A New Reagent for the Reduction of N-Arylsulfonylimines

Potassiumselenatedborohydride(KBHZSe3),sodiumselenatedborohydride(NaBHZSe3)werepreparedfirstbyLalancetteetall.However,sincethen,therehavebeenlittlereportabouttheirapplication.Wehaveusedpotassiumselenatedborohydrideinformamidetoreducearomaticnitrocompounds,andsuccessfullyobtainedthecorrespondinganilines2.Inaddition,wehavealsoreportedthereductionofarylsulfonylchloridestothecorrespondingdisulfidesbysodiumselenatedborohydriderefluxinginCH,CN'.Fromourresearchwork,KBHZSe3andNaBHZSe3werefou…     

A Barbier type reaction promoted by in situ formed active metal bismuth from NaBH_4 and BiCl_3 in aqueous media

In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresponding homoallylic alcohols were obtained in excellent yields with high chemo-and stereoselectivity.     

相移测量技术中相移器研究

本文介绍一种用于相移测量技术的相移器。该相移器由计算机通过Ｄ／Ａ接口板自动控制输出电压幅度，其电路采用闭环控制，位移由压电晶体产生，具有很高的电压稳定度（０１％）和较小的相移误差（小于３°）。描述相移器的结构、驱动源工作原理及相移器标定方法     

关于《L_p范数下凸约束最佳逼近的特征》中一个引理的注记

最近．许树声［１］撰文给出了对Ｌ_ｐ范数下凸约束最佳逼近的特征定理．并研究了该定理的苦干应用．然而，文［１］引理１证明中部分地方有误．本文给予了纠正，予以重新证明     

Generation of 2－10ns Excimer Laser Pulse by Optical Synchronizing Wave－clipping

Ｇｅｎｅｒａｔｉｏｎｏｆ２－１０ｎｓＥｘｃｉｍｅｒＬａｓｅｒＰｕｌｓｅｂｙＯｐｔｉｃａｌＳｙｎｃｈｒｏｎｉｚｉｎｇＷａｖｅ－ｃｌｉｐｐｉｎｇＸＩＡＮＧＳｈｉｑｉｎｇ；ＬＯＵＱｉｈｏｎｇ；ＤＯＮＧＪｉｎｇｘｉｎｇ；ＭＡＮＧＹａｎｐｉｎｇ；ＷＥＩＹｕｎｒ...     

SOLUTE REDISTRIBUTION IN THE INITIAL TRANSIENT REGION OF DIRECTIONAL SOLIDIFICATION SPECIMEN

The solute redistribution during initial transient process of directional solidification of a binary alloy is associated with the solid-liquid interface advancing velocity which will pass a hysteretic process approaching to the externally imposed velocity. In the present paper, a new accelerated growth equation, dV/dt = μG[m/G·(dG_L^*)/dt+V_e-V] is deduced, based on which a new formula for the initial transient solute redistribution is obtained with the reasonable assumption that the solid-liquid interface advancing velocity changes exponentially during solidification. It shows that the kinematic effect dominates solidification at high velocity while the coupling effect of thermal and mass transportation controls that at lower velocity.In addition, another new equation to calculate the time required for a planar interface to lose stability is also found. Since the effects of the imposed thermal gradient are taken into account in the new equations, they are more reasonable and satisfactory than those given by Tiller et al. and by Smith et al.     

Maximum Likelihood Estimation of Isotonic Normal Means with Unknown Variances

To analyze the isotonic regression problem for normal means, it is usual to assume that all variances are known or unknown but equal. This paper then studies this problem in the case that there are no conditions imposed on the variances. Suppose that we have data drawn fromkindependent normal populations with unknown meansμ_i's and unknown variancesσ²_i's, in which the means are restricted by a given partial ordering. This paper discusses some properties of the maximum likelihood estimates ofμ_i's andσ²_i's under the restriction and proposes an algorithm for obtaining the estimates.     

SU(2)格点规范理论几种不同形式的作用量的Monte Carlo研究

对SU(2)格点规范理论用三种不同于常用形式的作用量进行了Monte Carlo模拟,计算了平均内能和比热。内能曲线都趋向共同的弱耦合极限,都有比热峰标志着临界点。观察到仅由于格点间隔α的高次幂项不同而引起临界点明显漂移的现象。 关键词：     

人类认识和利用能源的历史

能源,是人类利用的自然界能量资源的总称。人类在不断征服自然、改造社会的斗争中,逐步加深、扩大对能源的认识和利用;而对自然界能源的利用越发展,就越增强了人类改造世界的物质力量。因此,能源发展史和人类社会的发展史总是紧密联系在一起的。在阶级社会里,人类对自然力的认识和利用,总是受一定的阶级关系支配的。因此,从原