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71.
72.
Investigation on Mechanism for Separation of Alkali, Alkaline Metal and Ammonium Cations in Nonaqueous Capillary Electrophoresis 总被引:2,自引:0,他引:2
Capillary electrophoresis ( CE ) has rapidly gained great interests among researchers in many different fields. One of these areas is the separation of small ions such as inorganic cations, anions, and low Mr organic molecules However, as the separation of ions 相似文献
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In the presence of Bu4NBr acting as phasetransfer reagent, organothiophosphoryl polyoxotungstate derivatives α-[RP(S)]2PW9O54^5- (R=C6Hs, C6H11) have been obtained by reaction of the trivacant β-[PW9O34]^9- anions with electrophilic C6H5P(S)Cl2 or C6H11P(S)Cl2 in acetonitrile. These new organic-inorganic hybrid anions have been characterized by elemental analysis, IR, ^31P and ^183W NMR spectroscopy. The collective application of the spectroscopy data of these new species indicates that the hybrid anion consists of an α-[PW9O34] framework on which are grafted two RP(S) groups through P-O-W bridges. The five-line ^183W spectra indicate that the hybrid anions possess Cs symmetry in acetonitrile. 相似文献
78.
建立了固相萃取-高效液相色谱同时测定辣椒粉中对位红、酸性橙Ⅱ、苏丹红Ⅰ和苏丹红Ⅱ 4种偶氮染料的方法。以多孔芳香骨架-6(PAF-6)材料作为固相萃取吸附剂,考察并获得了影响自制固相萃取柱的萃取效率和吸附容量等主要因素。在优化条件下,4种目标分析物的检出限(LOD)为1.5~7.0 μg/L(信噪比S/N=3),定量限(LOQ)为5.0~22.1 μg/L(S/N=10),加标回收率为76.5%~89.8%,相对标准偏差(RSD)均不大于5.3%(n=6)。此外,基于量子化学计算,考察了PAF-6与目标分析物之间的相互作用机制,结果表明,目标分析物可以稳定地吸附在PAF-6分子上。该方法准确可靠,具有良好的回收率和较高的灵敏度,可用于辣椒粉中4种偶氮类染料的检测。 相似文献
79.
The density functional theory (DFT)(b3p86) of Gaussian 03 has been
used to optimize the structure of the Co$_{2}$ molecule, a transition
metal element molecule. The result shows that the ground state for
the Co$_{2}$ molecule is a 7-multiple state, indicating a spin
polarization effect in the Co$_{2}$ molecule. Meanwhile, we have not
found any spin pollution because the wavefunction of the ground state
is not mingled with wavefunctions of higher-energy states. So for the
ground state of Co$_{2}$ molecule to be a 7-multiple state is the
indicative of spin polarization effect of the Co$_{2}$ molecule, that
is, there exist 6 parallel spin electrons in a Co$_{2}$ molecule. The
number of non-conjugated electrons is the greatest. These electrons
occupy different spacial orbitals so that the energy of the Co$_{2}$
molecule is minimized. It can be concluded that the effect of
parallel spin in the Co$_{2}$ molecule is larger than the effect of
the conjugated molecule, which is obviously related to the effect of
electron d delocalization. In addition, the Murrell--Sorbie potential
functions with the parameters for the ground state and the other
states of the Co$_{2}$ molecule are derived. The dissociation energy
$De$ for the ground state of Co$_{2}$ molecule is 4.0489eV,
equilibrium bond length $R_{\rm e}$ is 0.2061~nm, and vibration
frequency $\omega _\e $ is 378.13~cm$^{ - 1}$. Its diatomic molecule
force constants $f_2$, $f_3$, and $f_4$ are 2.4824~aJ$\cdot$nm$^{ -
2}$, -7.3451~aJ$\cdot$nm$^{ - 3}$, and 11.2222~aJ$\cdot$nm$^{ - 4
}$respectively(1~aJ=$10^{-18}$~J). The other spectroscopic data for
the ground state of Co$_{2}$ molecule $\omega_{\e}\chi _{\e}$,
$B_{\e}$, and $\alpha_{\e}$ are 0.7202~cm$^{-1}$, 0.1347~cm$^{-1 }$,
and 2.9120$\times $ 10$^{-1}$~cm$^{-1}$ respectively. And
$\omega_{\e}\chi _{\e}$ is the non-syntonic part of frequency,
$B_{\e}$ is the rotational constant, $\alpha_{\e}$ is revised
constant of rotational constant for non-rigid part of Co$_2$
molecule. 相似文献
80.
Effect of Electric Field on Spin Polarized Current in Ferromagnetic/Organic Semiconductor Systems 下载免费PDF全文
Considering the special carriers in organic semiconductors, the spin polarized current under electric field in a ferromagnetic/organic semiconductor system is theoretically studied. Based on the spin-diffusion theory, the current spin polarization under the electric field is obtained. It is found that electric field can enhance the current spin polarization. 相似文献