块动力学特性影响进行了仿真研究,结果表明,建立的传热模型及对雷诺方程的修正适用于求解磁头磁盘界面气膜传热问题和磁头滑块的动力学问题;影响滑块热力学性能的因素主要可以归结为加热器高度、热生成率以及材料的传热系数;空气轴承力及工作表面热变形的双重作用决定了滑块飞行高度的改变.仿真结果为磁头滑块加热器的设计及空气轴承动力学特性分析提供了依据. 相似文献
102.
以Bi(NO3)3·5H2O和Ti(OC4H9)4为原料,采用自组装单层膜技术,在负载有功能化三氯十八烷基硅烷(octadecyl-trichloro-silane,OTS)的FTO基板上制备了Bi2Ti2O7 薄膜。基板表面的亲水性测试表明,紫外照射使OTS自组装单层膜表面由疏水转变为亲水,实现功能化。借助X射线衍射(XRD)、X射线能量色散谱(EDS)、扫描电子显微镜(SEM)和原子力显微镜(AFM)分析分别对Bi2Ti2O7薄膜的组成、结构和微观形貌进行了表征。结果表明,沉积溶液浓度为0.02 mol·L-1时,所得Bi2Ti2O7薄膜均匀致密。560 ℃热处理1 h、厚度为0.4 μm的Bi2Ti2O7薄膜在100 kHz的介电常数为153,介电损耗为0.089。 相似文献
103.
本文基于粒子群优化算法的结构预测方法结合第一性原理计算,研究了LiYH4,Li2YH5和Li3YH6在0—300 GPa压力范围内的晶体结构、电子结构、热力学和动力学稳定性.研究结果表明LiYH4-P4/nmm,Li2YH5-I4/mmm和Li3YH6-P4/nmm结构可分别在169—221 GPa,141—300 GPa和166—300 GPa压力范围内由LiH和YH3按一定配比加压合成.富氢化合物的超导电性研究成为近年来高温超导体研究领域的热点,该研究结果有希望为Li-Y-H三元体系氢化物的超导电性研究及实验合成提供数据支撑. 相似文献
104.
In the present paper, we consider the oscillation of a class of self‐adjoint fourth order differential equation. Some oscillation and non‐oscillation criteria on a perturbation equation of Euler differential equation are given. In particular, we find the exact value of a constant in some oscillation criteria, which has answered the open problem presented by Do?lý in 2004. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
105.
A novel ligand with double sulfinyl groups, bis(benzylsulfinyl)methane, was synthesized by a new method and its two lanthanide
(III) complexes were synthesized and characterized by element analysis, molar conductivity, coordination titration analysis,
IR, TG-DSC, 1HNMR and UV spectra. The results indicated that the composition of these complexes was REL2.5(ClO4)3·3H2O (RE = Tb (III), Dy (III), L = C6H5CH2SOCH2SOCH2C6H5). The FT-IR results revealed that the perchlorate group was bonded with the lanthanide ion by the oxygen atoms, and the coordination
was bidentate. The fluorescent spectra illustrated that both the Tb (III) and Dy (III) complexes displayed characteristic
fluorescence in solid state, especially for the Tb (III) complex, the peak of 5D4 → 7 F5 of the Tb (III) ion in 544 nm was stronger than that of others. It indicated that the Tb (III) complex could emit purer green
fluorescence. By analysis fluorescence and phosphorescence spectra, it was found that the ligand had the advantage to absorb
energy and transfer it to the Tb (III) and Dy (III) ions. The phosphorescence spectra and fluorescence lifetimes of the complexes
were also measured. 相似文献
106.
Lycoris species have been known since long ago as a multi-utility ethnomedicinal herbal in China. It has been reported to exhibit a number of properties such as anticancer, neuroprotective, and antibacterial activities. In the present study, the anticancer efficacy of dichloromethane extracts of Lycoris aurea (DELA), was evaluated both in vivo and in vitro using murine sarcoma 180 cells. To evaluate the effects of DELA on apoptotic cell death, flow cytometry and Western blotting were performed. DELA demonstrated promising inhibition effects on sarcoma 180 cells in vitro and a 53.49% inhibitory rate on cancer cells in vivo. DELA treatment increased thymus indices and spleen indices in vivo, indicating that it reduced tumours, but did not damage the main immune organs. The DELA-evoked increase in apoptotic cell death was accompanied by occurrence of cleaved caspase-3 and decreases in the ratio of Bcl-2/Bax. Further purification and LCMS analysis showed DELA contained homolycorine, 2α-hydroxyoduline, oduline, hippeastrine, 2α-hydroxy-6-O- methyloduline, and 2α-methoxy-6-O-methyloduline. These results indicate that DELA exerted its anticancer effects, at least in part, by inducing cancer cell apoptosis and thus can be considered as a potential candidate agent for treatment of cancer. 相似文献
107.
Na Ye Xiangtao Xu Fuying LiMengmeng Ning Zhiqing LiuYuqing Cao Ying Leng Ao Zhang 《Tetrahedron letters》2012,53(35):4738-4742
RuCl3/NaIO4-initiated oxidation of oxiranemethanols was investigated, and two products, oxirane-2-carboxylic acid and (5′-oxotetrahydrofuran-3-yl)acetic acid, were obtained in variant ratios. The product structures were determined and a tentative mechanism involving oxidation-rearrangement-oxidation process was proposed. Glucokinase enzymatic assay revealed that oxiranecarboxamides 4a-c retained moderate GK activation potency with amide 4a showing an EC50 value of 584 nM and a high activation fold of 3.14. However, (5′-oxotetrahydrofuran-3-yl)acetamide 11a is inactive. This study not only provided an alternative protocol to access (5′-oxotetrahydrofuran-3-yl)acetic acid analogs, but also yielded nanomolar GA activators (esp. 4a) for further structure-activity relationship study. 相似文献
108.
Two new neolignans, syripinnalignins A and B ( 1 and 2 , resp.), were isolated from the 95% EtOH extract of the stem of Syringa pinnatifolia Hemsl . var. alashanensis. The structures of 1 and 2 were elucidated by spectroscopic methods, including UV, IR, HR‐ESI‐MS, and extensive 1D‐ and 2D‐NMR techniques. 相似文献
109.
110.
以基碳酸酰氯作衍生化试剂 ,采用高效液相色谱拆分 1,1′ 联萘 2 ,2′ 二酚光学异构体。当采用LichrosorbSi 6 0 (4mm× 30 0mm ,5 μm)柱 ,紫外 2 75nm检测 ,正己烷 乙醇 (98.5 1.5 ,V V)为流动相 ,1,1′ 联萘 2 ,2′ 二酚单基碳酸酯的分离因子和分离度分别为 1.36 8、3.0 5 1;用正己烷 乙醚 (98.5 1.5 ,V V)为流动相 ,1,1′ 联萘 2 ,2′ 二酚双基碳酸酯的分离因子和分离度分别为 1.0 5 5、1.347。这一方法可简便、快速地测定联萘二酚单基碳酸酯拆分样品的光学纯度 相似文献