全文获取类型
收费全文 | 14933篇 |
免费 | 2817篇 |
国内免费 | 1969篇 |
专业分类
化学 | 10380篇 |
晶体学 | 220篇 |
力学 | 1013篇 |
综合类 | 157篇 |
数学 | 1504篇 |
物理学 | 6445篇 |
出版年
2024年 | 28篇 |
2023年 | 334篇 |
2022年 | 443篇 |
2021年 | 627篇 |
2020年 | 672篇 |
2019年 | 647篇 |
2018年 | 549篇 |
2017年 | 541篇 |
2016年 | 803篇 |
2015年 | 781篇 |
2014年 | 939篇 |
2013年 | 1091篇 |
2012年 | 1395篇 |
2011年 | 1363篇 |
2010年 | 1057篇 |
2009年 | 990篇 |
2008年 | 1021篇 |
2007年 | 840篇 |
2006年 | 840篇 |
2005年 | 737篇 |
2004年 | 509篇 |
2003年 | 413篇 |
2002年 | 447篇 |
2001年 | 327篇 |
2000年 | 314篇 |
1999年 | 260篇 |
1998年 | 204篇 |
1997年 | 242篇 |
1996年 | 192篇 |
1995年 | 184篇 |
1994年 | 150篇 |
1993年 | 113篇 |
1992年 | 100篇 |
1991年 | 88篇 |
1990年 | 84篇 |
1989年 | 71篇 |
1988年 | 56篇 |
1987年 | 30篇 |
1986年 | 49篇 |
1985年 | 40篇 |
1984年 | 20篇 |
1983年 | 15篇 |
1982年 | 16篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1975年 | 7篇 |
1972年 | 7篇 |
1966年 | 5篇 |
1965年 | 6篇 |
1964年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
111.
Anwar Usman Suchada Chantrapromma Hoong‐Kun Fun 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):m45-m47
The title compound, bis(2,4‐dinitrophenolato‐κ2O,O′)(1,4,7,10,13,16‐hexaoxadecane‐κ6O)barium(II), [Ba(C6H3N2O5)2(C12H24O6)], is a 1:1 complex of barium(II)–2,4‐dinitrophenolate and 1,4,7,10,13,16‐hexaoxacyclooctadecane (18‐crown‐6). Its structure is located on a crystallographic inversion centre. The temperature dependence of the crystal structure has been studied. The monoclinic β angle of the P21/n space group increases with increasing temperature. The packing structure of the complex is stabilized by intermolecular C—H?O interactions. 相似文献
112.
113.
叠层连续开口圆柱壳的精确解 总被引:2,自引:0,他引:2
抛弃任何有关位移和应力模式的假设,引入δ-函数,对正变异性连续开口圆柱壳建立状态方程.给出薄的、中厚的和强厚的叠层连续开口圆柱壳静力问题的统一的精确解.数值结果和SAPS解进行了对比. 相似文献
114.
本文主要论述了0.5MeV,单能垂直入射的电子束在三种不同密度的氟化氪准分子激光介质中的能量沉积。计算是采用Monte Carlo方法的MCSED程序,光轴方向采用周期性边界条件,因此能够给出平行于和垂直于电子束入射方向的沉积能量的空间分布。本文给出了在三种不同密度下的出射电子的角分布。用该程序对垂直入射的,初始能量为1MeV的电子在半无限大Al靶中的沉积能量的计算结果与ONETRAN程序的结果及实验结果的比较表明MCSED程序的计算结果是可靠的。 相似文献
115.
Tumor cells transduced with herpes simplex virus thymidine kinase gene have been intensively applied to the field of positron emission tomography via imaging of its substrate. As a pilot synthesis approach, a facile preparation of 5‐[125I] iodoarabinosyl uridine starting from commercially available uridine is reported herein. 相似文献
116.
117.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
118.
介绍L波段长脉冲相对论速调管放大器研究中,长脉冲强流相对论电子束(IREB)经过输入腔和中间腔间隙后的脉冲缩短问题.分析了造成束流脉冲缩短的主要机理之一是高频系统的角向非均匀模式与电子束相互作用而使得束流扩散形成的,并经过实验参数的调节,减轻了长脉冲IREB的脉冲缩短问题,得到了较强的基波调制电流.从长脉冲加速器引出500 kV,3.5 kA,1.3 μs的电子束,经过输入腔和两个群聚腔的调制后,得到了2.0 kA的基波调制电流,束流脉冲宽度由0.3 μs增加到1 μs,束流脉冲缩短问题得到明显减轻.
关键词:
相对论速调管放大器
脉冲缩短
高功率微波
长脉冲强流相对论电子束 相似文献
119.
120.
Kikue S. Burnham Robert Roth Faith Zhou Wenya Fan Emma Brouk Mehari Stifanos 《Journal of polymer science. Part A, Polymer chemistry》2006,44(24):6909-6925
In an attempt to develop a low‐k interlayer dielectric, adamantane‐diphenyldiethynyl moiety containing oligomer is prepared. Oligomerization of 1,3,5,7‐tetrakis[3/4‐ethynylphenyl]adamantane ( 4 ) is accomplished by a Glaser–Hay oxidative coupling with 1,3,5‐triethynylbenzene and phenylacetylene end‐capping agent. The CHCl3 soluble oligomer is then thermally treated by step‐curing at 200, 300, 380, and 450 °C for 30 min at each temperature under nitrogen flow to render a shiny void‐free black polymer. TGA analysis indicates that the polymer is stable under nitrogen up to 500 °C with a marginal decomposition up to 800 °C. Solid‐state 13C NMR, Raman scattering, and FTIR are used to characterize the structure of the polymer. The polymer consists of amorphous carbon networks with the adamantane moieties and nanosized graphitic regions (clusters), which are generated from the thermal crosslinking of the diphenyldiethynyl units. It shows a remarkably low linear coefficient of thermal expansion (~25 ppm/°C), presumably due to the presence of the disordered graphitic structure. Its high density (~1.21 g/cm3), refractive index (~1.80 at 632 nm), and Young's modulus (~17.0 GPa) are also consistent with the interpretation. This study reveals important details about the effect of microscopic structure on the macroscopic properties of the highly crosslinked polymer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6909–6925, 2006 相似文献