F同位素的反应总截面测量和17F可能的质子皮结构

应用透射法对中能区F同位素与C靶的反应总截面进行了测量.发现¹⁷F的反应总截面比其邻近同位素的反应总截面稍有增强.用Glauber模型和BUU模型对F同位素进行了差异因子d的分析.¹⁷F的差异因子d比其附近同位素稍有增强.分析结果表明¹⁷F可能存在质子皮结构.     

中等质量核激发态奇异核结构的研究

在球形非线性相对论平均场(RMF)的理论框架下, 研究了β稳定线附近中等质量(z=20—50)奇A核在激发态下存在的晕或皮结构, 提取了价核子与核芯均方根半径的比值(R_vc), 并结合单中子或质子的分离能(Sn(p)), 讨论了具有晕或皮结构的激发态所呈现出来的带状分布, 说明了壳层结构与离心势垒对激发态晕或皮结构形成的重要影响.     

同位旋标度规律的动力学和统计衰变效应

通过同位旋相关的量子分子动力学模型和统计级联衰变模型, 计算了两个相似的同位旋不同的反应系统的同位旋标度规律, 计算的结果表明对于轻粒子碎片, 同位旋标度系数α随反应时间的增加有所变大, 而对于重的余核产物, α随反应时间的增加有所减小; 轻粒子碎片的α基本上保持不变化, 中等质量和重的余核, α与产物的大小相关, 产物越重α越大. 统计级联衰变可以稍微增加同位旋标度参数α, 但是不改变α对于轻粒子和重产物的变化规律.     

A Search for Solar Axions and Anomalous Neutrino Magnetic Moment with the Complete Panda X-Ⅱ Data

We report a search for new physics signals using the low energy electron recoil events in the complete data set from PandaX-Ⅱ,in light of the recent event excess reported by XENON1 T.The data correspond to a total exposure of 100.7 ton·day with liquid xenon.With robust estimates of the dominant background spectra,we perform sensitive searches on solar axions and neutrinos with enhanced magnetic moment.It is found that the axionelectron coupling gAe<4.6×10^-12 for an axion mass less than 0.1 keV/c² and the neutrino magnetic moment μv<4.9×10^-11μB at 90%confidence level.The observed excess from XENON1 T is within our experimental constraints.     

等色染料离子对浮选光度法测定铂

提出了等色染料离子对浮选光度法、向罗丹明６Ｇ（Ｒ６Ｇ）和Ｐｔ（ＳｎＣｌ３）５＾３－的异丙醚浮选物Ｐｔ（ＳｎＣｌ３（５（Ｒ６Ｇ）３中，加入ＰＨ＝５．５的醋酸－醋酸铵缓冲溶液，使Ｒ６Ｇ离子进入水相，并向其中加入与Ｒ６Ｇ颜色相同的四溴荧光素（ＴＢＦ）〉形成等色染料等离子对Ｒ６Ｇ，ＴＢＦ，再被甲茉浮选，将浮选物溶于丙酮，于５３０ｎｍ处进行光度测定，由于６个染料分子（Ｐｔ：Ｒ６Ｇ：ＴＢＦ）＝（１：３：３）ｅ     

亚甲基烯酮与5-亚甲基-1,3-二噁烷-4,6-二酮反应机理的研究

利用半经验分子轨道理论AM1方法，研究了5-亚甲基-1，3-二噁烷-4，6-二酮与亚甲基烯酮的2，3-位C＝C，3，4-位C＝O和1，2-位C＝O三种双键位置上的环加成反应的反应机理．采用Berny梯度法优化得到反应的过渡态，并进行了振动分析确认．计算结果表明，环加成反应是按照协同的非同步途径进行的，经过一个扭曲的六员环过渡态，前线轨道分析表明反应机理为［4＋2］机理．根据AM1优化得到的产物反应物及过渡态的生成热可知三个反应的活化焓分别为27．07kJ·mol-1，32．41kJ·mol-1和137．96kJ·mol-1，2，3-位C＝C双键上的环加成反应的活化焓最低，这与实验中只观察到2，3－位C＝C双键上环加成产物的结论是一致的．     

N,N‘—二（芳磺酰）亚磺酰胺—S—（2—苯并咪唑）钠作为稳定的研究

研究了新型感光稳定剂Ｎ，Ｎ’－二（芳磺酰）亚磺酰胺－Ｓ－（２－苯并咪唑）钠（芳磺酰基为苯磺酰，对甲苯磺酰，对氯苯磺酰）与增感染料在实用照相乳剂虽的超增感与防雾作用。     

烷基氟化物消除氟化氢反应的取代基效应-2

The substituent effect of the 1-1 elimination reaction of hydrogen fluoride from ethyl fluoride have been studied by ab initio method at the HF/3-21G level. The reactants are CH_3CH_2F, CH_3CHF_2, CH_2FCH_2F, CH_3CH_2CH_2F, CH_3CHFCH_3, CH_3CHFCN, CH_2CNCH_2F, CH_2NH_2CH_2F, CH_3CHFNH_2 and their reaction barriers are 369.5, 433.5, 306.9, 365.6, 357.3, 354.1, 383.2, 370.3, 250.3 kJ·mo1~(-1) respectively. It can be concluded that the 1-1 elimination reaction of CH3_CHFNH_2 is the easiest to proceed. This conclusion can be rationalized by its characteristic transition state geometry.     

One-Proton Halo Structure in ^23Al

The Glauber theory is used to investigate the reaction cross section of proton-rich nucleus ^23Al. A core plus a proton structure is assumed for ^23Al. HO-type density distribution is used for the core while the density distribution for the valence proton is calculated by solving the eigenvalue problem of Woods-Saxon potential The transparency function in an analytical expression is obtained by adopting multi-Gaussian expansion for the density distribution. Coulomb correction and finite-range interaction are introduced. This modified G1auber model is suitable for halo nuclei. A dominate s-wave is suggested for the last proton in ^23Al from our analysis which is possible in the calculation of relativistic mean-field theory.