磷脂改性聚合物膜

综述了膦脂改性聚合物膜的制备方法，其中饭知光引发接枝、电晕放电、化学接枝、原位聚合、共混改性、物理吸附等方法，并对磷脂改性聚合物膜的部分性质和应用前景作了简单介绍。     

AN ADAPTIVE OPTIMAL KALMAN FILTER FOR STOCHASTIC VIBRATION CONTROL SYSTEM WITH UNKNOWN NOISE VARIANCES

In this paper, an optimal criterion is presented for adaptive Kalman filter in a control system with unknown variances of stochastic vibration by constructing a function of noise variances and minimizing the function. We solve the model and measure variances by using DFP optimal method to guarantee the results of Kalman filter to be optimized. Finally, the control of vibration can be implemented by LQG method.     

Novel chiral thiazoline‐containing N―O ligands in the asymmetric addition of diethylzinc to aldehydes: substituent effect on the enantioselectivity

Several novel chiral thiazoline primary and tertiary alcohols were easily synthesized from commercially available l ‐cysteine in three steps and with high yield. These ligands were subsequently applied to the asymmetric addition of diethylzinc (Et₂Zn) to various aldehydes. Products with S configuration were obtained when thiazoline‐containing tertiary alcohol ligands were used as catalysts. The primary alcohol induced corresponding products with R configuration in 68% enantiomeric excess, which was a higher value relative to other N―O ligands possessing a primary alcohol unit in the literature. Furthermore, a plausible transition state model was proposed to explain the observed enantioselectivities. Copyright © 2012 John Wiley & Sons, Ltd.     

Enhancement of SrTiO<Subscript>3</Subscript>/BiPO<Subscript>4</Subscript> heterostructure for simulated organic wastewater degradation under UV light irradiation

A novel SrTiO₃/BiPO₄ heterostructure with different amounts of SrTiO₃ have been successfully prepared through the hydrothermal process. The photocatalysts were characterized by X-ray powder diffraction, UV–Vis diffuse reflectance spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy. The photocatalytic performance was evaluated by degrading the methylene blue dye solution under UV light. Results showed that the samples displayed excellent photocatalytic degradation efficiency due to the highly efficient suppression of the recombination of electron–hole pairs. A possible mechanism of SrTiO₃/BiPO₄ heterojunctions was discussed. The research indicated that the as-prepared SrTiO₃/BiPO₄ heterogeneous photocatalyst can be used as an effective material for degrading industrial organic wastewater.     

One-pot and microwave-assisted synthesis of N-sulfonylaziridines

A novel and efficient microwave-assisted one-step reaction was developed to synthesize chiral N-sulfonylaziridines by the reaction of different chiral amino alcohols and sulfonic chlorides. The newly developed microwave synthetic method has the advantage of reducing the reaction time from 24 to 0.5 h with improved yields (84-93%) and minimizing by-products.     

Rapid simultaneous determination of isoflavones in Radix puerariae using high-performance liquid chromatography-triple quadrupole mass spectrometry with novel shell-type column

A high-performance liquid chromatography (HPLC) coupled with triple quadrupole mass spectrometry (MS/MS) method was developed for rapid determination of 13 isoflavones in Radix puerariae. A novel shell-type column, namely Kinetex core-shell C(18) column (50 mm×2.1 mm id, 2.6 μm), and gradient elution were used during the analysis. The chromatographic peaks of 13 investigated compounds were identified by comparing their retention time and MS data with the related reference compounds. Multiple-reaction monitoring (MRM) was employed for the quantitative analysis with negative ionization mode. All calibration curves showed good linearity (r(2)>0.9990) within test ranges. The LOD and LOQ were lower than 0.017 and 0.873 μg/mL on column, respectively. The intra- and inter-day precisions for 13 analytes were <1.17 and 2.17%, respectively, and the recoveries were 93.1-104.4%. The validated method was applied for quantitative analysis of 13 isoflavones in 7 species of Radix puerariae. The result demonstrated that HPLC-MS/MS system with Kinetex column could be a promising analytical tool for the determination of isoflavones in traditional Chinese medicines, which is helpful for comprehensive evaluation of quality of R. puerariae.     

The Optimization of the PDA Optical System

ＴｈｅＯｐｔｉｍｉｚａｔｉｏｎｏｆｔｈｅＰＤＡＯｐｔｉｃａｌＳｙｓｔｅｍ￥ＨＯＵＱｉｎｇｗｅｎ；ＺＥＮＧＺｈｏｕｍｏ；ＳＵＮＪｉａｚｉ；ＹＡＮＧＸｕｅｙｏｕ（Ｄｅｐｔ．ｏｆＰｒｅｃｉｓｉｏｎＩｎｓｔｒｕｍｅｎｔＥｎｇｉｎｅｅｒｉｎｇ，ＴｉａｎｊｉｎＵ...     

体上的矩阵方程AXA=B

设Ｆ和Ω分别表示一个对合反自同构的体，一个加强Ｐ除环，本文定义了Ω上的亚（半）正定矩阵，给出了矩阵方程ＡＸＡ＾＊＝Ｂ在Ｆ上有（斜）自共轭矩阵解及在Ω上有亚（半）正定矩阵解的充要条件及其解集的显式表示。     

体上右线性方程组的反问题

设Ｆ，Ｋ，Ω分别表示一个任意的体、一个具有对合反自同构的体和一个实四元数体，Ｆ^ｎ表示Ｆ上的ｎ维右向量空间．本文推广和改进了实线性方程组的反问题及一系列结果，解决了Ｆ上右线性方程组更具一般性的反问题（简称ＩＰＳ）：给定ｂ∈Ｆ^s和α_ｉ∈Ｆ^ｎ（ｉ＝１，…，ｍ≤ｎ）满足ｒａｎｋ［α₁，…，α_m］＝ｍ，求所有的ｓ×ｎ矩阵Ａ使Ａα_ｉ＝ｂ（ｉ＝１，…，ｍ）．当ｓ＝ｎ时     

Spectroscopic and electrochemical studies of DNA breakage induced by dopamine and copper ion.

Dopamine may show some biological activities in antitumor and cell apoptosis. Herein, we attempted to employ UV-Vis, CD, and electrochemical methods to investigate the interaction between DNA and dopamine. Both the spectroscopic and electrochemical evidence indicated that dopamine, which was a cation, could interact with polyanion DNA. However, this kind of interaction, mainly by a static electronic force, did not result in any damage of the DNA structure. This situation was quite different when Cu ion was added to the dopamine-DNA system; an obvious change in the color of the solution and in the spectra of UV-Vis and CD showed that some chemical changes occurred in this system, and that the DNA native structure was destroyed. The results of gel electrophores further revealed that DNA might be broken into small segments by dopamine in the presence of Cu ion. The possible reaction mechanisms are discussed.