Some addition reactions of bisgermavinylidene

The reaction of bisgermavinylidene [(Me₃SiN?PPh₂)₂C?Ge→Ge?C(PPh₂?NSiMe₃)₂] ( 1 ) with AdNCO (Ad = Adamantyl) afforded the [2 + 2] cycloadditon product [(Me₃SiN?PPh₂)₂CGeC(O) NAd] ( 2 ). Similar reaction of 1 with Ph₃SiOH in tetrahydrofuran (THF) yielded the base‐stabilized germanium(II) triphenylsiloxide [H₂C(PPh₂?NSiMe₃)₂Ge(OSiPh₃)₂] ( 3 ). The results suggested that reactive germavinylidene may exist in solution and is capable of forming addition reaction products. The X‐ray structures of 2 and 3 were determined. Copyright © 2007 John Wiley & Sons, Ltd.     

Synthesis, crystal structure determination, spectroscopic and electrochemical studies of trans-[Ru(PPh3)2(bbpH2)Cl]Cl·CHCl3·H20 (bbpH2=2,6-bis(benzimidazolyl) pyridine) – an infinite double columnar supramolecule in the solid state

The synthesis, crystal structure, redox and spectroscopic properties of trans-[Ru(bbpH₂)(PPh₃)₂Cl]Cl are reported. In the crystalline solvate trans-[Ru(bbpH₂)(PPh₃)₂cCl]Cl CHCl₃ H₂O, the molecular components are connected by strong intermolecular hydrogen bonding to form an infinite double column.     

Modelling the cost of poor quality in a five-state part manufacturing operation: a case study

The quality history of individual parts from a critical operation can be modeled by a five-state Markov chain involving factory rework operation, customer inspection and field test, parts scrapped, parts defective but used-as-is by concession or re-graded for alternative applications, and defect-free parts satisfying customer requirements. We estimate total failure cost by a five-state Markov chain model and present a case study to demonstrate relationship of the total failure cost to appraisal and prevention costs.     

Conversion of the frequency of emission of a neodymium laser by the method of resonance pumping of active media

Journal of Applied Spectroscopy -     

Lifetimes of low-lying levels in 18F

Mean lifetimes of levels in ¹⁸F have been measured using the Doppler-shift attenuation method and the inverse reaction ³He(¹⁶O, p)¹⁸F. Targets of ³He implanted into Al, Nb, and Au foils were employed in the measurements. The Doppler-broadened lineshapes observed at 0° to the beam were analyzed to obtain the following lifetime values: 0.971 ± 0.030, 0.605 ± 0.029 and 0.435 ± 0.041 ps for the 1.70(1⁺), 2.52(2⁺) and 3.36(3⁺)MeV members of the K^π = 1⁺ rotational band, 5.12 ± 0.56, 0.403 ± 0.018 and 1.91 ± 0.17 ps for the 2.10(2^?), 3.13(1^?) and 3.79(3^?) MeV members of the K^π = 0^? bands, and 〈1.2, 2.7^+4.1_?2.7 and 20 ± 2 fs for the 3.06(2⁺, T = 1), 3.72(1⁺) and 3.84(2⁺) MeV states, respectively.     

Diffusion of iodine into PE and PET

We show that the Rutherford backscattering technique is very useful for studying the kinetics of diffusion processes in polymers. We have measured the diffusion of iodine into low-density polyethylene (LDPE) by optical absorbance and by Rutherford backscattering. The optical results appear to be normal, and show no electric field dependence, but the backscattering results reveal that this is misleading, because there is fast diffusion in the bulk accompanied by large surface concentrations of iodine. We have studied PET by the backscattering technique, and in this case the behavior corresponds to a weakly concentration-dependent diffusion coefficient with no observable surface effects. Neither set of results gives support to the domain theories of low-frequency electrical oscillation in these materials.     

Effect of Pr-Ca substitution on the transport and magnetic behavior of LaMnO3 perovskite

The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO₃ perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good example of these properties is (La_1−2x Pr _x Ca _x )MnO₃ (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T _c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for understanding the structural, transport and magnetic properties are discussed in detail.