Spectral Domain Analysis of Coaxial Cavities

Coaxial cavities are used in high power gyrotrons as the beam-wave interaction structure. Much research has been devoted to their mode selective properties. A coaxial cavity lacks a sharp boundary at its open end, so it has some physical features that can only be observed using a spectral model, such as frequency-dependent field profiles and mode overlapping effects. These properties are important since cold tests are usually conducted in the frequency domain. This study applies the incident/reflected wave boundary condition to the wave equation of a weakly irregular coaxial waveguide. The resistivity of the wall is considered in the analysis. Calculations reveal that the fixed-position spectrum yields an uncertain resonant frequency and quality factor. Although the maximum-field spectrum can uniquely determine the properties of the coaxial cavity, the resonant frequency obtained using the maximum-field spectral model is inconsistent with that obtained using the temporal model. The field-energy spectrum explains the low Q nature of the coaxial cavity. Moreover, resonant frequencies evaluated using the field-energy spectrum agree precisely with those evaluated using the temporal model.     

Synthesis and characterization of wholly aromatic poly(azomethine)s containing donor–acceptor triphenylamine moieties

N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl₃), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (T_gs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (Φ_F) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007     

CT实验仪的研制及其在物理教学中的应用

介绍了我们研制的CT实验仪的原理及开发，使用情况，包括CT的物理，数学原理，CT装置的结构，性能、工作原理等，文末给出实验结果，并对装置在物理实验教学中的意义作了讨论。     

Synthesis of poly(arylene disulfide)-vermiculite nanocomposites via in situ ring-opening reaction of cyclic oligomers

An exfoliated poly(4,4^′-oxybis(benzene)disulfide) (POBDS)/vermiculite (VMT) nanocomposite was prepared by using cyclo(4,4^′-oxybis(benzene)disulfide) (COBDS) oligomers and cetyltrimethyl ammonium bromide exchanged VMT. The POBDS/VMT nanocomposites were fabricated in two steps. First, the COBDS oligomers were used to swell and exfoliate organo VMT to afford COBDS-VMT nanocomposite precursor. Subsequently, the exfoliated POBDS-VMT nanocomposite can be made via in situ and instant melt ring-opening polymerization of the COBDS-VMT nanocomposite precursor. High molecular weight POBDS polymer can be formed in a few minutes. The nano scale dispersion of VMT layers within POBDS polymer was confirmed by both the X-ray diffraction patterns and TEM examinations. This methodology provides a potential approach to synthesize high performance polymer nanocomposite.     

ON THE COHOMOLOGY OF GENERALIZED RESTRICTED LIE ALGEBRAS

0.IntroductionThispaperisaimedatdevelopingthecohomologytheoryofmodularLiealgebrasandthendeterminingthefirstcohomologygroupsofCartantypeLiealgebras.AsgeneralizationoftheconceptofrestrictedLiealgebras,ageneralizedrestrictedLiealgebra(GRLiealgebra)wasintroducedin[21],whichisassociatedwithabasisandamappingofthebasisintotheLiealgebrasatisfyingthegeneralized-restrictednessconditions.Generalizedrestrictedrepresentations(GRrepresentations)werethenintroduced,whichcanbereducedtotherepresentationsofa…     

Bi3+和Eu3+在Ca2SiO4中的发光和能量传递

用高温固态反应合成了Ca2SiO4:Bi3+,Ca2SiO4:Eu3+和Ca2SiO4:Eu3+,Bi3+发光体。讨论了不同掺杂量和掺杂种类时Bi3+对Eu3+的5D0-7F1,5D0-7F2发射的影响规律。实验发现,Ca2SiO4:Bi3+在紫外线激发下发出明亮的蓝色光,Ca2SiO4:Eu3+,Bi3+中的Bi3+能将激发能传递给Eu3+,使Eu3+的5D0-7F1和5D0-7F2两种跃迁都大大加强,同时,Bi3+也发出鲜艳的紫色光。     

造纸污泥与废水污泥流化床焚烧时NO_x和SO_2的排放特性研究

1前言流化床焚烧污犯是近年来发达国家广泛采用的方法，它能很好地实现污泥的稳定化、无害化、减容化和资源化处理。燃煤流化床锅炉污染物排放方面已做了大量的研究工作，由于污泥与煤在结构和性质方面的差异较大，因此有必要对流化床焚烧污泥时污染物排放特性进行研究。本文详细研究了造纸、废水污泥在流化床中焚烧时污泥水份、运行床温及过量空气对NO。和SO。的排放特性及污泥N－＋NO。、S－SO。的转化率的影响，并对这两种性质差异较大的污泥焚烧时的NO。和502的生成特性进行了对比分析，取得了许多有价值的结果，为污泥流化床焚烧…     

Synthesis of 5‐Radioiodoarabinosyl Uridine Analog for Probing the HSV‐1 Thymidine Kinase Gene

Tumor cells transduced with herpes simplex virus thymidine kinase gene have been intensively applied to the field of positron emission tomography via imaging of its substrate. As a pilot synthesis approach, a facile preparation of 5‐[¹²⁵I] iodoarabinosyl uridine starting from commercially available uridine is reported herein.     

On the Kauffman skein modules

 Let k be a subring of the field of rational functions in α, s which contains α ^±1 ,s ^±1 . Let M be a compact oriented 3-manifold, and let K(M) denote the Kauffman skein module of M over k. Then K(M) is the k-module freely generated by isotopy classes of framed links in M modulo the Kauffman skein relations. In the case of , the field of rational functions in α, s, we give a basis for the Kauffman skein module of the solid torus and a basis for the relative Kauffman skein module of the solid torus with two points on the boundary. We then show that K(S ¹ × S ² is freely generated by the empty link, i.e., . Received: 20 October 2001 / Revised version: 20 March 2002