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131.
ZHANG Zhi-Li WANG Hong-Tao WANG Xiao-Wei MA Xiao-Yan LIU Jun-Yi R.J. Griff B.T. Golding 《有机化学》2003,23(Z1):10-10
Cobalamin-dependent methionine synthase plays a crucial role in folate metabolism and such would appear to be an excellent target for rational antifolate drug design. However, to date, no anticancer agents directed at this enzyme are available, but the enzyme is efficiently and specifically inhibited by N2O and this has proven invaluable for evaluating the biochemical consequence of enzyme inhibition and for mechanistic studies. [1,2] 2,5-Diamino-4-oxo-6-(3-butenyl) pyrimidine, a key intermediate in synthetic inhibitors of methionine synthase, was first synthesized using γbutenyl-β-ketoester and guanidine carbonate (Scheme 1). [3] 相似文献
132.
133.
Triterpenoid Constituents of Huperzia miyoshiana 总被引:1,自引:0,他引:1
Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis. 相似文献
134.
聚己内酯与不同纤维素衍生物形成的共混体系的红外光谱研究 总被引:1,自引:0,他引:1
用傅里叶变换红外光谱研究了聚己内酯与硝基纤维素、乙基纤维素和纤维素氨基甲酸酯所形成的共混体系中组分间的相互作用。对羟基基团、羰基基团以及聚己内酯结晶相相关的吸收谱带分析表明 :随着纤维素结构单元上羟基被取代程度的增加 ,纤维素衍生物的自身氢键相互作用明显减弱 ,而与聚己内酯之间的相互作用得到加强。这种相互作用的加强 ,显著改变了聚己内酯的结晶行为 ,使其结晶能力减弱。 相似文献
135.
Possible triggering of solar activity to big earthquakes (Ms ≥ 8) in faults with near west-east strike in China 总被引:1,自引:0,他引:1
HAN Yanben GUO Zengjian WU Jinbing & MA Lihua . National Astronomical Observatories Chinese Academy of Sciences Beijing China . Earthquake Research Institute of Lanzhou CSB Lanzhou China Correspondence should be addressed to Han Yanben 《中国科学G辑(英文版)》2004,(2)
A big earthquake (Ms = 8.1) occurred at western Kunlun Mts gap on November 14, 2001. It is the biggest earthquake in China in the past 50 years and the only one with a magnitude bigger than 8 in China after Dangxiong Earthquake (M = 8) in Tibet in 1951. The big earthquake has drawn wide attention of scientists in seismological, geophysical, geological and astro-geodynamic circles. Scientists are interested in the occurrence regularity of the very big earthquakes and try to find out the fac… 相似文献
136.
Jing Lin CHEN Gang Qiang YIN Zhong Ning CHEN* State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Fuzhou 《中国化学快报》2003,(5)
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl… 相似文献
137.
Forward degenerate four-wave mixing (DFWM) processes are investigated with a femtosecond pulsed laser in lithium niobate crystal doubly-doped with magnesium and iron (LiNbO3:Fe, Mg). The pulse energy dependence reveals a pure third-order nonlinear response, and the third-order nonlinear susceptibility x^(3) in the material is evaluated to be 4.96 × 10^-13 esu. The time-resolved DFWM process shows a response time of x^(3) shorter than 100fs, which is due to the nonresonant electronic nonlinearities. Our results indicate that LiNbO3 crystals have potentials for ultrafast real-time optical processing systems, which require a large and fast x^(3) optical nonlinearity. 相似文献
138.
In this paper, the authors obtain the endpoint estimates for a class of non-standard commutators with higher order remainders and their variants. Moreover, the authors show that these operators are actually not bounded in certain cases.
139.
140.
Three Stilbene Tetramers from the Roots of Caragana sinica 总被引:3,自引:0,他引:3
Three stilbene tetramers, carasinols A-C (1-3), along with three known substances, leachianol C, cararosinol A and stenophyllol B, were isolated from the roots of Caragana sinica. Their structures were elucidated by spectroscopy. It was found that compounds isolated except for stenophyllol B stimulated the proliferation of cultured osteoblasts. 相似文献