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881.
882.
Thomas Junkers Lin Zang Edgar H.H. Wong Nico Dingenouts Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2011,49(22):4841-4850
The preparation of ABA‐type block copolymers via tandem enhanced spin capturing polymerization (ESCP) and nitroxide‐mediated polymerization (NMP) processes is explored in‐depth. Midchain alkoxyamine functional polystyrenes (Mn = 6200, 12,500 and 19,900 g mol?1) were chain extended with styrene as well as tert‐butyl acrylate at elevated temperature NMP conditions (T = 110 °C) generating a tandem ESCP‐NMP sequence. Although the chain extensions and thus the block copolymer formation processes function well (yielding in the case of the chain extension with styrene number average molecular weights of up to 20,800 g mol?1 (PDI = 1.22) when the 6200 g mol?1 precursor is used and up to 67,500 g mol?1 (PDI = 1.36) when the 19,900 g mol?1 precursor is used and 21,600 g mol?1 (PDI = 1.17) as well as 37,100 g mol?1 (PDI = 1.21) for the tert‐butyl acrylate chain extensions for the 6200 and 12,500 g mol?1 precursors, respectively), it is also evident that the efficiency of the block copolymer formation process decreases with an increasing chain length of the ESCP precursor macromolecules (i.e., for the 19,900 g mol?1 ESCP precursor no efficient chain extension with tert‐butyl acrylate can be observed). For the polystyrene‐block‐tert‐butyl acrylate‐block‐polystyrene polymers, the molecular weights were determined via triple detection SEC using light scattering and small‐angle X‐ray scattering. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011. 相似文献
883.
Laser Doppler vibrometer (LDV) has a potential application prospect in remote sensing. Based on the correlation theories of heterodyne detection, a LDV system with a configuration of all fiber and heterodyne techniques is developed to detect the sound signal through the vibration of glass. Experimental results show that the LDV system has an ability to acquire the real-time speech signal 25 m away through glass. While, the system signal-to-noise ratio (SNR) value decreases with the increase of the glass thickness and the detection distance. 相似文献
884.
本文在适当的自然结构条件下证明了完全非线性常微分方程F(t,u(t),u′(t))=0的周期粘性解的存在唯一性. 相似文献
885.
886.
A method of eliminating the singularities involved in boundary element methods for three-dimensional potential problems is presented and the non-singular expressions of integrals on an element on which the singular point is situated are given for linear and quadratic interpolation functions. Numerical examples are compared with analytical solutions to show that the higher-order interpolations have better precision. 相似文献
887.
Platinum is released into the environment as a result of surface abrasion from automobile catalysts during operation. Previous investigations showed that this finely dispersed metallic platinum is dissolved in organic matrices, e.g. a humic soil to a significantly high degree, resulting in possibly bioavailable Pt species. In this work several natural complexing agents (adenosine, ADP, ATP, L-His, humic acid fraction, L-Met, pyrophosphate, and triphosphate) were treated with metallic platinum (as Pt black and as a Pt(0) containing tunnel dust) for 3–60 d. Some of the compounds used dissolved Pt(0) to a recognizable degree, whereas others were in the range of the aqueous blanks. Comparison of Pt black with a natural dust sample showed that L-methionine had in both cases the greatest effect after 60 d. Generally more Pt(0) was dissolved in the dust sample (finer dispersion and smaller particle size) than in the Pt-black used. By carrying out the experiment under natural conditions instead of in pure oxygen-, the amounts of dissolved platinum are about one order of magnitude lower.On leave from Liaoning University, Department of Chemistry, 110036 Shenyang, PR China 相似文献
888.
Generalized arcwise-connected functions and characterizations of local-global minimum properties 总被引:3,自引:0,他引:3
In this paper, new classes of generalized convex functions are introduced, extending the concepts of quasi-convexity, pseudoconvexity, and their associate subclasses. Functions belonging to these classes satisfy certain local-global minimum properties. Conversely, it is shown that, under some mild regularity conditions, functions for which the local-global minimum properties hold must belong to one of the classes of functions introduced.Dedicated to R. BellmanThe authors are indebted to I. Kozma, N. Megiddo, and A. Tamir for valuable discussions and to S. Schaible for valuable remarks. This research was partially supported by the Fund for the Encouragement of Research at the Technion. 相似文献
889.
The Near Field radiation pattern of a tapered monomode planar waveguide is investigated for the first time. A theoretical technique is developed and the results obtained are shown to agree sufficiently well with experiments performed on tapered ion-exchanged glass guides to permit using this technique to predict taper performance. 相似文献