钨钼钒硅杂多酸盐的合成

Keggin结构的杂多酸及其盐已广泛地应用于催化、比色分析、生化等领域,因此新型杂多酸,特别是高电荷、易还原的含钒混合齿顶杂多酸,及其盐的合成和性质的研究就成了引人注目的课题。含两种齿顶原子的杂多酸已见报道,含杂原子为硅的三种齿顶原子的杂多酸及其盐尚未见报道。本文报道了两个新的三种齿顶原子的杂多酸TBA盐(四丁基铵盐),其     

选择题试编

选择题作为一种新颖的试题形式,目前在国内外已普遍采用,这类试题能较好地考查学生的思维能力。现行中学数学教材,这类习题极其欠缺,为了使学生能适应这种试题,我在教学过程中,根据教学内容,给学生平时练习中出现的错误,编拟了一些选择题给学生练习,现抄录一部分供同行们参考。     

多线性Marcinkiewicz积分在Campanato空间上的存在性与有界性

设n≥2, m≥1,y=(y1,..., ym).μ(f)是如下定义的多线性Marcinkiewicz积分:μ(f)(x)=(∫∞01/tm∫(B(0,t))~m?(y)|y|m(n-1)m∏i=1f_i(x-y_i)|2dt/t)~(1/2),其中dy=dy1···dym.本文考虑了μ(f)在Campanato空间上的存在性与有界性,证明了若m-线性Marcinkiewicz积分μ(f)在一点处有限,则它几乎处处有限,而且,如下范数不等式成立:||μ(f)||Eα,p≤C m∏j=1||fj||Eαj,pj,其中E~(α,p)是经典的Campanato空间,1/p=1/_p1+···+1/p_m,α=α_1+···+α_m.     

Cross-section measurement for Ni（n,x）^58（m＋g）Co, Ni（n, x）^60mCo, Ni（n,x）^61Co and Ni（n,x）^62mCo reactions induced by neutrons around 14 MeV

The cross sections of Ni(n,x)~(58(m g))Co,Ni(n,x)~(60m)Co,Ni(n,x)~(61)Co and Ni(n,x)~(62m)Co reactions induced by neutrons around 14 MeV were measured in this work and calculated by a previously developed formula in this work.The neutron flux was determined using the monitor reaction ~(27)Al(n,α)~(24)Na and the neutron energies were measured with the method of cross-section ratios for ~(90)Zr(n,2n)~(89)Zr to ~(93)Nb(n,2n)~(92m)Nb reactions.     

有机材料(EDT-DSDTFVO)FeCl_4和(EDT-DSDTFVO)GaCl_4的输送现象

通过对有机材料(EDT-DSDTFVO)2FeCl4和(EDT-DSDTFVO)2GaCl4的输送测定,对其电阻率的温度依赖性以及压力效果进行了系统的比较,虽然两类盐的电阻率随着温度的变化行为十分相似,但是其压力效果尤其在高压时表现出明显的差异性。认为这种差异性和π-d相互作用密切相关。在这里,用EDT-DSDTFVO表示ethylenedithiodiselenadithiafulvalenothioquinone-1,3-dithiole methide。     

海洋光学浮标实时图像监测系统的设计与实现

设计了依托于海洋光学浮标平台的图像监测系统,可实时采集浮标点海面与水体的图像数据。采用新型的图像采集装置,解决了图像监测系统因浮标浮动而导致的图像失真问题,克服了在DOS系统下对USB设备存储介质读取的难题,运用两种无线网络的同时传输增大了实验室与浮标数据交换的可靠性,举例分析了图像监测系统所获得的实时数据,验证了其正确性。     

Construction and application of an electrochemical sensor based on graphene-MXene nanocomposites for baicalin detectionEI北大核心CSCD

Redox graphene-MXene(rGO-MXene) nanocomposites were prepared by ion polymerization and used to construct a highly sensitive electrochemical sensor for baicalin(BA) detection. The synergistic effect of rGO and MXene increased the specific surface area and electron transport capacity of the electrode, and significantly enhanced the electrochemical response of BA. The cyclic voltammetry and differential pulse voltammetry were used to investigate the electrochemical behavior of BA on the sensor. Under the optimal conditions, the peak current exhibited a good linear relationship with BA concentration in the range of 0. 05-10 μmol / L, and the limit of detection was as low as 28 nmol / L. The method was applied to analyze traditional Chinese medicine preparations containing baicalin, such as Qingkailing Capsule and Sanhuang Tablets with good accuracy and spiked recovery. The results were highly consistent with those of high performance liquid chromatography, providing a technical means for the rapid and sensitive detection of traditional Chinese medicine preparations. © 2022, Youke Publishing Co.,Ltd. All rights reserved.     

带新熵函数的Entropy-Ultra-bee格式计算线性传输方程

本文研究了线性传输方程的数值解法.利用物理的熵函数得到了一种新的Entropy-Ultrabee格式.数值实验表明该格式长时间计算效果非常好,在间断附近有比较高的分辨率.     

Blumlein传输线的解析分析

 在传输线应用中,负载终端匹配设计是一个重要问题。用拉普拉斯变换方法严格求解Blumlein传输线的电报方程,研究在纯电阻负载和带分布参数负载情况下,波在传输线中的瞬态传输过程,得到了清晰的物理图像,结果与通常的行波传播分析法完全一致。     

三腔渡越管振荡器高频结构的解析研究

 从圆柱坐标系下Borgnis位函数的齐次标量Helmholtz方程出发,引入慢波驻波概念及其场表达式,利用Borgnis位函数的边界条件及相邻子区公共界面上的场匹配条件,导出了三腔渡越管振荡器内角向均匀TM模的色散关系及场分布的解析表达式。运用该解析法求得三腔渡越管振荡器的谐振频率与实验中测得的微波频率一致,求得的场分布与数值法得到的场分布十分吻合。