| A Barbier type reaction promoted by in situ formed active metal bismuth from NaBH_4 and BiCl_3 in aqueous media |
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| 作者姓名： | REN Ping-Da PAN Shi-Feng DONG Ting-Wei WU Shi-Hui |
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| 作者单位： | REN，Ping-Da PAN，Shi-Feng DONG，Ting-Wei WU，Shi-HuiDepartment of Chemistry，Pudan University，Shanghai 200433，China |
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| 摘 要： | In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresponding homoallylic alcohols were obtained in excellent yields with high chemo-and stereoselectivity.
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A Barbier type reaction promoted by in situ formed active metal bismuth from NaBH_4 and BiCl_3 in aqueous media |
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| REN,Ping-Da PAN,Shi-Feng DONG,Ting-Wei WU,Shi-Hui.A Barbier type reaction promoted by in situ formed active metal bismuth from NaBH_4 and BiCl_3 in aqueous media[J].Chinese Journal of Chemistry,1996,14(5):462-466. |
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| Authors: | REN Ping-Da PAN Shi-Feng DONG Ting-Wei WU Shi-Hui |
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| Institution: | REN,Ping-Da PAN,Shi-Feng DONG,Ting-Wei WU,Shi-HuiDepartment of Chemistry,Pudan University,Shanghai 200433,China |
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| Abstract: | In the presence of active metal bismuth (Bi) which was prepared from the combination of bismuth trichloride and sodium borohydride,aldehydes have been found to react with allyl bromide in aqueous media,and the corresponding homoallylic alcohols were obtained in excellent yields with high chemo-and stereoselectivity. |
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| Keywords: | Barbier type reaction aqueous medium reaction active metal bismuth |
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