首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   19942篇
  免费   1763篇
  国内免费   1077篇
化学   13655篇
晶体学   172篇
力学   731篇
综合类   110篇
数学   3117篇
物理学   4997篇
  2023年   227篇
  2022年   251篇
  2021年   429篇
  2020年   514篇
  2019年   519篇
  2018年   456篇
  2017年   490篇
  2016年   818篇
  2015年   763篇
  2014年   886篇
  2013年   1356篇
  2012年   1549篇
  2011年   1655篇
  2010年   1071篇
  2009年   938篇
  2008年   1146篇
  2007年   1033篇
  2006年   935篇
  2005年   800篇
  2004年   719篇
  2003年   637篇
  2002年   589篇
  2001年   428篇
  2000年   322篇
  1999年   321篇
  1998年   222篇
  1997年   187篇
  1996年   220篇
  1995年   163篇
  1994年   186篇
  1993年   146篇
  1992年   141篇
  1991年   152篇
  1990年   126篇
  1989年   123篇
  1988年   105篇
  1987年   90篇
  1986年   83篇
  1985年   109篇
  1984年   123篇
  1983年   74篇
  1982年   83篇
  1981年   77篇
  1980年   74篇
  1978年   71篇
  1977年   72篇
  1976年   66篇
  1974年   62篇
  1973年   60篇
  1968年   69篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
The method of equivalent variational methods, originally due to Carathéodory for free problems in the calculus of variations is extended to investigate boundary value problems for a class of second order differential equations on the half-line. Some applications are presented to illustrate the potential of this method.  相似文献   
102.
Héléne Gispert 《ZDM》2002,34(4):158-163
Evolutions of mathematical curricula in French society have been marked by the successive answers intitutions have given to the following question since one century: Why and whom teaching mathematics? Here I present two of these, one given in 1908 and one in 1967. Each symbolises a breaking period of reforms in secondary mathematics teaching in France. We will see in the two first part of this paper that they belong to two different worlds, with social, institutional, ideological and mathematical specific features. In the third part, I’ll focus on geometry, showing the effects of the different answers concerning the public and the aims of mathematical teaching.  相似文献   
103.
The validity of local parton-hadron duality within the framework of HERWIG and JETSET event generators is investigated. We concentrate one + e annihilations in LEP 2 energy range as these interactions provide theoretically the cleanest condition for the discussion of this concept. We conclude that the concept of local parton-hadron duality is not valid in either of the two generators considered.  相似文献   
104.
通过对气吹式精密播种机田间试验资料的相关分析,发现合格指数A与|D-M|(重播指数与漏播指数之差的绝对值)之间里极显著负相关(r=-0.9312)。在对数据作进一步回归分析的基础上,本文建立了一套“由排种粒数预测排种质量”的方法。  相似文献   
105.
The laser cladding of Fe-based alloys on a medium carbon steel substrate was performed using a CO2 laser and Ar shielding gas that was blown into a molten pool. The microstructure and cracking susceptibility of the laser-clad layers were studied in terms of carbon additions. Results show that the small change of the carbon content in the alloy powders can obviously change the microstructure and properties of the layers. When the carbon content is in the range of 0.3–0.4 wt.%, the decrease of the carbon content in alloy powders will increase the hardness and toughness of the layers simultaneously under the same process parameters. As a result, crack-free coatings with high hardness can be obtained. As the carbon content increases from 0.2 wt.% to 0.4 wt.%, the segregation ratio of chromium increases, while the segregation ratios of nickel, manganese, and silicon first decrease and then increase. At the same time, a new designing principle concerning the composition and microstructure has been put forward, and the principal mechanisms of strengthening and toughening of the layers are fine-grain strengthening and low carbon martensitic phase transformation strengthening.  相似文献   
106.
107.
In this work we study semifield planes of orderq n(q=p r ,p prime) with a collineation whose order is ap-primitive divisor ofq n–1.Research supported in part by NSF Grant No. DMS-9107372Research supported in part by NSF grants RII-9014056, component IV of the EPSCoR of Puerto Rico grant and ARO grant for Cornell MSI.  相似文献   
108.
S-烯丙基硫赶磷酸酯在SiO2上的合成   总被引:1,自引:0,他引:1  
探讨了O 烯丙基硫逐磷酸酯热重排制备S 烯丙基硫赶磷酸酯的反应条件 ,结果表明 :反应在SiO2 上进行几乎可定量地完成 .运用这一合成方法 ,制备了 14个不对称结构的新型硫赶磷酸酯 ,所有的化合物均经IR ,1HNMR ,3 1PNMR及元素分析表征 .生物活性试验显示 5a ,5e ,5h ,5i及 5k有良好的杀虫活性 .  相似文献   
109.
Diatomaceous earth was functionalized by grafting organotrialkoxysilane precursors onto the surface of the porous silica cell walls of this biomineral. Vinyl- and mercapto-containing structures were prepared in aqueous media without disruption of the diatomic architecture. Successful grafting of the organic moieties was confirmed using solid state 29Si MAS NMR spectroscopy, and the presence of the intact diatom framework by scanning electron microscopy. The sorption properties of mercaptopropyl-functionalized diatoms towards heavy metals was studied by measuring the accessibility and diffusion rates of mercury(II) species to the binding sites (-SH) by the means of electrochemical methods.  相似文献   
110.
Michaël Ternon 《Tetrahedron》2004,60(39):8721-8728
FRET based systems are some of the best methods available to detect and monitor proteolytic activity. To enhance fluorescent signals and hence assay sensitivity, two different systems were developed using two different dendrimeric constructs. In the first case, a triple branched dendrimer bearing three dansyl groups was used to enhance assay sensitivity and showed a significant enhancement of fluorescence following enzymatic cleavage. In another example, a tris-fluorescein probe, that undergoes self-quenching, was utilized in a combinatorial library synthesis to map the substrate specificity of proteases.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号