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31.
Madalina Tudose Florin D. Badea Miron T. Caproiu Adrian Beteringhe Maria Maganu Petre Ionita Titus Constantinescu Alexandru T. Balaban 《Central European Journal of Chemistry》2010,8(4):789-796
Starting from N-hydroxyphthalimide 1 and the reactive fluoro- or chloro-nitroaryl derivatives 2, 3 and 4a-e (2-chloro-3,5-dinitropyridine; 3, NBD-chloride; 4a, 1-fluoro-2,4-dinitrobenzene; 4b, picryl chloride; 4c, 4-chloro-3,5-dinitrobenzotrifluoride; 4d, 2-chloro-3,5- dinitrobenzotrifluoride; 4e, 4-chloro-3,5-dinitrobenzoic acid) the corresponding N-(2-nitroaryloxy)-phthalimide derivatives 5a-e, or 6 and 7 were obtained and characterized by IR, UV-Vis 1H-NMR and 13C-NMR spectroscopy. The TLC behavior and the hydrophobicity of these derivatives have been experimentally evaluated by RM0 parameters (using RP-TLC). The experimental RM0 parameters were compared with the calculated partition coefficient, log P. A QSPR study was also performed to establish possible
correlations between the structure and physical properties (λmax and RM0) of compounds 5a-e, 6, and 7.
相似文献
32.
Dumitru Condrat Cristina Mosoarca Alina D. Zamfir Florin Cri?an Maria R. Szabo Alfa X. Lupea 《Central European Journal of Chemistry》2010,8(3):530-535
This study presents the results obtained from qualitative and quantitative analysis of gallic acid from hydro-alcoholic extracts
(methanol, ethanol) of plants from Plantae regnum. Plant qualitative analysis was performed using a novel mass spectrometric (MS) method based on fully automated chip-nanoelectrospray
ionization (nanoESI) high capacity ion trap (HCT) while quantitative analysis was carried out by high performance liquid chromatography
(HPLC). These methods were applied to Alchemilla vulgaris — common lady’s-mantle (aerial part), Allium ursinum — bear’s garlic (leaves), Acorus calamus — common sweet flag (roots), Solidago virga-aurea — goldenrod (aerial part). Obtained results indicated that methanol extracts (96%, 80%) have a gallic acid content ranging
between 0.0011–0.0576 mg mL−1 extract while the ethanol extracts (96%, 60%) exhibit a gallic acid concentration that varies between 0.0010–0.0182 mg mL−1 extract.
相似文献
33.
A low specific on-resistance (R S,on) silicon-on-insulator (SOI) trench MOSFET (metal-oxide-semiconductor-field-effect-transistor) with a reduced cell pitch is proposed.The lateral MOSFET features multiple trenches:two oxide trenches in the drift region and a trench gate extended to the buried oxide (BOX) (SOI MT MOSFET).Firstly,the oxide trenches increase the average electric field strength along the x direction due to lower permittivity of oxide compared with that of Si;secondly,the oxide trenches cause multiple-directional depletion,which improves the electric field distribution and enhances the reduced surface field (RESURF) effect in the SOI layer.Both of them result in a high breakdown voltage (BV).Thirdly,the oxide trenches cause the drift region to be folded in the vertical direction,leading to a shortened cell pitch and a reduced R S,on.Fourthly,the trench gate extended to the BOX further reduces R S,on,owing to the electron accumulation layer.The BV of the MT MOSFET increases from 309 V for a conventional SOI lateral double diffused metal-oxide semiconductor (LDMOS) to 632 V at the same half cell pitch of 21.5 μm,and R S,on decreases from 419 m · cm 2 to 36.6 m · cm 2.The proposed structure can also help to dramatically reduce the cell pitch at the same breakdown voltage. 相似文献
34.
An essential point of a conformal vector field ξ on a conformal manifold (M,c) is a point around which the local flow of ξ preserves no metric in the conformal class c. It is well-known that a conformal vector field vanishes at each essential point. In this note we show that essential points are isolated. This is a generalization to higher dimensions of the fact that the zeros of a holomorphic function are isolated. As an application, we show that every connected component of the zero set of a conformal vector field is totally umbilical. 相似文献
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37.
László Csaba Bencze Csaba Paizs Monica Ioana Toşa Maria Trif Florin Dan Irimie 《Tetrahedron: Asymmetry》2010,21(16):1999-2004
A highly stereoselective enzymatic kinetic resolution of novel various substituted racemic furylbenzthiazole-2-yl-ethanols and their acetates has been developed. Both processes, the enzymatic acylation of the racemic alcohols and the enzymatic methanolysis of racemic acetates yielded highly enantiomerically enriched (ee >98%) resolution product, when CaL-B was used as a biocatalyst in acetonitrile. The absolute configuration of the obtained (R)-(+)-1-(5-(4-chlorobenzo[d]thiazol-2-yl)furan-2-yl)ethanol was determined by a detailed 1H NMR study of rac- and (+)-1-(5-(4-chlorobenzo[d]thiazol-2-yl)furan-2-yl)ethanol Mosher derivatives. 相似文献
38.
We study the Lie algebra of infinitesimal isometries on compact Sasakian and K-contact manifolds. On a Sasakian manifold which is not a space form or 3-Sasakian, every Killing vector field is an infinitesimal automorphism of the Sasakian structure. For a manifold with K-contact structure, we prove that there exists a Killing vector field of constant length which is not an infinitesimal automorphism of the structure if and only if the manifold is obtained from the Konishi bundle of a compact pseudo-Riemannian quaternion-Kähler manifold after changing the sign of the metric on a maximal negative distribution. We also prove that nonregular Sasakian manifolds are not homogeneous and construct examples with cohomogeneity one. Using these results we obtain in the last section the classification of all homogeneous Sasakian manifolds. 相似文献
39.
Florin Nicolae 《Journal of Number Theory》2007,124(1):26-30
Let K/Q be a finite Galois extension with the Galois group G, let χ1,…,χr be the irreducible non-trivial characters of G, and let A be the C-algebra generated by the Artin L-functions L(s,χ1),…,L(s,χr). Let B be the subalgebra of A generated by the L-functions corresponding to induced characters of non-trivial one-dimensional characters of subgroups of G. We prove: (1) B is of Krull dimension r and has the same quotient field as A; (2) B=A iff G is M-group; (3) the integral closure of B in A equals A iff G is quasi-M-group. 相似文献
40.
Dinar Abdullin Nicole Florin Dr. Gregor Hagelueken Prof. Dr. Olav Schiemann 《Angewandte Chemie (International ed. in English)》2015,54(6):1827-1831
Metal ions play an important role in the catalysis and folding of proteins and oligonucleotides. Their localization within the three‐dimensional fold of such biomolecules is therefore an important goal in understanding structure–function relationships. A trilateration approach for the localization of metal ions by means of long‐range distance measurements based on electron paramagnetic resonance (EPR) is introduced. The approach is tested on the Cu2+ center of azurin, and factors affecting the precision of the method are discussed. 相似文献