全文获取类型
收费全文 | 24077篇 |
免费 | 4281篇 |
国内免费 | 4023篇 |
专业分类
化学 | 18377篇 |
晶体学 | 400篇 |
力学 | 1359篇 |
综合类 | 329篇 |
数学 | 2875篇 |
物理学 | 9041篇 |
出版年
2024年 | 51篇 |
2023年 | 399篇 |
2022年 | 612篇 |
2021年 | 869篇 |
2020年 | 968篇 |
2019年 | 984篇 |
2018年 | 848篇 |
2017年 | 890篇 |
2016年 | 1176篇 |
2015年 | 1216篇 |
2014年 | 1533篇 |
2013年 | 1902篇 |
2012年 | 2193篇 |
2011年 | 2343篇 |
2010年 | 1780篇 |
2009年 | 1778篇 |
2008年 | 1965篇 |
2007年 | 1700篇 |
2006年 | 1572篇 |
2005年 | 1222篇 |
2004年 | 925篇 |
2003年 | 740篇 |
2002年 | 754篇 |
2001年 | 642篇 |
2000年 | 532篇 |
1999年 | 454篇 |
1998年 | 364篇 |
1997年 | 286篇 |
1996年 | 300篇 |
1995年 | 260篇 |
1994年 | 178篇 |
1993年 | 160篇 |
1992年 | 134篇 |
1991年 | 127篇 |
1990年 | 105篇 |
1989年 | 99篇 |
1988年 | 57篇 |
1987年 | 49篇 |
1986年 | 50篇 |
1985年 | 37篇 |
1984年 | 21篇 |
1983年 | 27篇 |
1982年 | 17篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1974年 | 5篇 |
1972年 | 4篇 |
1957年 | 4篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 107 毫秒
91.
Jiaqiang Wang Hua Fang Ying Li Junjie Li Zhiying Yan 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):75-79
Cobalt-doped mesoporous titania with a crystalline framework synthesized by surfactant templating method presented highly selective (99%) and reasonable conversion rate (49%) of catalytic oxidation of para-chlorotoluene to para-chlorobenzaldehyde in acetic acid using aqueous hydrogen peroxide as oxidant for the first time. Recycling of the catalyst indicates that the catalyst can be used a number of times without losing its activity to a greater extent. By contrast, cobalt-doped mesoporous titania without a crystalline structure and cobalt doped the commercial titania, Degussa P25 prepared by impregnation method with the similar concentration of cobalt were found inactive. The effects of catalyst concentration, reaction time, reaction temperature, and solvents on the performance of the catalyst were also investigated. 相似文献
92.
Xiao-Hong Xu Xiao-Li Li Fang Wang Feng-Xian Jiang Hai-Shun Wu 《Applied Surface Science》2006,252(8):2910-2914
FexPt100−x(30 nm) and [FexPt100−x(3 nm)/ZrO2]10 (x = 37, 48, 57, 63, 69) films with different ZrO2 content were prepared by RF magnetron sputtering technique, then were annealed at 550 °C for 30 min. This work investigates the effect of ZrO2 doping on the microstructural evolution, magnetic properties, grain size, as well as the ordering kinetics of FePt alloy films. The as-deposited films behaved a disordered state, and the ordered L10 structure was obtained by post-annealing. The magnetic properties of the films are changed from soft magnetism to hard magnetism after annealing. The variation of the largest coercivities of [FexPt100−x/ZrO2]10 films with the Fe atomic percentage, x and differing amounts of ZrO2 content reveals that as we increase the ZrO2 content we must correspondingly increase the amount of Fe. This phenomenon suggests that the Zr or O atoms of ZrO2 preferentially react with the Fe atoms of FePt alloy to form compounds. In addition, introducing the nonmagnetic ZrO2 can reduce the intergrain exchange interactions of the FePt/ZrO2 films, and the interactions are decreased as the ZrO2 content increases, the dipole interactions are observed in FePt/ZrO2 films as the ZrO2 content is more than 15%. 相似文献
93.
利用关于乘积分布密度的相对熵和相对熵率的概念,建立了相依连续型随机变量序列关于参考微分熵的一类强偏差定理,证明中给出了将Laplace变换应用于微分熵强偏差定理的研究的一种途径. 相似文献
94.
超子中子星性质的温度效应 总被引:2,自引:0,他引:2
从相对论平均场理论出发,考虑核子、超子和介子的相互作用,研究了温度对中子星组成粒子、状态方程和中子星质量等的影响.发现温度越高,超子在中子星内部出现时的重子数密度越低.当密度较高时,中子星的核心区主要由超子组成,即中子星转变成以奇异粒子为主要成分的超子星,并且这种转变受到温度的影响,温度越高,转变密度越低.由于超子的出现,中子星核心高密度区域的状态方程,对于不同温度,差别不大,所以有限温度中子星的最大质量都在1.8M⊙附近.这与观测结果相符. 相似文献
95.
96.
中国股票市场波动特性的实证研究 总被引:4,自引:0,他引:4
倪杰 《数学的实践与认识》2003,33(9):50-54
本文以上证综指和深成分指数的日收益率为研究对象 ,应用 GARCH、TARCH模型理论 ,进一步分析了日收益率波动的条件异方差性、非对称性 ,同时比较了两个股票市场的不同波动特征 相似文献
97.
F. R. Ling B. Wang T. Geng S. Q. Fang W. Yuan D. D. Teng C. X. Guan 《Optics & Laser Technology》2004,36(7):541-544
In this paper experimental studies of nonvolatile photorefractive holographic recording in Ce:Cu:LiNbO3 crystals doped with Sc(0,1,2,3 mol%) were carried out. The Sc:Ce:Cu:LiNbO3 crystals were grown by the Czochralski method and oxidized in Nb2O5 powders. The nonvolatile holographic recording in Sc:Ce:Cu:LiNbO3 crystals was realized by the two-photon fixed method. We found that the recording time of Sc:Ce:Cu:LiNbO3 crystal became shorter with the increase of Sc doping concentration, especially doping with Sc(3 mol%), which exceeds the so-called threshold, and there was little loss of nonvolatile diffraction efficiencies between Sc(3 mol%):Ce:Cu:LiNbO3 and Ce:Cu:LiNbO3 crystals. 相似文献
98.
HaiHuiXIE XiaoYiWEI JiDongWANG MeiFangLIU RenZhouYANG 《中国化学快报》2003,14(6):588-590
A New Annonaceous acetogenin,squamostolide(1),was isolated from the seeds of Annona squamosa.Its structure was elucidated based on spectroscopic methods and comparison with known compounds.It is the first example of Annonaceous acetogenin with each of the two ends of the aliphatic chain bearing a γ-lactone.Thenew compound exhibited cytotoxic activity in vitro against bel-7402 and CNE2 human tumor cell lines. 相似文献
99.
F-H实验仪与光栅光谱仪连用观测253.7nm谱线 总被引:1,自引:0,他引:1
通过F-H实验仪和光栅光谱仪的连用,可实时观测汞原子从6s6s1So态激发到6s6sSP1态,退激时,辐射出能量为4.9eV的光量子,其波长为253.7nm. 相似文献
100.
Spectral and Pseudospectral Approximations Using Hermite Functions: Application to the Dirac Equation 总被引:1,自引:0,他引:1
We consider in this paper spectral and pseudospectral approximations using Hermite functions for PDEs on the whole line. We first develop some basic approximation results associated with the projections and interpolations in the spaces spanned by Hermite functions. These results play important roles in the analysis of the related spectral and pseudospectral methods. We then consider, as an example of applications, spectral and pseudospectral approximations of the Dirac equation using Hermite functions. In particular, these schemes preserve the essential conservation property of the Dirac equation. We also present some numerical results which illustrate the effectiveness of these methods. 相似文献