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941.
942.
943.
Fuqiang Niu Hengfei Zhang Jinpeng Yuan Liantuan Xiao Suotang Jia Lirong Wang 《Frontiers of Physics》2023,18(5):52304
Photonic graphene, possesses a honeycomb-like geometric structure, provides a superior platform for simulating photonic bandgap, Dirac physics, and topological photonics. Here, the photonic graphene with reconfigurable geometric structures is demonstrated in a 5S1/2 − 5P3/2 − 5D5/2 cascade-type 85Rb atomic ensembles. A strong hexagonal-coupling field, formed by the interference of three identical coupling beams, is responsible for optically inducing photonic graphene in atomic vapor. The incident weak probe beam experiences discrete diffraction, and the observed pattern at the output plane of vapor cell exhibits a clear hexagonal intensity distribution. The complete photonic graphene geometries from transversely stretched to longitudinally stretched are conveniently constructed by varying the spatial arrangement of three coupling beams, and the corresponding diffraction patterns are implemented theoretically and experimentally to map these distorted geometric structures. Moreover, the distribution of lattice sites intensity in photonic graphene is further dynamically adjusted by two-photon detuning and the coupling beams power. This work paves the way for further investigation of light transport and graphene dynamics. 相似文献
944.
机动方舱核爆炸冲击波动力响应和安定性分析 总被引:1,自引:0,他引:1
本文以核爆炸当量、高度、距离为参数,采用等超压圆给出了普通方舱和防核加固方舱结构在核冲击波下的安全域。研究了限制舱体倾斜的压力条件。本文还以冲击波压力的时间函数为激励,求解了方舱的动力响应。从试验结果推论和计算模拟两方面,分析了方舱承受冲击波的能力。 相似文献
945.
946.
弹/粘塑性柱体扭转问题的函数Laplace变换解 总被引:3,自引:1,他引:3
在应力Laplace变换分析粘塑性轴对称问题基础上,对弹性-弹/粘塑性圆柱体扭转全过程进行分析,根据柱体扭转的应力分布,构造应力函数与位移函数,并对函数进行Laplace变换。相应求出圆柱体、空心圆柱体的Laplace变换解,以及圆柱体的弹性-粘塑性交界线值 相似文献
947.
948.
Catalytic Asymmetric Inverse‐Electron‐Demand Oxa‐Diels–Alder Reaction of In Situ Generated ortho‐Quinone Methides with 3‐Methyl‐2‐Vinylindoles 下载免费PDF全文
Jia‐Jia Zhao Si‐Bing Sun Sai‐Huan He Dr. Qiong Wu Prof. Dr. Feng Shi 《Angewandte Chemie (International ed. in English)》2015,54(18):5460-5464
The first catalytic asymmetric inverse‐electron‐demand (IED) oxa‐Diels–Alder reaction of ortho‐quinone methides, generated in situ from ortho‐hydroxybenzyl alcohols, has been established. By selecting 3‐methyl‐2‐vinylindoles as a class of competent dienophiles, this approach provides an efficient strategy to construct an enantioenriched chroman framework with three adjacent stereogenic centers in high yields and excellent stereoselectivities (up to 99 % yield, >95:5 d.r., 99.5:0.5 e.r.). The utilization of ortho‐hydroxybenzyl alcohols as precursors of dienes and 3‐methyl‐2‐vinylindoles as dienophiles, as well as the hydrogen‐bonding activation mode of the substrates met the challenges of a catalytic asymmetric IED oxa‐Diels–Alder reaction. 相似文献
949.
Hyperbranched Hybridization Chain Reaction for Triggered Signal Amplification and Concatenated Logic Circuits 下载免费PDF全文
Dr. Sai Bi Min Chen Xiaoqiang Jia Ying Dong Prof. Dr. Zonghua Wang 《Angewandte Chemie (International ed. in English)》2015,54(28):8144-8148
A hyper‐branched hybridization chain reaction (HB‐HCR) is presented herein, which consists of only six species that can metastably coexist until the introduction of an initiator DNA to trigger a cascade of hybridization events, leading to the self‐sustained assembly of hyper‐branched and nicked double‐stranded DNA structures. The system can readily achieve ultrasensitive detection of target DNA. Moreover, the HB‐HCR principle is successfully applied to construct three‐input concatenated logic circuits with excellent specificity and extended to design a security‐mimicking keypad lock system. Significantly, the HB‐HCR‐based keypad lock can alarm immediately if the “password” is incorrect. Overall, the proposed HB‐HCR with high amplification efficiency is simple, homogeneous, fast, robust, and low‐cost, and holds great promise in the development of biosensing, in the programmable assembly of DNA architectures, and in molecular logic operations. 相似文献
950.
Aryne‐Induced Novel Tandem 1,2‐Addition/(3+2) Cycloaddition to Generate Imidazolidines and Pyrrolidines 下载免费PDF全文
Dr. Sharada P. Swain Yi‐Chun Shih Dr. Shwu‐Chen Tsay Joby Jacob Dr. Chun‐Cheng Lin Dr. Kuo Chu Hwang Dr. Jia‐Cherng Horng Prof. Dr. Jih Ru Hwu 《Angewandte Chemie (International ed. in English)》2015,54(34):9926-9930
A new “single‐flask” method was developed for the synthesis of imidazolidines and pyrrolidines with high stereoselectivity. First, a Schiff base was arylated with an aryne. Second, an intramolecular proton transfer took place from the methylene position to the anionic aryne ring. Third, the resultant ylide reacted with a second equivalent of the same Schiff base in situ or an electron‐deficient alkene through a (3+2) cycloaddition. These sequential tandem 1,2‐addition/(3+2) cycloaddition reactions led to the desired heterocycles in 63–88 % yields. 相似文献