Synthesis, crystal structure determination, spectroscopic and electrochemical studies of trans-[Ru(PPh3)2(bbpH2)Cl]Cl·CHCl3·H20 (bbpH2=2,6-bis(benzimidazolyl) pyridine) – an infinite double columnar supramolecule in the solid state |
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| Authors: | Dipankar Mishra Subhendu Naskar Shyamal K Chattopadhyay Milan Maji Parbati Sengupta Rupam Dinda Saktiprasad Ghosh and Thomas C W Mak |
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| Institution: | (1) Department of Chemistry, Bengal Engineering and Science University, Shibpur, Howrah, 711 103, India;(2) National Institute of Technology, Durgapur, 713209, India;(3) Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, 700 032, India;(4) Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, People’s Republic of China |
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| Abstract: | The synthesis, crystal structure, redox and spectroscopic properties of trans-Ru(bbpH2)(PPh3)2Cl]Cl are reported. In the crystalline solvate trans-Ru(bbpH2)(PPh3)2cCl]Cl CHCl3 H2O, the molecular components are connected by strong intermolecular hydrogen bonding to form an infinite double column. |
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